Composite binder, cathode electrode of lithium rechargeable battery using the same and method for making the same

Patent metadata

Field	Value
Publication number	US-2017263937-A1
Application number	US-201715603949-A
Country	US
Kind code	A1
Filing date	May 24, 2017
Priority date	Nov 25, 2014
Publication date	Sep 14, 2017
Grant date	—

Abstract

A composite binder includes an organic-inorganic hybrid polymer and a fluorinated binder uniformly mixed with each other. A repeating unit of the organic-inorganic hybrid polymer includes a silicon atom, a methacryloyloxy group, or an acryloyloxy group, and at least two alkoxy groups. The alkoxy groups and the methacryloyloxy group or the acryloyloxy group are respectively joined to the silicon atom. A method for making a cathode electrode and the cathode electrode are also disclosed.

First claim

What is claimed is:

1 . A composite binder comprising:
an organic-inorganic hybrid polymer, a repeating unit of the organic-inorganic hybrid polymer comprising a silicon atom, a methacryloyloxy group or an acryloyloxy group, and at least two alkoxy groups, the at least two alkoxy groups and the methacryloyloxy group or the acryloyloxy group are respectively joined to the silicon atom; and a fluorinated binder uniformly mixed with each other.

2 . The composite binder of claim 1 , wherein a number of the repeating units in the organic-inorganic hybrid polymer is in a range from about 40 to about 5000.

3 . The composite binder of claim 1 , wherein the organic-inorganic hybrid polymer is selected from the group consisting of poly-γ-(triethoxysilyl)propyl methacrylate, poly-γ-(trimethoxysilyl)propyl methacrylate, poly-γ-methacryloxypropylmethyldimethoxysilane, poly-(diethoxymethylsilyl)propyl methacrylate, poly-γ-acryloxypropyltriethoxysilane, poly-γ-acryloxypropyltrimethoxysilane, poly-γ-acryloxypropylmethyldimethoxysilane, poly-acryloxypropylmethyldiethoxysilane, poly-acryloxypropylmethyldimethoxysilane, and combinations thereof.

4 . The composite binder of claim 1 , wherein the fluorinated binder is selected from the group consisting of polyvinylidene fluoride, hexafluoropropylene, tetrafluoroethylene, trichlorofluoroethylene, and combinations thereof.

5 . The composite binder of claim 1 , wherein a mass ratio of the fluorinated binder to the organic-inorganic hybrid polymer is 1:20 to 10:1.

6 . The composite binder of claim 1 , wherein a mass ratio of the fluorinated binder to the organic-inorganic hybrid polymer is 1:5 to 10:1.

7 . The composite binder of claim 1 further comprising a third solvent, wherein the organic-inorganic hybrid polymer and the fluorinated binder are soluble in the third solvent to form a binder solution.

8 . A method for preparing a cathode electrode, the method comprising:
providing a composite binder and sulfur grains, the composite binder comprising:
an organic-inorganic hybrid polymer, a repeating unit of the organic-inorganic hybrid polymer comprising a silicon atom, a methacryloyloxy group, or an acryloyloxy group, and at least two alkoxy groups, the at least two alkoxy groups and the methacryloyloxy group or the acryloyloxy group are respectively joined to the silicon atom; and
a fluorinated binder uniformly mixed with each other;
uniformly mixing the composite binder and the sulfur grains to form a slurry; coating the slurry on a surface of a current collector to form a cathode electrode plate; and disposing the cathode electrode plate in an acidic environment or an alkaline environment to induce a condensation reaction of the organic-inorganic hybrid polymer in the composite binder.

9 . The method of claim 8 , wherein a mass percentage of the composite binder in the slurry is in a range from about 5% to about 20%.

10 . The method of claim 8 , wherein the uniformly mixing the composite binder and the sulfur grains is uniformly mixing the composite binder, a conducting agent, and the sulfur grains to form the slurry.

11 . The method of claim 8 , wherein the acidic environment is an acidic gas or an acidic liquid; the alkaline environment is an alkaline gas or an alkaline liquid.

12 . The method of claim 8 , wherein the alkaline environment is ammonia gas, ammonia water, or sodium carbonate solution.

13 . The method of claim 8 , wherein the condensation reaction forms a silicon-oxygen link consisted of alternatively joined silicon atoms and oxygen atoms.

14 . The method of claim 8 , wherein the condensation reaction forms a silicon-oxygen crosslinked network comprising a chemical group

wherein a and b are both in a range of 1 to 10000 and independent of each other.

15 . A cathode electrode, comprising:
a current collector; and an electrode material layer disposed on the surface of the current collector, the electrode material layer comprising a condensation product of an organic-inorganic hybrid polymer, the sulfur grains, and the fluorinated binder, wherein a repeating unit of the organic-inorganic hybrid polymer comprises a silicon atom, a methacryloyloxy group, or an acryloyloxy group, and at least two alkoxy groups, the alkoxy groups and the methacryloyloxy group or the acryloyloxy group are respectively joined to the silicon atom.

16 . The cathode electrode of claim 15 , wherein the condensation product comprises a silicon-oxygen link comprising alternatively joined silicon atoms and oxygen atoms.

17 . The cathode electrode of claim 15 , wherein the condensation reaction comprises a silicon-oxygen crosslinked network comprising a chemical group

wherein a and b are both in a range of 1 to 10000 and independent of each other.

Assignees

• Jiangsu Unionenergy Lithium Sulfur Battery Tech Co Ltd
• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua
• Tsinghua Inversity

Inventors

• Zhao Peng
• Wang Li
• He xiang-ming
• Li Jian-Jun
• Shang yu-ming
• Yang ju-ping
• Cao Jiang
• Zhang yu-feng
• Gao Jian
• Wang yao-wu

Classifications

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title