Electrochemical method for producing pure-oxygen gas and oxygen-lean gas from oxygen-containing gas mixtures
US-10017865-B2 · Jul 10, 2018 · US
US2017229727A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017229727-A1 |
| Application number | US-201415510688-A |
| Country | US |
| Kind code | A1 |
| Filing date | Sep 12, 2014 |
| Priority date | Sep 12, 2014 |
| Publication date | Aug 10, 2017 |
| Grant date | — |
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A device and a method for providing electricity to an electric motor for propulsion of a vehicle are provided. The method comprises the features of feeding Energy Carriers (EC) in the shape of particles having a first oxidation state (I) from a first container on board the vehicle to an Solid Oxide Fuel Cell (SOFC). The EC are reacted at the SOFC to change the oxidation state from the first oxidation (I) to the second oxidation state (II) while producing electric energy. The EC is thereafter fed from the SOFC to a second container on board the vehicle. A reversed reaction is enabled on board the vehicle, e.g., by applying a voltage to the SOFC to reverse the reaction, and the EC are reacted to change its oxidation state from its second oxidation state (II) back to its first oxidation state (I) before the EC is returned to the first container. A system for performing the method is also provided.
Opening claim text (preview).
1 . An Energy Carrier System (ECS) for a vehicle comprising: Energy carriers (EC) to be used as fuel, the EC being in the shape of particles and being able to be oxidized and reduced, A container system for storage of the EC, the container system comprising a first container and a second container, A Solid Oxide Fuel Cell (SOFC) being able to produce an electric current from oxidation and/or reduction of the EC, A fuel feed system which in a first discharge mode transports the EC, having a first oxidation state, from the first container to the second container via the Solid Oxide Fuel Cell (SOFC), whereby the oxidation state of the EC is changed to a second oxidation state by an oxidation/reduction in the Solid Oxide Fuel Cell (SOFC) so as to produce an electric current in the Solid Oxide Fuel Cell (SOFC) before the EC reaches the second container for storage of particles in the second oxidation state wherein the fuel feed system in a second recharge mode transports the EC from the second container to the first container wherein the ECS is provided with charge function for changing the oxidation state of the EC from its second oxidation state to its first oxidation state. 2 . An Energy Carrier System (ECS) according to claim 1 wherein the Solid Oxide Fuel Cell (SOFC) is used also in the second recharge mode such that by applying a voltage to the Solid Oxide Fuel Cell (SOFC) is the oxidation/reduction reaction reversed. 3 . An Energy Carrier System (ECS) according to claim 1 , wherein the system comprises a mixing chamber comprising a fuel exchange side of the Solid Oxide Fuel Cell (SOFC) which is designed to oxidise and/or reduce the Energy Carriers (EC) when in contact with the fuel exchange side and the Solid Oxide Fuel Cell (SOFC) further comprising a fluid exchange side, located in a redox chamber, designed to reduce and/or oxidise a redox agent when in contact with the fluid exchange side in such a way that a transport of an electric charge is enabled through the Solid Oxide Fuel Cell (SOFC) by the oxidation respectively reduction reactions at the fuel exchange side respectively the fluid exchange side, whereby electric energy is generated. 4 . An Energy Carrier System (ECS) according to claim 3 , wherein the mixing chamber is a fluidized bed. 5 . (canceled) 6 . An Energy Carrier System (ECS) according to claim 1 , wherein the first and second containers are placed besides each other and are separated by a movable partition wall in order to be able to increase respective decrease the volumes of the respective containers as the volume need for the Energy Carriers (EC) in the respective container change as the EC are transported to and from the containers. 7 . An Energy Carrier System (ECS) according to claim 3 , wherein a first beat exchanger is connected to the mixing chamber and the redox chamber in order to heat the flow of redox agent from the redox chamber with the flow of Energy Carriers (EC) from the mixing chamber whereby the heated flow of redox agent may be used for powering an expander turbine and/or for heating purposes. 8 . An Energy Carrier System (ECS) according to claim 7 , wherein the heated flow of redox agent is used to power an expander turbine which forms part of a turbo compound system in which the expander turbine is mechanically connected to power a compressor turbine for pressurizing redox agent directed to an inlet in the redox chamber. 9 . An Energy Carrier System (ECS) according to claim 7 , wherein the expander turbine is connected to a generator for production of electricity. 10 . An Energy Carrier System (ECS) according to claim 7 , wherein the flow of the used redox agent from the expander turbine is guided to a second heat exchanger for heating purposes, e.g. for preheating of fresh air to be directed to the redox chamber to be used as fresh redox agent. 11 . An Energy Carrier System (ECS) according to claim 1 , wherein the Energy Carriers (EC) are circulated in a closed pressurized system, preferably having a pressure of 2 to 5 bar. 12 . A vehicle comprising the Energy Carrier System according to claim 1 . 13 . A method for providing electricity to an electric motor for propulsion of a vehicle, the method comprising: Feeding Energy Carriers (EC) in the shape of particles having a first oxidation state from a first container onboard the vehicle to a Solid Oxide Fuel Cell (SOFC), Reacting the EC at the Solid Oxide Fuel Cell (SOFC) to change the oxidation state from the first oxidation to the second oxidation state while electric energy is produced in the SOFC due to the change of the oxidation state of the EC, Feeding EC from the Solid Oxide Fuel Cell (SOFC) to a second container onboard the vehicle after they have been reacted to be in the second oxidation state feeding the EC back on board the vehicle from the second container to the first container; and reacting the EC onboard the vehicle to change its oxidation state from its second oxidation state to its first oxidation state before returning the EC is to the first container. 14 . A method according to claim 12 , comprising using the SOFC for the reaction of changing the oxidation state of the EC from its second oxidation state to its first oxidation state and feeding the EC from the second container to the first container via the Solid Oxide Fuel Cell (SOFC) which reverse the oxidation reaction by applying a voltage to the the Solid Oxide Fuel Cell (SOFC).
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