Quenched-tempered high-strength steel with yield strength of 900 mpa to 1000 mpa grade, and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-2017349966-A1
Application number	US-201515536601-A
Country	US
Kind code	A1
Filing date	Dec 8, 2015
Priority date	Dec 19, 2014
Publication date	Dec 7, 2017
Grant date	—

Abstract

A quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade and a method of producing the same, with the components and amounts thereof by weight percentage being: C: 0.16-0.20%, Si: 0.10-0.30%, Mn: 0.80-1.60%, Cr: 0.20-0.70%, Mo: 0.10-0.45%, Ni: 0.10-0.50%, Nb: 0.010-0.030%, Ti: 0.010-0.030%, V: 0.010-0.050%, B: 0.0005-0.0030%, Al: 0.02-0.06%, Ca: 0.001-0.004%, N: 0.002-0.005%, P≦0.020%, S≦0.010%, O≦0.008%, and the balance of Fe and unavoidable impurities, and Ceq 0.51-0.60%, Ceq=C+Mn/6+(Cr+Mo+V)/5+(Ni+Cu)/15; 3.7≦Ti/N≦7.0; 1.0≦Ca/S≦3.0; 0.8%≦Mo+0.8Ni+0.4Cr+6V≦1.3%. By using a process of controlling rolling, controlling cooling, and off-line quenching+tempering, a steel sheet produced according to the disclosure has a yield strength of 900-1080 MPa, a tensile strength of 950-1200 MPa, an elongation >10%, and an impact energy at −40° C. >40 J.

First claim

What is claimed is:

1 . A quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade, consisting of the following components by weight percentage: C: 0.16-0.20%, Si: 0.10-0.30%, Mn: 0.80-1.60%, Cr: 0.20-0.70%, Mo: 0.10-0.45%, Ni: 0.10-0.50%, Nb: 0.010-0.030%, Ti: 0.010-0.030%, V: 0.010-0.050%, B: 0.0005-0.0030%, Al: 0.02-0.06%, Ca: 0.001-0.004%, N: 0.002-0.005%, P≦0.020%, S≦0.010%, O≦0.008%, the balance of Fe and unavoidable impurities, wherein the above elements meet the following relationships:
Ceq 0.51-0.60%, Ceq=C+Mn/ 6+( Cr+Mo+V )/5+( Ni+Cu )/15;
0.8%≦ Mo+ 0.8 Ni+ 0.4 Cr+ 6 V≦ 1.3%; 3.7≦ Ti/N≦ 7.0; 1.0≦ Ca/S≦ 3.0.

2 . The quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade according to claim 1 , wherein the quenched-tempered high-strength steel has a microstructure of tempered martensite.

3 . The quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade according to claim 1 , wherein the quenched-tempered high-strength steel has a yield strength of 900-1080 MPa, a tensile strength of 950-1200 MPa, an elongation >10%, and an impact energy at −40° C. >40 J.

4 . A method of producing a quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade, comprising the following steps:
1) Smelting and casting
smelting a composition as described below in a converter or electrical furnace, refining, and casting to a cast blank, wherein the composition consists of the following components by weight percentage: C: 0.16-0.20%, Si: 0.10-0.30%, Mn: 0.80-1.60%, Cr: 0.20-0.70%, Mo: 0.10-0.45%, Ni: 0.10-0.50%, Nb: 0.010-0.030%, Ti: 0.010-0.030%, V: 0.010-0.050%, B: 0.0005-0.0030%, Al: 0.02-0.06%, Ca: 0.001-0.004%, N: 0.002-0.005%, P≦0.020%, S≦0.010%, O≦0.008%, the balance of Fe and unavoidable impurities, wherein the above elements meet the following relationships:
Ceq 0.51-0.60%, Ceq=C+Mn/ 6+( Cr+Mo+V )/5+( Ni+Cu )/15;
0.8%≦ Mo+ 0.8 Ni+ 0.4 Cr+ 6 V≦ 1.3%; 3.7≦ Ti/N≦ 7.0; 1.0≦ Ca/S≦ 3.0;

2) Heating
heating the cast blank at 1150-1270° C. in a furnace, wherein, when the temperature of the core of the cast blank arrives at the temperature of the furnace, the temperature is held, and the holding time is >1.5 h;
3) Rolling
rolling the cast blank to a target thickness by single-stand reciprocating rolling or multi-stand hot continuous rolling, wherein a rolling reduction rate at a final rolling path is >15%; a final rolling temperature is 820-920° C., and the final rolling temperature Tf meets: Ar 3 <Tf<Tnr, wherein Ar 3 is a temperature at which hypo-eutectoid steel austenite begins to convert to ferrite, and Tnr is non-recrystallization critical temperature:
Ar 3 =901−325 C− 92 Mn− 126 Cr− 67 Ni− 149 Mo;

Tnr= 887+464 C +(6445 Nb− 644sqrt( Nb ))+(732 V− 230sqrt( V ))+890 Ti+ 363 Al− 357 Si;

4) Cooling
coiling a rolled member at a temperature in the range of 480-Bs° C. after hot rolling, followed by air cooling to room temperature; wherein
Bs= 630−45 Mn− 40 V− 35 Si− 30 Cr− 25 Mo− 20 Ni;

5) Heat treatment
quenching at a quenching heating temperature of Ac 3 +(30-80°) C, wherein Ac 3 is a temperature at which transformation of austenite is over:
Ac 3=955−350 C− 25 Mn+ 51 Si+ 106 Nb+ 100 Ti+ 68 Al− 11 Cr− 33 Ni− 16 Cu+ 67 Mo;

 when a core of a steel sheet arrives at a temperature of the furnace, the temperature is held for a holding time of 5-40 min, so as to obtain a full martensitic structure, wherein Ms is a temperature at which transformation of martensite begins:
Ms= 539−423 C− 30.4 Mn− 17.7 Ni− 12.1 Cr− 11.0 Si− 7.0 Mo;

wherein a quenching cooling speed V>e (5.3-2.53C-0.16Si—0.82Mn-0.95Cr-1.87Mo-160B) ° C./s;
 tempering at a tempering temperature of 400-550° C.; when the temperature of the core of the steel sheet arrives at the temperature of the furnace, the temperature is held for a holding time of 20-180 min, so as to obtain a quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade.

5 . The method of producing a quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade according to claim 4 , wherein a high-strength steel sheet obtained by said method has a microstructure of tempered martensite.

6 . The method of producing a quenched-tempered high-strength steel having a yield strength of 900-1000 MPa grade according to claim 4 , wherein a high-strength steel sheet obtained by said method has a yield strength of 900-1080 MPa, a tensile strength of 950-1200 MPa, an elongation >10%, and an impact energy at −40° C. >40 J.

Assignees

• Baoshan Iron & Steel

Inventors

• Yang Ana
• Liu Gang
• Wang Wei
• Yang Xiaozhen

Classifications

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• C21D6/008

  containing Si · CPC title

• C21D1/18

  Hardening (C21D1/02 takes precedence); Quenching with or without subsequent tempering (quenching devices C21D1/62) · CPC title

• C21D6/005

  containing Mn · CPC title

• C21D6/004

  containing Cr and Ni · CPC title