Ink compositions for fabricating objects from regoliths and methods of forming the objects

Patent metadata

Field	Value
Publication number	US-2018079922-A1
Application number	US-201615564522-A
Country	US
Kind code	A1
Filing date	Apr 7, 2016
Priority date	Apr 7, 2015
Publication date	Mar 22, 2018
Grant date	—

Abstract

Ink compositions for fabricating objects from planetary regoliths and objects fabricated from the ink compositions are provided. The objects include flexible, elastomeric objects and hard objects. Also provided are methods, including three-dimensional (3D) printing methods, for fabricating objects using the ink compositions. The ink compositions comprise a natural planetary regolith, such as an extraterrestrial regolith, a graded solvent system, and an elastomeric polymer binder.

First claim

What is claimed is:

1 . An ink composition comprising:
a planetary regolith comprising a reducible metal oxide and non-reducible ceramics; a graded organic solvent system; and an elastomeric polymer binder.

2 . The ink composition of claim 1 , wherein the planetary regolith is a naturally occurring terrestrial regolith.

3 . The ink composition of claim 1 , wherein the planetary regolith is a naturally occurring extraterrestrial regolith.

4 . The ink composition of claim 1 , wherein the reducible metal oxide comprises iron oxide.

5 . The ink composition of claim 1 , wherein the non-reducible ceramics comprise SiO 2 and Al 2 O 3 .

6 . The ink composition of claim 4 , wherein the non-reducible ceramics comprise SiO 2 and Al 2 O 3 .

7 . The ink composition of claim 6 , wherein the SiO 2 and Al 2 O 3 comprise at least 50 wt. % of the total weight of the reducible metal oxides and non-reducible ceramics in the planetary regolith.

8 . A method of forming a three-dimensional object, the method comprising:
(a) forming an elastomeric three-dimensional object from an ink composition comprising:
a planetary regolith comprising a reducible metal oxide and non-reducible ceramics;
a graded organic solvent system; and
an elastomeric polymer binder; and
(b) exposing the elastomeric three-dimensional object to a reducing gas at a temperature and for a period of time sufficient to reduce the reducible metal oxide to its corresponding metal to form a three-dimensional object comprising a composite comprising the metal and the non-reducible ceramics.

9 . The method of claim 8 , wherein the reducing gas comprises H 2 .

10 . The method of claim 8 , wherein the temperature is in the range from 900° C. to 1300° C. and the time is in the range from 2 to 48 hours.

11 . The method of claim 8 , further comprising adding an additional quantity of a reducible metal oxide to the ink composition prior to using it to form the elastomeric three-dimensional object.

12 . The method of claim 8 , wherein forming an elastomeric three-dimensional object from the ink composition comprises 3D printing the ink composition.

13 . The method of claim 8 , wherein the planetary regolith is a naturally occurring terrestrial regolith.

14 . The method of claim 8 , wherein the planetary regolith is a naturally occurring extraterrestrial regolith.

15 . The method of claim 8 , wherein the reducible metal oxide comprises iron oxide and its corresponding metal is iron.

16 . The method of claim 8 , wherein the non-reducible ceramics comprise SiO 2 and Al 2 O 3 .

17 . The method of claim 15 , wherein the non-reducible ceramics comprise SiO 2 and Al 2 O 3 .

18 . The method of claim 17 , wherein the SiO 2 and Al 2 O 3 comprise at least 50 wt. % of the total weight of the reducible metal oxides and non-reducible ceramics in the planetary regolith.

19 . A three-dimensional object comprising:
a composite comprising a metal and a planetary regolith; and an elastomeric polymer binder.

20 . The object of claim 19 , wherein the planetary regolith is a naturally occurring extraterrestrial regolith.

Assignees

• Univ Northwestern

Inventors

• Shah Ramille N
• Jakus Adam E
• Koube Katie D
• Taylor Shannon L

Classifications

• C09D11/10

  based on artificial resins · CPC title

• C04B35/14

  based on silica · CPC title

• B29C64/165 Primary

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• C04B35/10

  based on aluminium oxide · CPC title