Chemical lithiation of electrode active material

Patent metadata

Field	Value
Publication number	US-2018062168-A1
Application number	US-201715687610-A
Country	US
Kind code	A1
Filing date	Aug 28, 2017
Priority date	Aug 30, 2016
Publication date	Mar 1, 2018
Grant date	—

Abstract

A method for manufacturing a electrochemical energy storage system that includes at least one current collector and at least one electrode, including, for example, and anode, that includes at least one prelithiated electrode active material, includes reacting the electrode active material with an organolithium compound of formula Li—R for the lithiation, moiety R being selected from the group consisting of: a linear or branched, saturated or unsaturated, preferably saturated, aliphatic or heteroaliphatic hydrocarbon moiety having 5 to 12 carbon atoms, which can include at least one heteroatom selected from Si, S, N, and O; a cycloaliphatic or heterocycloaliphatic hydrocarbon moiety having 5 to 12 carbon atoms, which can include at least one heteroatom selected from Si, S, N, and O; and an aromatic or heteroaromatic hydrocarbon moiety having 5 to 9 carbon atoms, which can include at least one heteroatom selected from Si, S, N, and O.

First claim

What is claimed is:

1 . A method for manufacturing an electrochemical energy storage system that includes (1) an electrode that includes a pre-lithiated electrode active material and (2) a current collector, the method comprising:
(a) reacting an electrode active material with an organolithium compound of formula Li—R for a lithiation, wherein moiety R is selected from the group consisting of:
an aliphatic or heteroaliphatic hydrocarbon moiety having 5 to 12 carbon atoms;
a cycloaliphatic or heterocycloaliphatic hydrocarbon moiety having 5 to 12 carbon atoms; and
an aromatic or heteroaromatic hydrocarbon moiety having 5 to 9 carbon atoms.

2 . The method of claim 1 , wherein the hydrocarbon moiety is the aliphatic or heteroaliphatic hydrocarbon moiety.

3 . The method of claim 2 , wherein the hydrocarbon moiety is linear.

4 . The method of claim 2 , wherein the hydrocarbon moiety is branched.

5 . The method of claim 2 , wherein the hydrocarbon moiety is saturated.

6 . The method of claim 2 , wherein the hydrocarbon moiety is unsaturated.

7 . The method of claim 2 , wherein the hydrocarbon moiety includes at least one heteroatom selected from Si, S, N, and O.

8 . The method of claim 1 , wherein the hydrocarbon moiety is the cycloaliphatic or heterocycloaliphatic hydrocarbon moiety.

9 . The method of claim 8 , wherein the hydrocarbon moiety includes at least one heteroatom selected from Si, S, N, and O.

10 . The method of claim 1 , wherein the hydrocarbon moiety is the aromatic or heteroaromatic hydrocarbon moiety.

11 . The method of claim 10 , wherein the hydrocarbon moiety includes at least one heteroatom selected from Si, S, N, and O.

12 . The method of claim 1 , wherein the electrode is an anode.

13 . The method of claim 1 , wherein moiety R is selected from the group consisting of:
a linear or branched, saturated aliphatic hydrocarbon moiety having 5 to 9 carbon atoms; a linear or branched, saturated heteroaliphatic hydrocarbon moiety having 5 to 9 carbon atoms, and which includes at least one heteroatom selected from Si, S, N, and O; a cycloaliphatic saturated hydrocarbon moiety having 5 to 9 hydrocarbon atoms; a heterocycloaliphatic saturated hydrocarbon moiety having 5 to 9 hydrocarbon atoms hydrocarbon atoms, and which includes at least one heteroatom selected from Si, S, N, and O; a monocyclic aromatic hydrocarbon moiety having 5 to 9 carbon atoms; and a monocyclic heteroaromatic hydrocarbon moiety having 5 to 9 carbon atoms, and which includes at least one heteroatom selected from Si, S, N, and O.

14 . The method as recited of claim 1 , wherein moiety R selected from the group consisting of:
a pentyl moiety; a hexyl moiety; a heptyl moiety; an octyl moiety; a nonyl moiety; a decyl moiety; an undecyl moiety; a dodecyl moiety; a phenyl moiety; a benzyl moiety; a 2-thienyl moiety; a 3-thienyl moiety; a 2-furanyl moiety; a 3-furanyl moiety; and an R 1 3 SiCH 2 moiety, wherein R 1 is independently selected from a linear or branched, saturated or unsaturated hydrocarbon moiety having 1 to 6 carbon atoms.

15 . The method of claim 1 , wherein the electrode active material is a silicon-containing electrode active material.

16 . The method of claim 1 , wherein the electrode active material includes elemental silicon, a silicon-containing alloy, or a silicon-containing composite.

17 . The method of claim 1 , further comprising:
(b) removing an unreacted organolithium compound of formula Li—R, a resulting by-product R—H, and a solvent to form the pre-lithiated electrode active material; (c) applying the electrode including the pre-lithiated electrode active material to at least a portion of a surface of the current collector; (d) providing at least one electrochemical cell that includes the electrode, an additional electrode, and a separator between the electrodes; (e) inserting the two electrodes and the separator as a system into a housing; and (f) filling the system with an electrolyte composition in such a way that the electrodes and the separator are completely surrounded by the electrolyte composition.

18 . The method of claim 1 , further comprising:
(b) applying the electrode active material to at least a portion of a surface of the current collector prior to step (a), wherein the electrode active material applied to the current collector is reacted with the organolithium compound of formula Li—R; (c) removing unreacted organolithium compound of formula Li—R, a resulting by-product R—H, and a solvent in order to form the electrode containing the pre-lithiated electrode active material; (d) providing at least one electrochemical cell that includes the electrode, an additional electrode, and a separator that is situated between the electrodes; (e) inserting the two electrodes and the separator as a system into a housing; and (f) filling the system with an electrolyte composition in such a way that the electrodes and the separator are completely surrounded by the electrolyte composition.

19 . The method of claim 1 , wherein the method includes the following method steps:
(b) applying the electrode including the electrode active material to at least a portion of a surface of the current collector; (c) providing at least one electrochemical cell that includes the electrode, an additional electrode, and a separator that is situated between the electrodes; (d) inserting the electrodes and the separator as a system into a housing, wherein the organolithium compound of formula Li—R is filled into the housing after step (d) to thereby cause the reacting of step (a); (e) removing unreacted organolithium compound of formula Li—R, a resulting by-product R—H, and solvent; and (f) filling the housing with an electrolyte composition so that the electrodes and the separator are completely surrounded by the electrolyte composition.

20 . The method of claim 1 , wherein the electrochemical energy storage system is a lithium-containing battery or a lithium-containing hybrid supercapacitor.

21 . The method of claim 1 , wherein the electrochemical energy storage system is a lithium-ion battery.

22 . An electrochemical energy storage system ( 2 ) comprising:
an electrode that includes (a) a current collector and (b) an electrode active material that is pre-lithiated by a reaction with an organolithium compound of formula Li—R for a lithiation, wherein moiety R is selected from the group consisting of:
an aliphatic or heteroaliphatic hydrocarbon moiety having 5 to 12 carbon atoms;
a cycloaliphatic or heterocycloaliphatic hydrocarbon moiety having 5 to 12 carbon atoms; and
an aromatic or heteroaromatic hydrocarbon moiety having 5 to 9 carbon atoms.

Assignees

• Bosch Gmbh Robert

Inventors

• Gonser Andreas

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/1395 Primary

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/386 Primary

  Silicon or alloys based on silicon · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M2004/027

  Negative electrodes · CPC title