Anode electrode material and lithium ion battery using the same

Patent metadata

Field	Value
Publication number	US-2017229710-A1
Application number	US-201715498837-A
Country	US
Kind code	A1
Filing date	Apr 27, 2017
Priority date	Oct 29, 2014
Publication date	Aug 10, 2017
Grant date	—

Abstract

An anode binder, a cathode electrode material, and a lithium ion battery are disclosed. The anode binder includes a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer. The anode electrode material includes an anode active material, a conducting agent, and the anode binder. The lithium ion battery includes an anode electrode, an electrolyte, a separator, and the cathode electrode, the cathode electrode comprising a cathode active material, a conducting agent, and the anode binder.

First claim

What is claimed is:

1 . An anode electrode material comprising an anode binder, the anode binder comprising a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer, wherein the dianhydride monomer comprises a monomer selected from the group consisting of monomers represented by formulas I, II, III, and combinations thereof, the diamine monomer comprises a first monomer represented by formula IV,

2 . The anode electrode material of claim 1 , wherein the R in formula III is selected from the group consisting of bisphenol A unit, —O—, —S—, and —CH 2 —.

3 . The anode electrode material of claim 1 , wherein the dianhydride monomer is selected from the group consisting of 4,4′-(4,4′-isopropylidenediphenoxy)bis(phthalic anhydride), 2,3,3′,4′-diphenyl ether tetracarboxylic acid dianhydride, 1,2,4,5-benzenetetracarboxylic anhydride, 3,3′,4,4′-biphenyltetracarboxylic dianhydride, and combinations thereof.

4 . The anode electrode material of claim 1 , wherein the diamine monomer further comprises a second monomer represented by formula V,

5 . The anode electrode material of claim 4 , wherein the R 4 in formula V is selected from the group consisting of —(CH2)n-, —O—, —S—, —CH 2 —O—CH 2 —, —CH(NH)—(CH 2 ) n —,

6 . The anode electrode material of claim 4 , wherein a molar ratio of the first monomer to the second monomer is 1:2 to 10:1.

7 . The anode electrode material of claim 4 , wherein a molar ratio of the first monomer to the second monomer is 1:1 to 3:1.

8 . The anode electrode material of claim 1 , wherein a molar ratio of the dianhydride monomer to the diamine monomer is 1:10 to 10:1.

9 . The anode electrode material of claim 1 , wherein a molar ratio of the dianhydride monomer to the diamine monomer is 1:2 to 4:1.

10 . The anode electrode material of claim 1 having a molecular weight in a range from about 1000 to about 50000.

11 . The anode electrode material of claim 1 further comprising an anode active material and a conducting agent.

12 . The anode electrode material of claim 11 , wherein a mass percentage of the anode binder is in a range from about 0.01% to about 50%.

13 . The anode electrode material of claim 11 , wherein a mass percentage of the anode binder is in a range from about 1% to about 20%.

14 . A lithium ion battery comprising:
a cathode electrode; an electrolyte; a separator; and an anode electrode, the anode electrode comprising an anode active material, a conducting agent, and an anode binder, wherein the anode binder comprises a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer, the dianhydride monomer comprises a monomer selected from the group consisting of monomers represented by formulas I, II, III, and combinations thereof, the diamine monomer comprises a first monomer represented by formula IV,

15 . The lithium ion battery of claim 14 , wherein the anode binder is consisted of the polymer.

16 . The lithium ion battery of claim 14 , wherein the cathode active material is selected from the group consisting of lithium titanate, graphite, mesophase carbon micro beads (MCMB), acetylene black, mesocarbon miocrobead, carbon fibers, carbon nanotubes, cracked carbon, and combinations thereof.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• Qian guan-nan
• He xiang-ming
• Wang Li
• Shang yu-ming
• Li Jian-Jun
• Luo Jing
• Xu cheng-hao
• Gao Jian
• Wang yao-wu

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/622 Primary

  being polymers · CPC title