Method for forming catalytic nanocoating

Patent metadata

Field	Value
Publication number	US-2017348683-A1
Application number	US-201515541205-A
Country	US
Kind code	A1
Filing date	Dec 8, 2015
Priority date	Dec 31, 2014
Publication date	Dec 7, 2017
Grant date	—

Abstract

Provided is a method for forming catalytic nanocoating on a metal surface. The method comprises pretreating the metal surface by means of heat treatment at 500-800° C., forming a metaloxide support, and depositing catalytic nanosized metal and/or metaloxide particles on the metaloxide support and coating the metal surface with catalytic nanosized metal and/or metaloxide particles. Further, the invention relates to a catalyst and a use.

First claim

1 . A method for forming a catalytic nanocoating on a metal surface, wherein the method comprises
pretreating the metal surface by means of heat treatment at 500-800° C., forming a metaloxide support, and depositing catalytic nanosized metal and/or metaloxide particles on the metaloxide support and coating the metal surface with catalytic nanosized metal and/or metaloxide particles.

2 . The method according to claim 1 , wherein the metal surface is heat-treated by oxidizing.

3 . The method according to claim 1 , wherein the metaloxide support is formed by washcoating on the metal surface, and catalytic nanosized metal and/or metaloxide particles are deposited by means of flame spray pyrolysis (FSP) method on the metal surface which has been coated with the metaloxide support.

4 . The method according to claim 3 , wherein the metal surface is washcoated with a metaloxide based slurry.

5 . The method according to claim 3 , wherein the washcoating is carried out by spraying or dip-coating.

6 . The method according to claim 3 , wherein the metaloxide support formed by washcoating is calcined at 400-800° C.

7 . The method according to claim 1 , wherein nanoparticles of the metaloxide support are formed by means of a flame spray pyrolysis (FSP) method, catalytic nanosized metal and/or metaloxide particles are formed by means of chemical vapour synthesis (CVS) and deposited on the surface of the nanoparticles of the metaloxide support, and the metal surface is coated with catalytic nanosized metal and/or metaloxide particles.

8 . The method according to claim 1 , wherein the metaloxide support comprises Al 2 O 3 , MgO, TiO 2 , other metaloxide or their combination.

9 . The method according to claim 1 , wherein catalytic nanosized metal and/or metaloxide particles comprises metal selected from the group Co, Ni, Mo, Zr, Ti, Hf, noble metal, other suitable metal and their combinations.

10 . The method according to claim 1 , wherein a distance between the metal surface of the metal object and the flame is adjusted in connection with the flame spray pyrolysis (FSP).

11 . A catalyst, wherein the catalyst comprises a catalytic nanocoating on the metal surface, and the catalytic nanocoating has been formed onto the metal surface by the method of claim 1 .

12 . A catalyst according to claim 11 , wherein the catalyst is used in catalytic reactors, in self-cleaning surfaces, in production of biomass derived chemicals, in production of transportation fuels, in FT-synthesis, in reformers for fuel cell applications, in gas treatment units for syngas applications or in aqueous phase reformers for biorefineries.

13 . A use of the method of claim 1 , wherein the method is used to form a catalytic nanocoating in reactors, such as catalytic reactors reformers of fuel cell applications and aqueous phase reformers for biorefinery, and in processes, such as production of biomass derived chemicals, production of transportation fuels, FT-synthesis and gas treatment unit for syngas applications and production of self-cleaning surfaces, and their combinations.

Assignees

• Teknologian Tutkimuskeskus Vtt Oy

Inventors

• Simell Pekka
• Kihlman Johanna
• Reinikainen Matti
• Jokiniemi Jorma
• LÄHDE Anna

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J35/0013

  Operations & Transport · mapped topic

• B01J35/023

  Operations & Transport · mapped topic

• B01J37/0232

  by pulverisation · CPC title

• B01J37/0217

  Pretreatment of the substrate before coating · CPC title