Plasticizer for halogen-based resin

Patent metadata

Field	Value
Publication number	US-2017349727-A1
Application number	US-201515536042-A
Country	US
Kind code	A1
Filing date	Nov 11, 2015
Priority date	Dec 18, 2014
Publication date	Dec 7, 2017
Grant date	—

Abstract

The present invention relates to [1] a plasticizer for a halogen-based resin including a condensate obtainable by an esterification reaction between a furan dicarboxylic acid compound and an aliphatic alcohol having 4 to 22 carbon atoms, in which the aliphatic alcohol includes a saturated aliphatic alcohol and an unsaturated aliphatic alcohol, and a content of the unsaturated aliphatic alcohol in the aliphatic alcohol is not more than 25% by mass; and [2] a halogen-based resin composition including the aforementioned plasticizer. The plasticizer has a plasticization performance for a halogen-based resin at a level identical to or higher than that of a phthalate-based plasticizer, and exhibits excellent effects of improving compatibility, heat resistance and cold resistance.

First claim

1 . A plasticizer for a halogen-based resin comprising a condensate obtainable by an esterification reaction between a furan dicarboxylic acid compound and an aliphatic alcohol (A) having not less than 4 and not more than 22 carbon atoms, in which the aliphatic alcohol (A) comprises a saturated aliphatic alcohol (a1) and an unsaturated aliphatic alcohol (a2), and a content of the unsaturated aliphatic alcohol (a2) in the aliphatic alcohol (A) is not more than 25% by mass.

2 . The plasticizer for a halogen-based resin according to claim 1 , wherein an average number of carbon atoms in the aliphatic alcohol (A) is not less than 6 and not more than 18.

3 . The plasticizer for a halogen-based resin according to claim 1 , wherein the aliphatic alcohol (A) is a liner aliphatic monovalent alcohol.

4 . The plasticizer for a halogen-based resin according to claim 1 , wherein the aliphatic alcohol (A) comprises a saturated linear aliphatic monovalent alcohol in an amount of not less than 60 mol %.

5 . The plasticizer for a halogen-based resin according to claim 1 , wherein the unsaturated aliphatic alcohol (a2) is an unsaturated aliphatic alcohol having not less than 14 and not more than 22 carbon atoms.

6 . The plasticizer for a halogen-based resin according to claim 1 , wherein the unsaturated aliphatic alcohol (a2) is oleyl alcohol.

7 . The plasticizer for a halogen-based resin according to claim 1 , wherein the condensate is in the form of a mixture comprising a furan dicarboxylic acid diester represented by the following general formula (1):

wherein R 1 and R 2 are each independently an aliphatic hydrocarbon group having not less than 4 and not more than 22 carbon atoms.

8 . The plasticizer for a halogen-based resin according to claim 1 , wherein the halogen-based resin is at least one resin selected from the group consisting of a vinyl chloride-based resin, polyvinylidene chloride and a chloroprene rubber.

9 . A halogen-based resin composition comprising the plasticizer according to claim 1 .

10 . The halogen-based resin composition according to claim 9 , wherein a content of the plasticizer in the composition is not less than 0.01 part by mass and not more than 200 parts by mass on the basis of 100 parts by mass of the halogen-based resin.

11 . A process for producing a halogen-based resin composition, comprising the step of compounding not less than 0.01 part by mass and not more than 200 parts by mass of the plasticizer according to claim 1 with 100 parts by mass of a halogen-based resin.

12 . A process for producing a plasticizer for a halogen-based resin according to claim 1 , comprising a step of esterifying a furan dicarboxylic acid compound with an aliphatic alcohol (A) having not less than 4 and not more than 22 carbon atoms, in which the aliphatic alcohol (A) comprises a saturated aliphatic alcohol (a1) and an unsaturated aliphatic alcohol (a2), and a content of the unsaturated aliphatic alcohol (a2) in the aliphatic alcohol (A) is not more than 25% by mass.

Assignees

• Kao Corp

Inventors

• Oshiro Kojun
• Tsuchihashi Masaaki

Classifications

• C08L11/00

  Compositions of homopolymers or copolymers of chloroprene · CPC title

• C08L27/00

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers · CPC title

• C07D307/68

  Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen · CPC title

• C08K5/12 Primary

  of cyclic polycarboxylic acids · CPC title

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title