Lithium metal electrode, method for preparing the same, and lithium rechargeable battery using the same

Patent metadata

Field	Value
Publication number	US-2017263936-A1
Application number	US-201715603164-A
Country	US
Kind code	A1
Filing date	May 23, 2017
Priority date	Nov 25, 2014
Publication date	Sep 14, 2017
Grant date	—

Abstract

A lithium metal electrode includes a lithium metal plate and a protective layer coated on a surface of the lithium metal plate. The protective layer includes an organic-inorganic hybrid polymer comprising a repeating unit. The repeating unit includes a silicon atom, a methacryloyloxy group or an acryloyloxy group, and at least two alkoxy groups. The alkoxy groups and the methacryloyloxy group or the acryloyloxy group are respectively joined to the silicon atom. A method for preparing the lithium metal electrode and a lithium ion battery is also disclosed.

First claim

What is claimed is:

1 . A lithium metal electrode comprising:
a lithium metal plate; and a protective layer coated on a surface of the lithium metal plate, wherein the protective layer comprises an organic-inorganic hybrid polymer comprising a repeating unit, the repeating unit comprises a silicon atom, a methacryloyloxy group or an acryloyloxy group, and at least two alkoxy groups, the alkoxy groups and the methacryloyloxy group or the acryloyloxy group are respectively joined to the silicon atom.

2 . The lithium metal electrode of claim 1 , wherein an amount of the repeating unit in the organic-inorganic hybrid polymer is in a range from about 40 to about 5000.

3 . The lithium metal electrode of claim 1 , wherein the organic-inorganic hybrid polymer is selected from the group consisting of poly-γ-(triethoxysilyl)propyl methacrylate, poly-γ-(trimethoxysilyl)propyl methacrylate, poly-γ-methacryloxypropylmethyldimethoxysilane, poly-(diethoxymethylsilyl)propyl methacrylate, poly-γ-acryloxypropyltriethoxysilane, poly-γ-acryloxypropyltrimethoxysilane, poly-γ-acryloxypropylmethyldimethoxysilane, poly-acryloxypropylmethyldiethoxysilane, poly-acryloxypropylmethyldimethoxysilane, and combinations thereof.

4 . The lithium metal electrode of claim 1 , wherein the organic-inorganic hybrid polymer is a polymerization product of a silicon-oxygen organic monomer, and the silicon-oxygen organic monomer comprises —Si(OR 1 ) x (R 2 ) y , wherein x+y=3, x≧2, y≧0.

5 . The lithium metal electrode of claim 4 , wherein the R 2 is a hydrocarbon group or hydrogen, and the R 1 is an alkyl group.

6 . The lithium metal electrode of claim 4 , wherein the silicon-oxygen organic monomer is represented by

n is 0 or 1, and m is 1 to 5.

7 . A method for preparing a lithium metal electrode, the method comprising:
providing a lithium metal plate and an organic-inorganic hybrid polymer comprising a repeating unit, the repeating unit comprising a silicon atom, a methacryloyloxy group or an acryloyloxy group, and at least two alkoxy groups, and the alkoxy groups and the methacryloyloxy group or the acryloyloxy group being respectively joined to the silicon atom; and coating the organic-inorganic hybrid polymer on a surface of the lithium metal plate to form a protective layer.

8 . The method of claim 7 , further comprising:
polishing the surface of the lithium metal plate by using polyolefin or polyester to form a hydroxyl group.

9 . The method of claim 7 , wherein the organic-inorganic hybrid polymer is formed by:
providing a silicon-oxygen organic monomer; and polymerizing the silicon-oxygen organic monomer.

10 . The method of claim 9 , wherein the silicon-oxygen organic monomer comprises —Si(OR 1 ) x (R 2 ) y , wherein x+y=3, x≧2, and y≧0.

11 . The method of claim 10 , wherein the R 2 is a hydrocarbon group or hydrogen.

12 . The method of claim 9 , wherein the silicon-oxygen organic monomer comprises an organic group, the methacryloyloxy group or the acryloyloxy group is joined to the —Si(OR 1 ) x (R 2 ) y through an organic group, and the organic group is selected from the group consisting of alkanes, alkenes, alkynes, cycloalkanes, aromatic groups, and combinations thereof.

13 . The method of claim 9 , wherein the silicon-oxygen organic monomer is represented by

n is 0 or 1, and m is 1 to 5.

14 . The method of claim 9 , wherein the silicon-oxygen organic monomer is selected from the group consisting of γ-(triethoxysilyl)propyl methacrylate, γ-(trimethoxysilyl)propyl methacrylate, γ-methacryloxypropylmethyldimethoxysilane, (diethoxymethylsilyl)propyl methacrylate, γ-acryloxypropyltriethoxysilane, γ-acryloxypropyltrimethoxysilane, γ-acryloxypropylmethyldimethoxysilane, acryloxypropylmethyldiethoxysilane, acryloxypropylmethyldimethoxysilane, and combinations thereof.

15 . The method of claim 7 , wherein the coating the organic-inorganic hybrid polymer further comprises:
dissolving the organic-inorganic hybrid polymer in a nonaqueous electrolyte solution to form a polymer solution; and coating the polymer solution on the surface of the lithium metal plate to form the protective layer.

16 . The method of claim 15 , wherein the nonaqueous electrolyte solution comprises a solvent and a salt dissolved in the solvent; the solvent is selected from the group consisting of ethylene carbonate, propylene carbonate, diethyl carbonate, dimethyl carbonate, ethylmethyl carbonate, methyl acetate, ethyl acetate, propyl acetate, methyl propionate, ethyl propionate, γ-butyrolactone, tetrahydrofuran, 1,2-dimethoxyethane, acetonitrile, dimethylformamide, and combinations thereof; and the lithium salt is selected from the group consisting of lithium hexafluorophosphate, lithium tetrafluoroborate, lithium trifluoromethanesulfonate, lithium hexafluoroarsenate, lithium bis(oxalate)borate, and combinations thereof.

17 . A lithium ion battery comprising:
a cathode electrode; an anode electrode comprising
a lithium metal plate; and
a protective layer coated on a surface of the lithium metal plate;
a nonaqueous electrolyte solution; and a separator disposed between the cathode electrode and the anode electrode; wherein the protective layer comprises an organic-inorganic hybrid polymer comprising a repeating unit; the repeating unit comprises a silicon atom, a methacryloyloxy group or an acryloyloxy group, and at least two alkoxy groups; the at least two alkoxy groups and the methacryloyloxy group or the acryloyloxy group are respectively joined to the silicon atom.

Assignees

• Jiangsu Unionenergy Lithium Sulfur Battery Tech Co Ltd
• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• Zhao Peng
• Wang Li
• He xiang-ming
• Li Jian-Jun
• Shang yu-ming
• Yang ju-ping
• Cao Jiang
• Zhang yu-feng
• Gao Jian
• Wang yao-wu

Classifications

• C08F292/00

  Macromolecular compounds obtained by polymerising monomers on to inorganic materials · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C09D143/04

  Homopolymers or copolymers of monomers containing silicon · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/134 Primary

  Electrodes based on metals, Si or alloys · CPC title