Anode composite material, method for making the same, and lithium ion battery

Patent metadata

Field	Value
Publication number	US-2017288261-A1
Application number	US-201715627240-A
Country	US
Kind code	A1
Filing date	Jun 19, 2017
Priority date	Dec 19, 2014
Publication date	Oct 5, 2017
Grant date	—

Abstract

An anode composite material includes an anode active material and a polymer composited with the anode active material. The polymer is obtained by polymerizing a maleimide type monomer with an organic diamine type compound. The maleimide type monomer is a maleimide monomer, a bismaleimide monomer, a multimaleimide monomer, a maleimide type derivative monomer, or combinations thereof. A method for forming the anode composite material and a lithium ion battery are also disclosed.

First claim

What is claimed is:

1 . An anode composite material comprising:
an anode active material; and a polymer composited with the anode active material, wherein the polymer is obtained by polymerizing a maleimide type monomer with an organic diamine type compound, the maleimide type monomer is selected from the group consisting of a maleimide monomer, a bismaleimide monomer, a multimaleimide monomer, a maleimide type derivative monomer, and combinations thereof; and the organic diamine type compound is represented by formula III or formula IV:

wherein R 3 is a bivalent organic substituent and R 4 is another bivalent organic substituent.

2 . The anode composite material of claim 1 , wherein R 3 is selected from the group consisting of —(CH 2 ) n —, —CH 2 —O—CH 2 —, —CH(NH)—(CH 2 ) n —, phenylene, diphenylene, substituted phenylene, substituted diphenylene, and bivalent alicyclic group, R 4 is selected from the group consisting of —(CH 2 ) n —, —O—, —S—, —S—S—, —CH 2 —O—CH 2 —, —CH(NH)—(CH 2 ) n —, and —CH(CN)(CH 2 ) n —, and n=1 to 12.

3 . The anode composite material of claim 1 , wherein the organic diamine type compound is selected from the group consisting of ethylenediamine, phenylenediamine, methylenedianiline, oxydianiline, and combinations thereof.

4 . The anode composite material of claim 1 , wherein the maleimide monomer is represented by formula I:

wherein R 1 is a monovalent organic substitute.

5 . The anode composite material of claim 4 , wherein R 1 is selected from the group consisting of —R, —RNH 2 R, —C(O)CH 3 , —CH 2 OCH 3 , —CH 2 S(O)CH 3 , —C 6 H 5 , —C 6 H 4 C 6 H 5 , —CH 2 (C 6 H 4 )CH 3 , and monovalent alicyclic group; R is hydrocarbyl with 1 to 6 carbon atoms.

6 . The anode composite material of claim 1 , wherein the maleimide monomer is selected from the group consisting of N-phenyl-maleimide, N-(p-tolyl)-maleimide, N-(m-tolyl)-maleimide, N-(o-tolyl)-maleimide, N-cyclohexyl-maleimide, maleimide, maleimidephenol, maleimidebenzocyclobutene, dimethylphenyl-maleimide, N-methyl-maleimide, ethenyl-maleimide, thio-maleimide, ketone-maleimide, methylene-maleimide, maleimide-methyl-ether, maleimide-ethanediol, 4-maleimide-phenyl sulfone, and combinations thereof.

7 . The anode composite material of claim 1 , wherein the bismaleimide monomer is represented by formula II:

wherein R 2 is a bivalent organic substitute.

8 . The anode composite material of claim 7 , wherein R 2 is selected from the group consisting of —R—, —RNH 2 R—, —C(O)CH 2 —, —CH 2 OCH 2 —, —C(O), —O—, —O—O—, —S—, —S—S—, —S(O)—, —CH 2 S(O)CH 2 —, —(O)S(O)—, —CH 2 (C 6 H 4 )CH 2 —, —CH 2 (C 6 H 4 )(O)—, —R—Si(CH 3 ) 2 —O—Si(CH 3 ) 2 —R—, —C 6 H 4 —, —C 6 H 4 C 6 H 4 —, bivalent alicyclic group or —(C 6 H 4 )—R 5 —(C 6 H 4 )—; R 5 is —CH 2 —, —C(O)—, —C(CH 3 ) 2 , —O—, —O—O—, —S—, —S—S—, —S(O)—, and —(O)S(O)—; and R is hydrocarbyl with 1 to 6 carbon atoms.

9 . The anode composite material of claim 1 , wherein the bismaleimide monomer is selected from the group consisting of N,N′-bismaleimide-4,4′-diphenyl-methane, 1,1′-(methylene-di-4,1-phenylene)-bismaleimide, N,N′-(1,1′-diphenyl-4,4′-dimethylene)-bismaleimide, N,N′-(4-methyl-1,3-phenylene)-bismaleimide, 1,1′-(3,3′-dimethyl-1,1′-diphenyl-4,4′-dimethylene)-bismaleimide, N,N′-ethenyl-bismaleimide, N,N′-butenyl-bismaleimide, N,N′-(1,2-phenylene)-bismaleimide, N,N′-(1,3-phenylene)-bismaleimide, N,N′-thiodimaleimide, N,N′-dithiodimaleimide, N,N′-ketonedimaleimide, N,N′-methylene-bismaleimide, bismaleimidomethyl-ether, 1,2-bismaleimido-1,2-ethandiol, N,N′-4,4′-diphenyl-ether-bismaleimide, 4,4′-bismaleimido-diphenylsulfone, and combinations thereof.

10 . The anode composite material of claim 1 , wherein a molecular weight of the polymer is in a range from about 1000 to about 500000.

11 . The anode composite material of claim 1 , wherein a molar ratio of the maleimide type monomer to the organic diamine type compound is 1:10 to 10:1.

12 . The anode composite material of claim 1 , wherein a molar ratio of the maleimide type monomer to the organic diamine type compound is 1:2 to 4:1.

13 . The anode composite material of claim 1 , wherein a mass percent of the polymer in the anode composite material is in a range from about 0.1% to about 5%.

14 . The anode composite material of claim 1 , wherein the anode active material is selected from the group consisting of graphite, mesophase carbon micro beads, acetylene black, petroleum coke, carbon fibers, cracked polymers, carbon nanotubes, cracked carbon, and combinations thereof.

15 . A lithium ion battery comprising a cathode electrode, an anode electrode, a separator, and an electrolyte liquid, the cathode electrode comprises an anode composite material comprising:
an anode active material; and a polymer composited with the anode active material, wherein the polymer is obtained by polymerizing a maleimide type monomer with an organic diamine type compound, the maleimide type monomer is selected from the group consisting of a maleimide monomer, a bismaleimide monomer, a multimaleimide monomer, a maleimide type derivative monomer, and combinations thereof; and the organic diamine type compound is represented by formula III or formula IV:

wherein R 3 is a bivalent organic substituent and R 4 is another bivalent organic substituent.

16 . A method for making an anode composite material comprising:
polymerizing a maleimide type monomer with an organic diamine type compound to form a polymer; and compositing the polymer with an anode active material; wherein the maleimide type monomer is selected from the group consisting of a maleimide monomer, a bismaleimide monomer, a multimaleimide monomer, a maleimide type derivative monomer, and combinations thereof; and the organic diamine type compound is represented by formula III or formula IV:

wherein R 3 is a bivalent organic substituent and R 4 is another bivalent organic substituent.

17 . The method of claim 16 , wherein a molar ratio of the maleimide type monomer to the organic diamine type compound is 1:2 to 4:1.

18 . The method of claim 16 , further comprising:
dissolving the organic diamine type compound in an organic solvent to form a diamine solution; mixing the maleimide type monomer with another organic solvent to form a first mixture, and then preheating the first mixture to form a solution of the maleimide type monomer; further mixing the anode active material with the solution of the maleimide type monomer to form a second mixture; adding the diamine solution to the second mixture to directly synthesize the polymer on a surface of the anode active material.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• He xiang-ming
• Qian guan-nan
• Shang yu-ming
• Li Jian-Jun
• Wang Li
• Yang ju-ping
• Gao Jian
• Zhao Peng
• Wang yao-wu

Classifications

• H01M4/602

  Polymers · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/362

  Composites · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title