Gas barrier coatings
US-9221956-B2 · Dec 29, 2015 · US
US2017321069A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017321069-A1 |
| Application number | US-201615144856-A |
| Country | US |
| Kind code | A1 |
| Filing date | May 3, 2016 |
| Priority date | May 3, 2016 |
| Publication date | Nov 9, 2017 |
| Grant date | — |
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An article comprises a substrate, a coating disposed on a surface of the substrate. The coating comprises a carbon composite dispersed in one or more of the following: a polymer matrix; a metallic matrix; or a ceramic matrix. The carbon composite comprises carbon and a binder containing one or more of the following: SiO 2 ; Si; B; B 2 O 3 ; a filler metal; or an alloy of the filler metal.
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What is claimed is: 1 . An article comprising a substrate, a coating disposed on a surface of the substrate, the coating comprising a carbon composite dispersed in one or more of the following: a polymer matrix; a metallic matrix; or a ceramic matrix, wherein the carbon composite comprises carbon and a binder containing one or more of the following: SiO 2 ; Si; B; B 2 O 3 ; a filler metal; or an alloy of the filler metal, and the filler metal comprises one or more of the following: aluminum; copper; titanium; nickel; tungsten; chromium; iron; manganese; zirconium; hafnium; vanadium; niobium; molybdenum; tin; bismuth; antimony; lead; cadmium; or selenium. 2 . The article of claim 1 , wherein the carbon composite is present in an amount of about 0.1 wt. % to about 75 wt. % based on the total weight of the coating. 3 . The article of claim 1 , wherein the coating has a thickness of about 5 μm to about 10 mm. 4 . The article of claim 1 , wherein the carbon composite comprises at least two carbon microstructures; and a binding phase disposed between the at least two carbon microstructures. 5 . The article of claim 4 , wherein the binding phase comprises a binder layer and an interface layer bonding one of the at least two carbon microstructures to the binder layer, wherein the interface layer comprises one or more of the following: a C-metal bond; a C—B bond; a C—Si bond; a C—O—Si bond; a C—O-metal bond; or a metal carbon solution. 6 . The article of claim 1 , wherein the carbon comprises graphite. 7 . The article of claim 1 , wherein the coating comprises a metallic matrix including one or more of the following: Ni; Cu; Ag; Au; Sn; Zn; Fe; In; W; Ti; Co; Al; Mg; Cr; or Mo; or an alloy thereof. 8 . The article of claim 1 , wherein the coating comprises a ceramic matrix comprising one or more of the following: an oxide-based ceramic; nitride-based ceramic; carbide-based ceramic; boride-based ceramic; or silicide-based ceramic. 9 . The article of claim 1 , wherein the polymer matrix comprises a thermoplastic polymer, an elastomer, or a combination thereof. 10 . The article of claim 1 , further comprising a binding layer disposed between the coating and the substrate. 11 . The article of claim 1 , wherein the substrate comprises one or more of the following: a metal; a polymer; or ceramics. 12 . The article of claim 1 , wherein the article is a coated bearing, a coated pipeline, a coated valve, a coated piston, or a coated shaft. 13 . A method of coating a substrate, the method comprising: depositing a matrix material and a carbon composite on a surface of a substrate, the carbon composite comprising carbon and a binder; the binder comprising one or more of the following: SiO 2 ; Si; B; B 2 O 3 ; a metal; or an alloy of the metal; and the metal comprising one or more of the following: aluminum; copper; titanium; nickel; tungsten; chromium; iron; manganese; zirconium; hafnium; vanadium; niobium; molybdenum; tin; bismuth; antimony; lead; cadmium; or selenium. 14 . The method of claim 13 , further comprising combining a matrix material with a carbon composite to form a coating composition. 15 . The method of claim 14 , wherein depositing a matrix material and a carbon composite comprises disposing the coating composition on a surface of the substrate. 16 . The method of claim 15 , wherein the matrix material comprises a material or a precursor for the polymer matrix, and combing the matrix material with the carbon composite comprises dispersing the carbon composite in a dispersion of the matrix material. 17 . The method of claim 16 , wherein disposing the coating composition comprises one or more of the following: spray coating; brushing; screen casting; blade casting; drop casting; spin coating; or molding. 18 . The method of claim 15 , wherein the matrix material comprises a material or a precursor for the metallic or ceramic matrix, and the matrix material is combined with a carbon composite and an organic compound to form a coating composition in the form of a paste. 19 . The method of claim 18 , wherein disposing the coating composition comprises brushing, immersion dipping, or molding. 20 . The method of claim 13 , wherein disposing the matrix material and the carbon composite is an all-solid state coating process. 21 . The method of claim 14 , wherein disposing the matrix material and the carbon composite comprises thermal spraying the matrix material and the carbon composite simultaneously on the surface of the substrate. 22 . The method of claim 14 , wherein the coating comprises a metallic matrix, and depositing the matrix material and the carbon composite is conducted via electroplating.
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