Method for preparing electrolyte for redox flow battery including organic molecule as additive and redox flow battery using the same

Patent metadata

Field	Value
Publication number	US-2018013163-A1
Application number	US-201715612399-A
Country	US
Kind code	A1
Filing date	Jun 2, 2017
Priority date	Jul 5, 2016
Publication date	Jan 11, 2018
Grant date	—

Abstract

Disclosed is an electrolyte for a redox flow battery including at least one additive selected from the group consisting of a taurine compound and an amino acid compound. Thus, it is possible to provide an electrolyte for a redox flow battery which may have high solubility of active materials, be stable at high temperature or high pH, and show excellent electrochemical properties. In addition, when the electrolyte for a redox flow battery includes a nitrogen (N)-containing organic molecule having high redox activity as an active material, it is possible to realize a high-efficiency demetallized redox flow battery capable of solving the problems of dendrite formation or irreversible precipitation fundamentally.

First claim

What is claimed is:

1 . An electrolyte for a redox flow battery comprising at least one additive selected from the group consisting of a taurine compound and an amino acid compound.

2 . The electrolyte for a redox flow battery according to claim 1 , wherein the taurine compound is a C0-C10 hydrocarbon compound having an amine group and a sulfonic acid group as functional groups.

3 . The electrolyte for a redox flow battery according to claim 1 , wherein the amino acid compound comprises at least one of an amino acid and an amino acid derivative.

4 . The electrolyte for a redox flow battery according to claim 3 , wherein the amino acid is α-amino acid, β-amino acid, or γ-amino acid and the amino acid derivative is a derivative of the amino acid which has a substituent containing at least one element selected from the group consisting of nitrogen (N) and sulfur (S) at the side chain thereof through ionic bonding or covalent bonding.

5 . The electrolyte for a redox flow battery according to claim 3 , wherein the amino acid derivative is a hydrocarbon compound having an imidazole ring or a heteroaromatic ring including a C5-C9 aromatic ring, at least two carbon (C) atoms of which are substituted with at least one element selected from the group consisting of nitrogen (N), oxygen (O) and sulfur (S).

6 . The electrolyte for a redox flow battery according to claim 5 , wherein the heteroaromatic ring is pyrazolium, oxazolium, triazolium, thiazolium or pyrimidine.

7 . The electrolyte for a redox flow battery according to claim 1 , wherein the electrolyte is an electrolyte for a redox flow battery based on an aqueous or non-aqueous solvent and further comprising a metal ion active material or an organic molecule active material, and the additive forms a complex ion with the metal ion active material or organic molecule active material.

8 . The electrolyte for a redox flow battery according to claim 7 , wherein the organic molecule active material comprises at least one selected from the group consisting of flavin, a flavin derivative, a vitamin, a vitamin derivative, purine, a purine derivative, nicotinamide and phthalocyanine.

9 . The electrolyte for a redox flow battery according to claim 8 , wherein the flavin derivative is a compound of riboflavin, pteridine, isoalloxazine, alloxazine, lumichrome or lumazine, or the compound to which at least one heteroatom selected from the group consisting of carbon (C), nitrogen (N), oxygen (O) and sulfur (S) is attached through ionic bonding or covalent bonding.

10 . The electrolyte for a redox flow battery according to claim 8 , wherein the vitamin is vitamin A, vitamin B, vitamin C, vitamin D, vitamin E or vitamin K, and the vitamin derivative is the vitamin to which at least one heteroatom selected from the group consisting of carbon (C), nitrogen (N), oxygen (O) and sulfur (S) is attached through ionic bonding or covalent bonding.

11 . The electrolyte for a redox flow battery according to claim 8 , wherein the purine derivative is a purine to which at least one heteroatom selected from the group consisting of carbon (C), nitrogen (N), oxygen (O) and sulfur (S) is attached through ionic bonding or covalent bonding.

12 . A method for preparing the electrolyte for a redox flow battery as defined in claim 1 , comprising:
forming a first electrolyte in which an active material is dissolved; and adding at least one additive selected from the group consisting of a taurine compound and an amino acid compound to the first electrolyte to form a second electrolyte.

13 . The method for preparing the electrolyte for a redox flow battery according to claim 12 , further comprising:
supplying the second electrolyte to a redox flow battery; and charging or discharging the redox flow battery.

14 . The method for preparing the electrolyte for a redox flow battery according to claim 13 , wherein the redox flow battery is a unit cell, a half cell, a cell having asymmetric electrodes, a large-scale cell or a stack cell with large capacity.

15 . The method for preparing the electrolyte for a redox flow battery according to claim 12 , wherein the additive forms a complex ion with the active material in the second electrolyte.

Assignees

• Korea Inst Sci & Tech

Inventors

• Hwang Jinyeon
• Ha Heung Yong

Classifications

• H01M6/04

  Cells with aqueous electrolyte · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M8/20

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title

• H01M10/0564

  the electrolyte being constituted of organic materials only · CPC title

• H01M2/38

  Electricity · mapped topic