Power storage device and manufacturing method thereof

Patent metadata

Field	Value
Publication number	US-2017331144-A1
Application number	US-201715586354-A
Country	US
Kind code	A1
Filing date	May 4, 2017
Priority date	May 12, 2016
Publication date	Nov 16, 2017
Grant date	—

Abstract

In initial charge and discharge, decomposition products or a gas is generated, degrading a battery. At least one of solvents (e.g., ethylene carbonate) used for an electrolytic solution is brought into contact with a positive electrode and a negative electrode and then charge is performed to some degree, and after that, a different solvent or electrolytic solution (e.g., ethyl methyl carbonate or vinylene carbonate) was added to adjust the electrolytic solution and then charge is performed. Through this process, stable coating films are formed in initial charge and discharge, which stably inhibits a side reaction between the electrolytic solution and an active material.

First claim

What is claimed is:

1 . A method for manufacturing a power storage device, comprising:
putting a positive electrode and a negative electrode in a container with an opening; injecting a first electrolytic solution containing an electrolyte, a first solvent, a second solvent, and a third solvent from the opening; sealing the opening and then performing charge under a first condition; performing a first step of removing a gas from the container; further mixing the third solvent into the first electrolytic solution; performing charge under a second condition; performing a second step of removing a gas from the container; performing charge under a third condition; and performing discharge and then repeating charge and discharge to obtain a power storage device containing a second electrolytic solution, wherein the first electrolytic solution contains the first solvent at more than 50 vol %, and wherein the second electrolytic solution contains the first solvent at 40 vol % or less.

2 . The method for manufacturing a power storage device, according to claim 1 , wherein the electrolyte is a lithium salt.

3 . The method for manufacturing a power storage device, according to claim 1 , wherein the first solvent content in the first electrolytic solution is determined by analyzing a power storage device that is fabricated in advance using a deuterated product of the first solvent and a deuterated product of the second solvent and subjected to initial charge and discharge so as to deteriorate.

4 . The method for manufacturing a power storage device, according to claim 1 , further comprising:
injecting vinylene carbonate into the first electrolytic solution after the first step of removing a gas from the container.

5 . The method for manufacturing a power storage device, according to claim 1 , wherein charge under the first condition, the second condition, or the third condition is performed with the container pressurized.

6 . The method for manufacturing a power storage device, according to claim 5 , wherein in the pressurization, higher pressure is applied to a region overlapping with the negative electrode and the positive electrode than to the other region.

7 . The method for manufacturing a power storage device, according to claim 1 , wherein the first solvent is ethylene carbonate.

8 . The method for manufacturing a power storage device, according to claim 1 , wherein the second solvent is diethyl carbonate.

9 . The method for manufacturing a power storage device, according to claim 1 , wherein the third solvent is ethyl methyl carbonate.

10 . A method for manufacturing a power storage device, comprising:
putting a positive electrode and a negative electrode in a container with an opening; injecting a first electrolytic solution containing an electrolyte, a first solvent, and a second solvent from the opening; sealing the opening and then performing charge under a first condition; mixing a third solvent into the first electrolytic solution; performing a first step of removing a gas from the container after mixing the third solvent into the first electrolytic solution; performing charge under a second condition; performing a keeping step; performing a second step of removing a gas from the container after performing the keeping step; performing charge under a third condition; and performing discharge and then repeating charge and discharge to obtain a power storage device containing a second electrolytic solution, wherein the first electrolytic solution contains the first solvent at more than 70 vol %, and wherein the second electrolytic solution contains the first solvent at 60 vol % or less.

11 . The method for manufacturing a power storage device, according to claim 10 , wherein the second electrolytic solution contains the first solvent at more than 40 vol %.

12 . The method for manufacturing a power storage device, according to claim 10 , wherein the electrolyte is a lithium salt.

13 . The method for manufacturing a power storage device, according to claim 10 , wherein the first solvent content in the first electrolytic solution is determined by analyzing a power storage device that is fabricated in advance using a deuterated product of the first solvent and a deuterated product of the second solvent and subjected to initial charge and discharge so as to deteriorate.

14 . The method for manufacturing a power storage device, according to claim 10 , further comprising:
injecting vinylene carbonate into the first electrolytic solution after the first step of removing a gas from the container.

15 . The method for manufacturing a power storage device, according to claim 10 , wherein charge under the first condition, the second condition, or the third condition is performed with the container pressurized.

16 . The method for manufacturing a power storage device, according to claim 15 , wherein in the pressurization, higher pressure is applied to a region overlapping with the negative electrode and the positive electrode than to the other region.

17 . The method for manufacturing a power storage device, according to claim 10 , wherein the first solvent is ethylene carbonate.

18 . The method for manufacturing a power storage device, according to claim 10 , wherein the second solvent is diethyl carbonate.

19 . The method for manufacturing a power storage device, according to claim 10 , wherein the third solvent is ethyl methyl carbonate.

Assignees

• Semiconductor Energy Lab

Inventors

• Oguni Teppei
• Goto Junya
• Nakagawa Ai

Classifications

• H01M10/446

  Initial charging measures · CPC title

• H01M10/058 Primary

  Construction or manufacture · CPC title

• H01M2300/004

  Three solvents · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title