Method for carbon coating on electrode active material of lithium ion battery

Patent metadata

Field	Value
Publication number	US-2017214043-A1
Application number	US-201715482466-A
Country	US
Kind code	A1
Filing date	Apr 7, 2017
Priority date	Oct 14, 2014
Publication date	Jul 27, 2017
Grant date	—

Abstract

A method for carbon coating on an electrode active material of a lithium ion battery is disclosed. The method comprises mixing a plurality of electrode active material particles, a carbon source, and a first solvent to obtain a first mixture liquid; heating the first mixture liquid at a temperature from about 130° C. to about 240° C. under a pressure from about 0.2 MPa to about 30 MPa to obtain a plurality of carbon source coated electrode active material particles; separating the plurality of carbon source coated electrode active material particles from the first mixture liquid; and sintering the plurality of carbon source coated electrode active material particles to obtain a plurality of carbon coated electrode active material particles.

First claim

What is claimed is:

1 . A method for carbon coating an electrode active material of a lithium ion battery, comprising:
providing a plurality of electrode active material particles, a carbon source, and a first solvent, wherein the carbon source is a nonionic surfactant; mixing the plurality of electrode active material particles, the carbon source, and the first solvent, thereby obtaining a first mixture liquid wherein the plurality of electrode active material particles are dispersed in the first solvent, and the carbon source is dissolved in the first solvent; heating the first mixture liquid at a temperature from about 130° C. to about 240° C. under a pressure from about 0.2 MPa to about 30 MPa to have a reaction forming a carbon source layer from the carbon source on a surface of each of the plurality of electrode active material particles, thereby obtaining a plurality of carbon source coated electrode active material particles; separating the plurality of carbon source coated electrode active material particles from the first mixture liquid; and sintering the plurality of carbon source coated electrode active material particles, thereby obtaining a plurality of carbon coated electrode active material particles.

2 . The method of claim 1 , wherein the first mixture liquid is obtained by:
providing a dispersion liquid, wherein the dispersion liquid comprises the first solvent, and the plurality of electrode active material particles uniformly dispersed in the first solvent; and adding the carbon source to the dispersion liquid, and dissolving the carbon source into the first solvent.

3 . The method of claim 2 , wherein the dispersion liquid is obtained by:
providing electrode active material precursors, and the first solvent; carrying out a liquid phase reaction of the electrode active material precursors in the first solvent, thereby obtaining a second mixture liquid, wherein the second mixture liquid comprises the first solvent, and the plurality of electrode active material particles dispersed in the first solvent; and using the second mixture liquid as the dispersion liquid.

4 . The method of claim 3 , wherein the liquid phase reaction is selected from a hydrothermal method, a solvothermal method, a coprecipitation method, a supercritical hydrothermal method, and a microwave synthesis method.

5 . The method of claim 3 , wherein the second mixture liquid is directly used as the dispersion liquid.

6 . The method of claim 3 , wherein the second mixture liquid is used as the dispersion liquid after removing impurities in the second mixture.

7 . The method of claim 6 , wherein the impurities are removed from the second mixture liquid by:
washing the second mixture liquid using a second solvent, and obtaining wet powder by filtering but not drying, wherein the wet powder can comprise the plurality of electrode active material particles, and the second solvent adsorbed on the surface of each of the plurality of electrode active material particles; dispersing the wet powder in the first solvent, thereby obtaining the second mixture liquid substantially without the impurities; and using the second mixture liquid substantially without the impurities as the dispersion liquid.

8 . The method of claim 7 , wherein the first solvent and the second solvent are soluble to each other at any proportion.

9 . The method of claim 1 , wherein the carbon source is selected from the group consisting of polyvinyl pyrrolidone, polyethylene glycol, fatty acid ethoxylate, alkyl alcohol ethoxylate, alkyl phenol ethoxylate, fatty amine ethoxylate, alkyl amide ethoxylate, sorbitan fatty acid ester, and polyoxyethylene sorbitan fatty acid ester, and combinations thereof.

10 . The method of claim 1 , wherein the carbon source is polyvinyl pyrrolidone.

11 . The method of claim 1 , wherein a mass ratio of the carbon source to the plurality of electrode active material particles in the first mixture liquid is in a range from about 10% to about 300%.

12 . The method of claim 1 , wherein a mass ratio of the carbon source to the plurality of electrode active material particles in the first mixture liquid is in a range from about 20% to about 200%.

13 . The method of claim 1 , wherein the first solvent is selected from the group consisting of water, ethanol, ethylene glycol, glycerol, diethylene glycol, triethylene glycol, tetraethylene glycol, butanetriol, butanol, isobutanol, polyethylene glycol, dimethyl formamide, and combinations thereof.

14 . The method of claim 1 , wherein the plurality of electrode active material particles is a plurality of nanosized electrode active material particles.

15 . The method of claim 1 , wherein the plurality of carbon source coated electrode active material particles are sintered at a temperature from about 400° C. to about 1000° C. in an inert gas.

16 . The method of claim 1 , wherein the first mixture liquid is heated at a temperature from about 150° C. to about 220° C. under the pressure from about 0.2 MPa to about 30 MPa to form the carbon source layer.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• Liu shao-jun
• Wang Li
• Li Jian-Jun
• He xiang-ming
• Luo Jing
• Xu cheng-hao
• Shang yu-ming
• Gao Jian
• Wang yao-wu

Classifications

• H01M4/625

  Carbon or graphite · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/366 Primary

  as layered products · CPC title