Method for recovering high-purity scandium

Patent metadata

Field	Value
Publication number	US-2017321301-A1
Application number	US-201515526862-A
Country	US
Kind code	A1
Filing date	Nov 25, 2015
Priority date	Nov 26, 2014
Publication date	Nov 9, 2017
Grant date	—

Abstract

Provided is a method for recovering scandium, with which it is possible to easily and efficiently recover high-purity scandium from nickel oxide ores. This method for recovering scandium involves passing a solution containing scandium through an ion exchange resin, then subjecting the eluant eluted from the ion exchange resin to solvent extraction and separating the extraction residual liquid and the extraction agent after extraction, then performing an oxalation process on the extraction residual liquid to obtain a scandium oxalate precipitate, and roasting the precipitate to obtain scandium oxide, wherein the method is characterized in that an amine-based extraction agent is used as the extraction agent for solvent extraction.

First claim

1 . A method of recovering scandium, comprising: passing a scandium-containing solution through an ion exchange resin; then subjecting an eluent eluted from the ion exchange resin to solvent extraction to allow separation into a raffinate liquid and an post-extraction extractant; then adding oxalic acid to the raffinate liquid to obtain a precipitate of scandium oxalate; and roasting the precipitate to obtain scandium oxide,
wherein an amine-based extractant is used as an extractant for the solvent extraction.

2 . The method of recovering scandium according to claim 1 , comprising: performing scrubbing, the scrubbing comprising mixing a washing liquid with the extractant after the solvent extraction to separate scandium contained in the extractant into the washing liquid, the washing liquid comprising a sulfuric acid solution having a concentration between 1.0 mol/L or more and 3.0 mol/L or less; and recovering scandium from the washing liquid after the scrubbing.

3 . The method of recovering scandium according to claim 1 , comprising adding a carbonate salt to the extractant after the solvent extraction to perform backward extraction, thereby obtaining a post-backward extraction extractant and a backward extraction liquid.

4 . The method of recovering scandium according to claim 3 , wherein the post-backward extraction extractant is repeatedly used as the extractant for the solvent extraction.

5 . The method of recovering scandium according to claim 1 , wherein the scandium-containing solution to be subjected to the solvent extraction is a post-sulfuration liquid obtained by hydrometallurgy of nickel oxide ore, the hydrometallurgy comprising:
a leaching step of leaching the nickel oxide ore with sulfuric acid under high temperature and high pressure to obtain a leachate; a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid; and a sulfuration step of adding a sulfurizing agent to the post-neutralization liquid to obtain nickel sulfide and a post-sulfuration liquid.

6 . The method of recovering scandium according to claim 1 , comprising: adding a neutralizing agent to the eluent eluted from the ion exchange resin to adjust pH to the range of 5 to 6; performing solid-liquid separation to obtain a neutralized precipitate and a neutralized filtrate; and subjecting a re-dissolved liquid obtained by adding an acid to the neutralized precipitate to the solvent extraction.

7 . The method of recovering scandium according to claim 1 , comprising: adding a neutralizing agent to the eluent eluted from the ion exchange resin to adjust pH to the range of 3.5 to 4.5; performing solid-liquid separation to obtain a primary neutralized precipitate and a primary neutralized filtrate; then further adding the neutralizing agent to the primary neutralized filtrate to adjust pH to the range of 5.5 to 6.5; performing solid-liquid separation to obtain a secondary neutralized precipitate and a secondary neutralized filtrate; subjecting a re-dissolved liquid obtained by adding an acid to the secondary neutralized precipitate to the solid-liquid separation.

8 . The method of recovering scandium according to claim 1 , comprising: upon performing the oxalate-formation treatment of the raffinate liquid to obtain the precipitate of scandium oxalate, adjusting the pH of the raffinate liquid to the range of between −0.5 or more and less than 1; adding the solution after the pH adjustment to an oxalic acid-containing solution to generate a precipitate of scandium oxalate.

9 . The method of recovering scandium according to claim 2 , wherein the scandium-containing solution to be subjected to the solvent extraction is a post-sulfuration liquid obtained by hydrometallurgy of nickel oxide ore, the hydrometallurgy comprising:
a leaching step of leaching the nickel oxide ore with sulfuric acid under high temperature and high pressure to obtain a leachate; a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid; and a sulfuration step of adding a sulfurizing agent to the post-neutralization liquid to obtain nickel sulfide and a post-sulfuration liquid.

10 . The method of recovering scandium according to claim 3 , wherein the scandium-containing solution to be subjected to the solvent extraction is a post-sulfuration liquid obtained by hydrometallurgy of nickel oxide ore, the hydrometallurgy comprising:
a leaching step of leaching the nickel oxide ore with sulfuric acid under high temperature and high pressure to obtain a leachate; a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid; and a sulfuration step of adding a sulfurizing agent to the post-neutralization liquid to obtain nickel sulfide and a post-sulfuration liquid.

11 . The method of recovering scandium according to claim 4 , wherein the scandium-containing solution to be subjected to the solvent extraction is a post-sulfuration liquid obtained by hydrometallurgy of nickel oxide ore, the hydrometallurgy comprising:
a leaching step of leaching the nickel oxide ore with sulfuric acid under high temperature and high pressure to obtain a leachate; a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid; and a sulfuration step of adding a sulfurizing agent to the post-neutralization liquid to obtain nickel sulfide and a post-sulfuration liquid.

12 . The method of recovering scandium according to claim 2 , comprising: adding a neutralizing agent to the eluent eluted from the ion exchange resin to adjust pH to the range of 5 to 6; performing solid-liquid separation to obtain a neutralized precipitate and a neutralized filtrate; and subjecting a re-dissolved liquid obtained by adding an acid to the neutralized precipitate to the solvent extraction.

13 . The method of recovering scandium according to claim 3 , comprising: adding a neutralizing agent to the eluent eluted from the ion exchange resin to adjust pH to the range of 5 to 6; performing solid-liquid separation to obtain a neutralized precipitate and a neutralized filtrate; and subjecting a re-dissolved liquid obtained by adding an acid to the neutralized precipitate to the solvent extraction.

14 . The method of recovering scandium according to claim 4 , comprising: adding a neutralizing agent to the eluent eluted from the ion exchange resin to adjust pH to the range of 5 to 6; performing solid-liquid separation to obtain a neutralized precipitate and a neutralized filtrate; and subjecting a re-dissolved liquid obtained by adding an acid to the neutralized precipitate to the solvent extraction.

15 . The method of recovering scandium according to claim 2 , comprising: adding a neutralizing agent to the eluent eluted from the ion exchange resin to adjust pH to the range of 3.5 to 4.5; performing solid-liquid separation to obtain a primary neutralized precipitate and a primary neutralized filtrate; then further adding the neutralizing agent to the primary neutralized filtrate to adjust pH to the range of 5.5 to 6.5; performing solid-liquid separation to obtain a secondary neutralized precipitate and a secondary neutralized filtrate; subjecting a re-dissolved liquid obtained by adding an acid to the secondary neutralized precipitate to the solid-liquid separation.

16 . The method of recovering scandium ac

Assignees

• Sumitomo Metal Mining Co

Inventors

• Matsuoka Itsumi
• Nagai Hidemasa
• Kudo Keiji
• Matsumoto Shin-Ya
• Higaki Tatsuya
• Ozaki Yoshitomo
• Shouji Hirofumi
• Kobayashi Hiroshi

Classifications

• C07C51/412

  by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• C01P2006/80

  Compositional purity · CPC title

• C22B3/42

  by ion-exchange extraction · CPC title

• C22B1/02

  Roasting processes (C22B1/16 takes precedence) · CPC title