Preventing migration of liquid electrolyte out of a fuel cell

Patent metadata

Field	Value
Publication number	US-2018053954-A1
Application number	US-201715802599-A
Country	US
Kind code	A1
Filing date	Nov 3, 2017
Priority date	Apr 20, 2009
Publication date	Feb 22, 2018
Grant date	—

Abstract

An illustrative example cell stack assembly includes a plurality of fuel cells that each include a cathode electrode, an anode electrode and a matrix for holding a liquid acid electrolyte. The electrodes have lateral outside edges that are generally coplanar. A plurality of separator plates are respectively between the cathode electrode of one of the fuel cells and the anode electrode of an adjacent one of the fuel cells. The separator plates have lateral outside edges that are generally coplanar with the lateral outside edges of the electrodes. A plurality of barriers along at least one of the lateral outside edges of respective ones of the separator plates extend outwardly beyond the lateral outside edges of the electrodes and separator plates. The barriers inhibit acid migration between one of the electrodes on one side of the barrier and one of the electrodes on an opposite side of the barrier.

First claim

1 . A cell stack assembly, comprising:
a plurality of fuel cells, each fuel cell including a cathode electrode, an anode electrode and a matrix for holding a liquid acid electrolyte between the cathode electrode and the anode electrode, the cathode electrodes having lateral outside edges, the anode electrodes having lateral outside edges, the lateral outside edges of the electrodes being generally coplanar; a plurality of separator plates respectively between the cathode electrode of one of the fuel cells and the anode electrode of an adjacent one of the fuel cells, the separator plates having lateral outside edges that are generally coplanar with the lateral outside edges of the electrodes; and a plurality of barriers respectively situated along at least one of the lateral outside edges of respective ones of the separator plates, the barriers respectively extending outwardly beyond the lateral outside edges of the electrodes and separator plates, the barriers respectively inhibiting acid migration between one of the electrodes on one side of the barrier and one of the electrodes on an opposite side of the barrier.

2 . The cell stack assembly of claim 1 , wherein
the lateral outside edges of the separator plates respectively have a first thickness; the barriers have a second thickness; and the first thickness is greater than the second thickness.

3 . The cell stack assembly of claim 1 , wherein
the separator plates respectively have a step recess along the at least one of the lateral outside edges; a portion of the separator plates that includes the step recess has a first thickness; another portion of the separator plates that does not include the step recess has a second thickness; the second thickness is greater than the first thickness; the step recesses extend laterally inward on the separator plates; respective first portions of the barriers are received in the step recesses; and respective second portions of the barriers extend laterally outward beyond the at least one of the lateral outside edges.

4 . The cell stack assembly of claim 3 , wherein
the barriers respectively have a third thickness; and the third thickness is approximately equal to a difference between the first thickness and the second thickness.

5 . The cell stack assembly of claim 1 , wherein the barriers respectively extend away from the lateral outside edges between about 0.127 mm and about 2.0 mm (about 2 mils and about 80 mils).

6 . The cell stack assembly of claim 1 , wherein the barriers respectively comprise a film that is between about 0.051 mm and 0.127 mm (about 2 mils and about 5 mils).

7 . The cell stack assembly of claim 1 , comprising
a step within the respective separator plates that extends from the outside lateral edge all or a portion of a distance between the outside lateral edge and a flow channel; and the barriers are respectively secured partially within the step.

8 . The cell stack assembly of claim 7 , wherein the step has a depth that is about equal to a thickness of the barrier.

9 . The cell stack assembly of claim 1 , wherein each barrier comprises a hydrophobic polymer film distinct from a material of the separator plate.

10 . The cell stack assembly of claim 9 , wherein said polymer film is selected from polytetrafluroethylene, fluorinated ethylene propylene and polyfluoroaloxy copolymer resin.

11 . The cell stack assembly of claim 1 , wherein the barrier is bonded to a step within the separator plate.

12 . The cell stack assembly of claim 1 , wherein the barrier is bonded to the step with a fluoroelastomer.

13 . The cell stack assembly of claim 12 , wherein the fluoroelastomer has a fluorine content greater than about 68% by weight.

14 . The cell stack assembly of claim 1 , wherein said liquid acid electrolyte is selected from phosphoric acid and fluoroborate acid.

Assignees

• Doosan Fuel Cell America Inc

Inventors

• Kanuri Sridhar V
• Breault Richard D
• Tenneti Kishore Kumar
• Cipollini Ned E

Classifications

• H01M8/0228

  in the form of layered or coated products · CPC title

• H01M8/242 Primary

  comprising framed electrodes or intermediary frame-like gaskets (H01M8/2425, H01M8/244 take precedence) · CPC title

• H01M8/086 Primary

  Phosphoric acid fuel cells [PAFC] · CPC title

• H01M8/0284

  Organic resins; Organic polymers · CPC title

• H01M8/02

  Details (electrodes H01M4/86 - H01M4/98) · CPC title