Positive electrode active material and preparation method thereof, positive electrode plate, secondary battery, battery module, battery pack, and electric apparatus
US-2024429384-A1 · Dec 26, 2024 · US
US2018048016A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2018048016-A1 |
| Application number | US-201615556277-A |
| Country | US |
| Kind code | A1 |
| Filing date | Mar 4, 2016 |
| Priority date | Mar 6, 2015 |
| Publication date | Feb 15, 2018 |
| Grant date | — |
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The present invention provides a battery, including a cathode, a anode, and an electrolyte solution. The cathode includes a cathode active substance and a cathode current collector. The electrolyte solution includes first metal ions and second metal ions. In a charging/discharging process, the first metal ions can be reversibly deintercalated-intercalated at the cathode, the second metal ions can be reduced and deposited as a second metal at the anode, and the second metal can be oxidized and dissolved back to the second metal ions. The anode includes a anode active substance and a anode current collector. A lead-containing substance is provided on a surface of the anode active substance and/or in the electrolyte solution. A mass ratio of lead in the lead-containing substance to the battery is not greater than 1000 ppm. The present invention can effectively improve a dendrite problem at a anode of a battery, prolong the cycle life of the battery, and improve the electrochemical performance and safety performance of the battery.
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What is claimed is: 1 . A battery, comprising a cathode, a anode, and an electrolyte solution, wherein the cathode comprises a cathode active substance and a cathode current collector; the electrolyte solution comprises first metal ions and second metal ions; in a charging/discharging process, the first metal ions are reversibly deintercalated-intercalated at the cathode, the second metal ions are reduced and deposited as a second metal at the anode, and the second metal is oxidized and dissolved back to the second metal ions; the anode comprises a anode active substance and a anode current collector; a composite cathode material, where the composite cathode material includes a cathode active substance and a coating layer, the cathode active substance includes a lithium ion intercalation/deintercalation compound, and the coating layer is at least one of metallic lead, lead monoxide, or lead tetroxide. 2 . The battery according to claim 1 , wherein a surface of the cathode active substance is provided with a coating layer, and the coating layer is metallic lead and/or lead oxide. 3 . The battery according to claim 1 , wherein the battery comprises an additive of a bismuth compound, and the bismuth compound is added to the anode and/or the electrolyte solution. 4 . The battery according to claim 1 , wherein the anode active substance comprises zinc, and the anode current collector comprises brass foil. 5 . The battery according to claim 1 , wherein the cathode current collector comprises a nylon mesh carrier and graphite foil that is coated on the nylon mesh carrier. 6 . The battery according to claim 1 , wherein the first metal ions comprise lithium ions, sodium ions, or magnesium ions, and the second metal ions comprise zinc ions. 7 . The battery according to claim 1 , wherein a lead-containing substance is provided on a surface of the anode active substance and/or in the electrolyte solution; and a mass ratio of lead in the lead-containing substance to the battery is not greater than 1000 ppm. 8 . The battery according to claim 7 , wherein the lead-containing substance on the surface of the anode active substance comprises a lead metal. 9 . The battery according to 7, wherein the lead-containing substance in the electrolyte solution comprises lead ions. 10 . The battery according to claim 7 , wherein a mass ratio of lead in the lead-containing substance in the electrolyte solution to the electrolyte solution is not less than 10 ppm. 11 . The battery according to claim 7 , wherein the lead-containing substance comprises at least one of metallic lead, lead sulfate, or lead oxide 12 . The battery according to claim 1 , wherein the cathode active substance comprises a modified lithium manganese oxide material, and the modified lithium manganese oxide material meets a general formula Li 1+x Mn y M z O k , wherein M is selected from Pb, −1≦x≦0.5, 1≦y≦2.5, 0<z≦0.1, and 3≦k≦6. 13 . The battery according to claim 12 , wherein a mass percentage of lead in the metallic lead and/or the lead oxide in the cathode active substance is in the range of 0.001%-10%. 14 . A battery pack, comprising several batteries according claim 1 . 15 . An uninterruptible power supply, comprising the battery according to claim 1 .
acting upon multiple batteries simultaneously or sequentially · CPC title
Semi-lead accumulators, i.e. accumulators in which only one electrode contains lead · CPC title
as layered products · CPC title
of elements or alloys · CPC title
Alloys based on zinc · CPC title
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