Apparatus and method for making lithium iron phosphate

Patent metadata

Field	Value
Publication number	US-2017324078-A1
Application number	US-201715659625-A
Country	US
Kind code	A1
Filing date	Jul 26, 2017
Priority date	Jan 28, 2015
Publication date	Nov 9, 2017
Grant date	—

Abstract

An apparatus and a method for making lithium iron phosphate are disclosed. The apparatus comprises a raw material system to provide a raw material mixed solution of raw materials of a hydrothermal reaction or a solvothermal reaction; a tubular reaction device to make the raw material mixed solution in a plug flowing and reacting state to obtain a reacted material; and a kettle reaction device to make the reacted material in a complete mixing and reacting state to obtain a product. The method comprises providing a raw material mixed solution of raw materials of a hydrothermal reaction or a solvothermal reaction; making the raw material mixed solution in a plug flowing and reacting state to obtain a reacted material; and making the reacted material in a complete mixing and reacting state. The lithium iron phosphate can be continuously produced by the apparatus and method.

First claim

What is claimed is:

1 . An apparatus for making lithium iron phosphate, comprising:
a raw material system to provide a raw material mixed solution of a hydrothermal reaction or a solvothermal reaction; a tubular reaction device to make the raw material mixed solution in a plug flowing and reacting state to obtain a reacted material; and a kettle reaction device to make the reacted material in a complete mixing and reacting state to obtain a product.

2 . The apparatus of claim 1 , wherein the tubular reaction device comprises:
a continuous tubular reactor to make the raw material mixed solution in the plug flowing and reacting state; and a first heating device to heat the continuous tubular reactor.

3 . The apparatus of claim 2 , wherein the continuous tubular reactor is configured to make the raw material mixed solution in a plug flowing and reacting state at a predetermined temperature under a predetermined pressure for a first predetermined time to obtain the reacted material.

4 . The apparatus of claim 3 , wherein a length of the continuous tubular reactor is decided according to the first predetermined time and a flow rate of the raw material mixed solution in the continuous tubular reactor.

5 . The apparatus of claim 1 , wherein the product is lithium iron phosphate.

6 . The apparatus of claim 1 , wherein the kettle reaction device comprises:
a continuously stirred tank reactor to receiving the reacted material; a stirrer to stir the reacted material; and a second heating device to heat the continuously stirred tank reactor.

7 . The apparatus of claim 6 , wherein an outlet is defined on a side wall of the continuously stirred tank reactor to output the product by a centrifugal force generated from a revolution of the stirrer.

8 . The apparatus of claim 1 , wherein a first pressure inside the tubular reaction device is substantially the same as a second pressure inside the kettle reaction device.

9 . The apparatus of claim 1 , further comprising a discharge system to receive the product, the discharge system comprises at least two kettle containers respectively connected to the kettle reaction device, the at least two kettle containers are configured to alternately receive the product.

10 . The apparatus of claim 9 , wherein the at least two kettle containers are respectively connected to the kettle reaction device through inlet valves, of which one of the inlet valves is opened, and another of inlet valves is closed.

11 . The apparatus of claim 9 , further comprising a pressure regulating system, wherein the pressure regulating system is configured to introducing a second solvent into the kettle container communicated with the tubular reaction device and the kettle reaction device, a first pressure inside the tubular reaction device and a second pressure inside the kettle reaction device are kept substantially the same as a predetermined pressure by evaporation of the second solvent.

12 . The apparatus of claim 1 , further comprising a material transport system to transport the raw material mixed solution from the raw materials system to the tubular reaction device.

13 . The apparatus of claim 12 , the material transport system comprises a delivery pump located between the raw material system and the tubular reaction device, and the delivery pump comprises a frequency converter to control a flow rate of the raw material mixed solution.

14 . The apparatus of claim 1 , the raw material system comprises a mixing container and a first stirrer located in the mixing container.

15 . A method for making lithium iron phosphate, comprising steps of:
providing a raw material mixed solution of a hydrothermal reaction or a solvothermal reaction; making the raw material mixed solution in a plug flowing and reacting state to obtain a reacted material; and making the reacted material in a complete mixing and reacting state.

16 . The method of claim 15 , wherein the raw material mixed solution is kept in the plug flowing and reacting state and the complete mixing and reacting state at a temperature in a range from about 0° C. to about 250° C. under a pressure in a range from about 0 MPa to about 2 MPa.

17 . The method of claim 15 , wherein the raw material mixed solution is kept in the plug flowing and reacting state for a time equal to or no longer than 4 hours.

18 . The method of claim 15 , wherein the reacted material is kept in the complete mixing and reacting state for a time in a range from about 1 hour to about 10 hours.

19 . The method of claim 15 , wherein raw material mixed solution is for synthesizing lithium iron phosphate through the hydrothermal reaction or the solvothermal reaction.

20 . The method of claim 15 , wherein a pressure of a reaction system of the hydrothermal reaction or the solvothermal reaction is regulated by controlling an evaporation of a solvent added to the reaction system.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua
• Jiangsu Huadong Inst Of Li-Ion Battery Co L Td

Inventors

• Wang Li
• He xiang-ming
• Luo Jing
• Xu cheng-hao
• Li Jian-Jun
• Lv Dan
• Shang yu-ming
• Zhang hong-sheng

Classifications

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/0438 Primary

  by electrochemical processing (electroless electrochemical plating C23C18/54) · CPC title

• B01F7/00241

  Operations & Transport · mapped topic

• H01M4/765

  Tubular type or pencil type electrodes; tubular or multitubular sheaths or covers of insulating material for said tubular-type electrodes · CPC title

• C01B25/45 Primary

  containing plural metal, or metal and ammonium · CPC title