Method For Preparing A Sorbent

Patent metadata

Field	Value
Publication number	US-2018071711-A1
Application number	US-201715814007-A
Country	US
Kind code	A1
Filing date	Nov 15, 2017
Priority date	Dec 18, 2013
Publication date	Mar 15, 2018
Grant date	—

Abstract

A method is described for preparing a sorbent comprising the steps of:
(i) mixing together an inert particulate support material and one or more binders to form a support mixture, (ii) shaping the support mixture by granulation in a granulator to form agglomerates, (iii) coating the agglomerates with a coating mixture powder comprising a particulate copper sulphide and one or more binders to form a coated agglomerate, and (iv) drying the coated agglomerate to form a dried sorbent.

First claim

What is claimed is:

1 . A method for preparing a sorbent comprising the steps of:
(i) mixing an inert particulate support material and one or more binders to form a support mixture, (ii) shaping the support mixture in a granulator using a liquid to form agglomerates, (iii) without drying the agglomerates, coating the agglomerates with a coating mixture powder comprising a particulate copper sulphide and one or more binders to form a coated agglomerate by adding the coating mixture to the agglomerates in the granulator, and (iv) drying the coated agglomerate to form a dried sorbent.

2 . The method according to claim 1 , wherein the inert particulate support material is alumina, a metal-aluminate, silicon carbide, silica, titania, zirconia, zinc oxide, an aluminosilicate, zeolite, a metal carbonate, carbon, or a mixture thereof.

3 . The method according to claim 1 , wherein the inert particulate support material is an alumina or hydrated alumina.

4 . The method according to claim 1 , wherein the inert particulate support material is in the form of a powder with a D 50 particle size in the range of 1-100 μm.

5 . The method according to claim 1 , wherein the binder is a clay binder, cement binder, or organic polymer binder.

6 . The method according to claim 1 , wherein the binder is a combination of a cement binder and a clay binder.

7 . The method according to claim 6 , wherein the relative weights of the cement and clay binders is in the range 1:1 to 3:1 (first to second binder).

8 . The method according to claim 1 , wherein the total amount of the binder in the agglomerate is in the range of 5-30% by weight.

9 . The method according to claim 1 , wherein agglomerates have a diameter in the range of 1-15 mm.

10 . The method according to claim 1 , wherein the particulate copper sulphide material is manufactured by roasting copper or a copper compound with elemental sulphur, precipitating copper sulphide from solution, sulphiding a copper compound using hydrogen sulphide, or mixing powdered copper metal with elemental sulphur under conditions that cause the elemental copper and elemental sulphur to react to form one or more copper sulphides.

11 . The method according to claim 1 , wherein the copper sulphide comprises copper (II) sulphide and/or substoichiometric copper sulphides of formula Cu 2-x S where x is 0-1.

12 . The method according to claim 1 , wherein the particulate copper sulphide has a S:Cu atomic ratio of ≧0.8.

13 . The method according to claim 1 , wherein the particulate copper sulphide is in the form of a powder with an average particle size, [D 50 ],in the range of 5-100 μm.

14 . The method according to claim 1 , wherein the copper sulphide content of the sorbent is in the range of 0.5-75% by weight (expressed as CuS in the dried sorbent).

15 . The method according to claim 1 , wherein the total binder content of the coating mixture is in the range of 5-20% by weight.

16 . The method according to claim 1 , wherein the coating mixture comprises a particulate copper sulphide and a clay binder as the sole binder.

17 . The method according to claim 1 , wherein the copper sulphide is present as a layer on the surface of the agglomerate and the thickness of the layer in the dried sorbent is in the range 1 to 1000 μm.

18 . The method according to claim 1 , wherein the sorbent comprises a particulate copper sulphide coated, along with a clay binder and optionally an alumina and/or hydrated alumina, as a surface layer of 1 to 1000 μm thickness on the surface of agglomerates formed from a particulate hydrated alumina support material, bound together with a cement binder and a clay binder.

19 . The method according to claim 1 , wherein the coating mixture further comprises an alumina and/or hydrated alumina.

20 . The method according to claim 1 , wherein the coating mixture is applied to the agglomerates under a dry and/or non-oxidising atmosphere.

21 . The method according to claim 1 , wherein the coated agglomerate is dried at 70-150° C.

22 . A sorbent obtained by the method of claim 1 .

23 . A process for removing a heavy metal from a fluid stream, comprising contacting the fluid stream with a sorbent prepared according to claim 22 .

Assignees

• Johnson Matthey Plc

Inventors

• Evans Matthew James
• Lunn Matthew David Gwydion
• Partridge Martin Graham
• Young Christopher John

Classifications

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title

• B01J20/3204

  Inorganic carriers, supports or substrates · CPC title

• B01D53/64

  Heavy metals or compounds thereof, e.g. mercury · CPC title

• B01J20/18

  Synthetic zeolitic molecular sieves · CPC title

• B01J20/3028 Primary

  Granulating, agglomerating or aggregating · CPC title