Solvothermal apparatus for making lithium iron phosphate

Patent metadata

Field	Value
Publication number	US-2017320738-A1
Application number	US-201715658401-A
Country	US
Kind code	A1
Filing date	Jul 25, 2017
Priority date	Jan 27, 2015
Publication date	Nov 9, 2017
Grant date	—

Abstract

A solvothermal apparatus for making lithium iron phosphate is disclosed. The solvothermal apparatus comprises a manufacture unit and a recycle unit. The manufacture unit comprises a feeding device, a reaction device, a filtering device, and a countercurrent washing device which are sequentially connected to each other. The recycle unit comprises a flash evaporation device and a solid-liquid separation device connected to the flash evaporation device. A waste liquid produced by the manufacture unit is recycled by the recycle unit.

First claim

What is claimed is:

1 . A solvothermal apparatus for making lithium iron phosphate, comprising a manufacture unit and a recycle unit, wherein the manufacture unit comprises:
a feeding device to provide a precursor solution for synthesizing lithium iron phosphate; a reaction device in which the precursor solution is subjected a solvothermal reaction to obtain a first suspension liquid; a filtering device to filter the first suspension liquid to obtain a wet lithium iron phosphate material and a filtrate, wherein the filtrate comprises an organic solvent, water, and a byproduct of the solvothermal reaction; and a countercurrent washing device to countercurrently wash the wet lithium iron phosphate material; the recycle unit comprises: a flash evaporation device to flash evaporate the filtrate to respectively obtain distilled water and a suspension liquid, wherein the suspension liquid comprises the organic solvent and the byproduct; and a solid-liquid separation device to separate the organic solvent from the byproduct in the suspension liquid; wherein the distilled water obtained by the flash evaporation device and one part of the organic solvent obtained by the solid-liquid separation device are supplied into the countercurrent washing device to countercurrent wash the wet lithium iron phosphate material, and another part of the organic solvent obtained by the solid-liquid separation device is supplied into the feeding device.

2 . The solvothermal apparatus of claim 1 , wherein a washing liquid output from the countercurrent washing device feeds into the flash evaporation device.

3 . The solvothermal apparatus of claim 2 , wherein
a filtering inlet, a filtering solid outlet, and a filtering liquid outlet are defined on the filtering device; a washing solid inlet, a washing solid outlet, a washing liquid inlet, and a washing liquid outlet are defined on the countercurrent washing device; an evaporation liquid inlet, a first evaporation liquid outlet, and a second evaporation liquid outlet are defined on the flash evaporation device; a separation inlet, a separation solid outlet, and a separation liquid outlet are defined on the solid-liquid separating device; the filtering inlet is connected to the reaction device, the filtering solid outlet is connected to the washing solid inlet, the filtering liquid outlet and the washing liquid outlet are connected to the evaporation liquid inlet, the first evaporation liquid outlet and the separation liquid outlet are connected to the washing liquid inlet, the second evaporation liquid outlet is connected to the separation inlet, and the separation liquid outlet is further connected to the feeding device.

4 . The solvothermal apparatus of claim 1 , wherein
the feeding device comprises an organic solvent container, a first mixing tank, a second mixing tank, and a third mixing tank; the first mixing tank and the second mixing tank are respectively connected to the organic solvent container and are simultaneously connected to the third mixing tank, and the third mixing tank is connected to the reaction device.

5 . The solvothermal apparatus of claim 1 , wherein the reaction device comprises a solvothermal reactor and a metering device, the metering device is configured to control an amount of the precursor solution introduced into the solvothermal reactor.

6 . The solvothermal apparatus of claim 1 , wherein the filtering device is a continuous precision membrane filter.

7 . The solvothermal apparatus of claim 3 , wherein the countercurrent washing device comprises a first washing sink, a second washing sink, and a third washing sink which are sequentially connected to each other.

8 . The solvothermal apparatus of claim 7 , wherein the washing solid inlet and the washing liquid outlet are defined on the first washing sink, and the washing solid outlet and the washing liquid inlet are defined on the third washing sink.

9 . The solvothermal apparatus of claim 3 , wherein the flash evaporation device comprises a pre-heater and a vapor-liquid separator connected to the pre-heater.

10 . The solvothermal apparatus of claim 9 , wherein the evaporation liquid inlet is defined on the pre-heater, the first evaporation liquid outlet and the second evaporation liquid outlet are defined on the vapor-liquid separator.

11 . The solvothermal apparatus of claim 1 , wherein the solid-liquid separation device is a centrifugal separator.

12 . The solvothermal apparatus of claim 1 , wherein the feeding device, the reaction device, the filtering device, and the countercurrent washing device are sequentially connected to each other.

13 . The solvothermal apparatus of claim 1 , further comprising a plurality of delivery pumps configured to transport liquid materials from one device to another device.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua
• Jiangsu Huadong Inst Of Li-Ion Battery Co L Td

Inventors

• He xiang-ming
• Xu cheng-hao
• Wang Li
• Li Jian-Jun
• Shang yu-ming
• Gao Jian
• Wang yao-wu

Classifications

• C01B25/45 Primary

  containing plural metal, or metal and ammonium · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/5805 Primary

  Phosphides · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title