Fire-protection composition and use of the same

Patent metadata

Field	Value
Publication number	US-2017355862-A1
Application number	US-201515532720-A
Country	US
Kind code	A1
Filing date	Nov 30, 2015
Priority date	Dec 5, 2014
Publication date	Dec 14, 2017
Grant date	—

Abstract

A fire-protection composition is described that contains a polyurea-based binder. By virtue of the inventive composition, coatings having the layer thickness necessary for the respective fire-resistance duration can be applied simply and quickly, wherein the layer thickness can be reduced to a minimum and nevertheless a good fire-protection effect can be achieved. The inventive composition is suitable in particular for fire protection, especially as a coating of cables and cable runs, in order to increase the fire resistance duration.

First claim

1 . A fire-protection composition, comprising:
an ingredient A, which contains an isocyanate compound, an ingredient B, which contains a reactive component capable of reacting with an isocyanate compound and which is selected from the group consisting of compounds with at least two amino groups, wherein the amino groups, independently of one another, are primary and/or secondary amino groups, and an ingredient C, which contains an ablatively acting fire-protection additive.

2 . The composition according to claim 1 , wherein the reactive component capable of reacting with the isocyanate compound is selected from the group consisting of polyamines, polyether polyamines, polyaspartic acid esters and a mixture thereof.

3 . The composition according to claim 2 , wherein the reactive component capable of reacting with the isocyanate compound is a polyether polyamine, which is selected from among the group consisting of compounds of general formula (I)

in which
R is a group of an initiator for oxalkylation with 2 to 12 carbon atoms and 2 to 8 groups containing an active hydrogen atom,
T represents hydrogen or a C 1 -C 4 alkyl group,
V and U, independently of one another, are hydrogen or T,
n is a value between 0 and 100,
m is a whole number between 2 and 8, wherein m corresponds to the number of groups that contain an active hydrogen atom and that were initially contained in the initiator for oxalkylation.

4 . The composition according to claim 2 , wherein the reactive component capable of reacting with the isocyanate compound is a polyaspartic acid ester of general formula (VII),

in which
R 1 and R 2 may be identical or different and stand for organic groups that are inert toward isocyanate groups,
R 3 and R 4 may be identical or different and stand for hydrogen or organic groups that are inert toward isocyanate groups,
X stands for an n-valent organic group that is inert toward isocyanate groups, and
n stands for a whole number of at least 2.

5 . The composition according to claim 4 , wherein, in formula (VII), R 1 and R 2 , independently of one another, stand for a methyl or ethyl group and R 3 and R 4 each stand for hydrogen.

6 . The composition according to claim 4 , wherein, in formula (VII), X stands for a group which is obtained by removal of primary amino groups from an aliphatic polyamine.

7 . The composition according to claim 1 , wherein ingredient B further contains a polyol compound.

8 . The composition according to claim 7 , wherein the polyol compound is selected from the group consisting of polyester polyols, polyether polyols, hydroxylated polyurethanes, and/or alkanes with at least two hydroxyl groups each per molecule and a mixture thereof.

9 . The composition according to claim 1 , wherein the isocyanate compound comprises an aliphatic or aromatic skeleton and at least two isocyanate groups or a mixture thereof.

10 . The composition according to claim 1 , wherein the quantitative ratios of ingredients A and B are chosen such that the equivalent ratio of isocyanate groups of the isocyanate compound to groups, capable of reacting with the isocyanate group, of the reactive component capable of reacting with the isocyanate compound lies between 0.3 and 1.7.

11 . The composition according to claim 7 , which further contains a catalyst for the reaction between the isocyanate compound and the reactive component capable of reacting with the isocyanate compound and/or the polyol.

12 . The composition according to claim 1 , wherein the at least one ablatively acting fire-protection additive is selected from the group consisting of LiNO 3 .3H 2 O, Na 2 CO 3 .H 2 O (thermonatrite), Na 2 CO 3 .7H 2 O, Na 2 CO 3 .10H 2 O (soda), Na 2 Ca(CO 3 ) 2 .2H 2 O (pirssonite), Na 2 Ca(CO 3 ) 2 .5H 2 O (gaylussite), Na(HCO 3 )Na 2 CO 3 .2H 2 O (trona), Na 2 S 2 O 3 .5H 2 O, Na 2 O 3 Si.5H 2 O, KF.2H 2 O, CaBr 2 .2H 2 O, CaBr 2 .6H 2 O, CaSO 4 .2H 2 O (gypsum), Ca(SO 4 ). ½H 2 O (bassanite), Ba(OH) 2 .8H 2 O, Ni(NO 3 ) 2 .6H 2 O, Ni(NO 3 ) 2 .4H 2 O, Ni(NO 3 ) 2 2H 2 O, Zn(NO 3 ) 2 .4H 2 O, Zn(NO 3 ) 2 .6H 2 O, (ZnO) 2 (B 2 O 3 ) 2 .3H 2 O, Mg(NO 3 ) 2 .6H 2 O (U.S. Pat. No. 5,985,013 A), MgSO 4 .7H 2 O (EP1069172A), Mg(OH) 2 , Al(OH) 3 , Al(OH) 3 .3H 2 O, AlOOH (boehmite), Al 2 [SO 4 ] 3 .nH 2 O with n=14-18 (U.S. Pat. No. 4,462,831 B), possibly optionally mixed with AlNH 4 (SO 4 ) 2 .12H 2 O (U.S. Pat. No. 5,104,917 A), KA1(SO 4 ) 2 .12H 2 O (EP1069172A), CaO.Al 2 O 3 .10H 2 O (nesquehonite), MgCO 3 .3II 2 O (wermlandite), Ca 2 Mg 14 (Al,Fe) 4 CO 3 (OII) 42 .29II 2 O (thaumasite), Ca 3 Si(OH) 6 (SO 4 )(CO 3 ).12H 2 O (artinite), Mg 2 (OH) 2 CO 3 .H 2 O (ettringite), 3CaO.Al 2 O 3 .3CaSO 4 .32H 2 O (hydromagnesite), Mg 5 (OH) 2 (CO 3 ) 4 .4H 2 O (hydrocalumite), Ca 4 Al 2 (OH) 14 .6H 2 O (hydrotalcite), Mg 6 Al 2 (OH) 16 CO 3 .4H 2 O alumohydrocalcite, CaAl 2 (OH) 4 (CO 3 ) 2 .H 2 O scarbroite, Al 14 (CO 3 ) 3 (OH) 36 hydrogarnet, 3CaO.Al 2 O 3 .6H 2 O dawsonite, NaAl(OH)CO 3 , water-containing zeolites, vermiculite, colemanite, perlite, mica, alkali silicates, borax, modified carbons, modified graphites, silicas and mixtures thereof.

13 . The composition according to claim 1 , wherein the composition further contains organic and/or inorganic aggregates and/or a further additive.

14 . The composition according to one of the claim, which is packaged as a two-component or multi-component system.

15 . A coating, comprising:
the composition according to one of claim 1 .

16 . A construction element, comprising:
the coating according to claim 15 .

17 . The construction element according to claim 16 which is a nonmetallic construction element.

18 . The coating according to claim 15 which is a fire-protection coating.

19 . A cured object, obtained by curing the composition according to claim 1 .

20 . A cable, cable bundle, cable run, cable duct, line or soft partition, comprising: the coating according to claim 18 .

Assignees

• Hilti Ag

Inventors

• Marauska Juliane
• Lang Martin
• Simon Sebastian

Classifications

• C08G18/246

  containing also tin-carbon bonds · CPC title

• C09D5/18 Primary

  Fireproof paints {including high temperature resistant paints} · CPC title

• C09K21/02

  Inorganic materials · CPC title

• C08K2003/265

  Calcium, strontium or barium carbonate · CPC title

• C08K3/016

  Flame-proofing or flame-retarding additives · CPC title