PTC thermistor ceramic composition and PTC thermistor element
US-9697935-B2 · Jul 4, 2017 · US
US2017229219A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017229219-A1 |
| Application number | US-201715409989-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jan 19, 2017 |
| Priority date | Feb 8, 2016 |
| Publication date | Aug 10, 2017 |
| Grant date | — |
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A semiconductor ceramic composition which is a BaTiO 3 based semiconductor ceramic composition, wherein, part of Ba is replaced by at least A (at least one alkali metal element selected from Na and K), Bi and RE (at least one element selected from rare earth elements including Y), and part of Ti is replaced by at least TM (at least one element selected from the group including of V, Nb and Ta), the relationships of 0.7≦{(the content of Bi)/(the content of A)}≦1.43, 0.017≦{(the content of Bi)+(the content of A)}≦0.25, and 0<{(the content of RE)+(the content of TM)}≦0.01 are satisfied when the total content of Ti and TM is set as 1 mol, the grain sizes have a maximum peak in a grain size distribution in a range of 1.1 μm to 4.0 μm or less, and the distribution frequency of the peak is 20% or more.
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What is claimed is: 1 . A semiconductor ceramic composition which is a BaTiO 3 based semiconductor ceramic composition, wherein, part of Ba is replaced by at least A, Bi and RE, and part of Ti is replaced by at least TM, wherein A represents at least one alkali metal element selected from the group consisting of Na and K, RE represents at least one element selected from rare earth elements including Y, and TM represents at least one element selected from the group consisting of V, Nb and Ta, the relationships of 0.7≦{(the content of Bi)/(the content of A)}≦1.43, 0.017≦{(the content of Bi)+(the content of A)}≦0.25, and 0<{(the content of RE)+(the content of TM)}≦0.01 are satisfied when the total content of Ti and TM is set as 1 mol, the semiconductor ceramic composition is composed of several crystal grains, the grain sizes of the several crystal grains have a maximum peak in a grain size distribution in a range of 1.1 μm or more and 4.0 μm or less, and the distribution frequency of the peak is 20% or more. 2 . A PTC thermistor comprising a ceramic body and a pair of electrodes formed on surfaces of the ceramic body, wherein, the ceramic body is formed by using the semiconductor ceramic composition of claim 1 .
based on BaTiO3 perovskite phase · CPC title
Bismuth oxides, bismuthates or oxide forming salts thereof, e.g. zinc bismuthate · CPC title
characterised by specific heating conditions during heat treatment · CPC title
Mixing media, e.g. organic solvents · CPC title
Making the green bodies or pre-forms by moulding · CPC title
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