Electrode, electrode producing method, and electrochemical device

Patent metadata

Field	Value
Publication number	US-2017338483-A1
Application number	US-201515535838-A
Country	US
Kind code	A1
Filing date	Dec 10, 2015
Priority date	Feb 6, 2015
Publication date	Nov 23, 2017
Grant date	—

Abstract

An electrode includes at least magnesium, carbon, oxygen, sulfur, and halogen. The electrode also has a surface exhibiting a single peak derived from magnesium in the range of 40 eV to 60 eV.

First claim

1 . An electrode comprising at least magnesium, carbon, oxygen, sulfur, and halogen and having a surface exhibiting a single peak derived from magnesium in a range of 40 eV to 60 eV.

2 . The electrode according to claim 1 , which exhibits, over a region from the surface to a depth of 200 nm, a single peak derived from magnesium in a range of 40 eV to 60 eV.

3 . The electrode according to claim 1 , wherein an oxidized state of magnesium is substantially constant from the surface to a depth of 200 nm.

4 . The electrode according to claim 1 , further comprising a collector and an active material layer provided on the collector, wherein the active material layer includes at least magnesium, carbon, oxygen, sulfur, and halogen and exhibits, over a depth from one to another surface of the active material layer, a single peak derived from magnesium in a range of 40 eV to 60 eV.

5 . The electrode according to claim 1 , further comprising a collector and an active material layer provided on the collector, wherein the active material layer includes at least magnesium, carbon, oxygen, sulfur, and halogen, and an oxidized state of magnesium is substantially constant from one to another surface of the active material layer.

6 . An electrochemical device comprising a positive electrode, a negative electrode, and an electrolyte, wherein the negative electrode includes at least magnesium, carbon, oxygen, sulfur, and halogen and has a surface exhibiting a single peak derived from magnesium in a range of 40 eV to 60 eV.

7 . An electrode producing method comprising performing electrochemical plating using an electrolytic solution including a sulfone and a magnesium salt.

8 . The electrode producing method according to claim 7 , wherein the sulfone comprises at least one selected from the group consisting of ethyl isopropyl sulfone, ethyl n-propyl sulfone, ethyl sec-butyl sulfone, and di-n-propyl sulfone.

9 . The electrode producing method according to claim 7 , wherein the magnesium salt comprises at least one selected from the group consisting of magnesium chloride, magnesium bromide, magnesium iodide, magnesium perchlorate, magnesium tetrafluoroborate, magnesium hexafluorophosphate, magnesium hexafluoroarsenate, magnesium perfluoroalkylsulfonate, and magnesium perfluoroalkylsulfonylimidate.

10 . An electrode obtainable by electrochemical plating using an electrolytic solution comprising a sulfone and a magnesium salt.

Assignees

• Sony Corp

Inventors

• Nakayama Yuri
• Matsumoto Ryuhei
• Kawasaki Hideki

Classifications

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01G11/04

  Hybrid capacitors · CPC title

• H01M4/46 Primary

  Alloys based on magnesium or aluminium · CPC title

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title

• C01F5/00

  Compounds of magnesium · CPC title