Method for carbon coating on electrode active material of lithium ion battery

Patent metadata

Field	Value
Publication number	US-2017214039-A1
Application number	US-201715482446-A
Country	US
Kind code	A1
Filing date	Apr 7, 2017
Priority date	Oct 14, 2014
Publication date	Jul 27, 2017
Grant date	—

Abstract

A method for carbon coating on an electrode active material of a lithium ion battery is disclosed. The method comprises carrying out a liquid phase reaction of an electrode active material precursor in a first solvent, thereby obtaining a first mixture liquid comprising the first solvent, and a plurality of electrode active material particles dispersed in the first solvent; adding a carbon source into the first mixture liquid, thereby obtaining a second mixture liquid; drying the second mixture liquid, thereby obtaining a plurality of carbon source coated electrode active material particles; and sintering the plurality of carbon source coated electrode active material particles, thereby obtaining a plurality of carbon coated electrode active material particles.

First claim

What is claimed is:

1 . A method for carbon coating an electrode active material of a lithium ion battery, comprising:
providing an electrode active material precursor and a first solvent, and carrying out a liquid phase reaction of the electrode active material precursor in the first solvent, thereby obtaining a first mixture liquid comprising the first solvent, and a plurality of electrode active material particles dispersed in the first solvent; providing a carbon source, and adding the carbon source into the first mixture liquid to dissolve the carbon source into the first solvent, thereby obtaining a second mixture liquid; drying the second mixture liquid, thereby obtaining a plurality of carbon source coated electrode active material particles wherein a carbon source layer is formed on a surface of each of the plurality of electrode active material particles; and sintering the plurality of carbon source coated electrode active material particles, thereby obtaining a plurality of carbon coated electrode active material particles.

2 . The method of claim 1 , unreacted ionic impurities in the first mixture liquid are removed by:
obtaining a first wet powder by separating the plurality of electrode active material particles from the first mixture liquid but not drying, and obtaining a second wet powder by washing the first wet powder with a second solvent, filtering, but not drying; and dispersing the second wet powder in the first solvent, thereby obtaining the first mixture liquid substantially without the unreacted ionic impurities.

3 . The method of claim 2 , wherein the first wet powder comprises the plurality of electrode active material particles, the first solvent and the unreacted ionic impurities, the first solvent and the unreacted ionic impurities are absorbed on the surface of each of the plurality of electrode active material particles, and the second wet powder comprises the plurality of electrode active material particles, and the second solvent adsorbed on the surface of each of the plurality of electrode active material particles.

4 . The method of claim 2 , wherein the unreacted ionic impurities are dissolved in the second solvent.

5 . The method of claim 2 , wherein the first solvent and the second solvent are soluble to each other at any proportion.

6 . The method of claim 2 , wherein the second solvent is the same as the first solvent.

7 . The method of claim 2 , wherein the second solvent is selected from the group consisting of water, ethanol, ethylene glycol, glycerol, diethylene glycol, triethylene glycol, tetraethylene glycol, butanetriol, n-butanol, isobutanol, polyethylene glycol, dimethyl formamide, and combinations thereof.

8 . The method of claim 2 , wherein solid contents of the first wet powder and the second wet powder are smaller than about 50%.

9 . The method of claim 1 , wherein the electrode active material precursor comprises raw materials which are essential reactants to produce the plurality of electrode active material particles by the liquid phase reaction.

10 . The method of claim 1 , wherein the first solvent is selected from the group consisting of water, ethanol, ethylene glycol, glycerol, diethylene glycol, triethylene glycol, tetraethylene glycol, butanetriol, n-butanol, isobutanol, polyethylene glycol, dimethyl formamide, and combinations thereof.

11 . The method of claim 1 , wherein the liquid phase reaction is a hydrothermal method, a solvothermal method, a coprecipitation method, a supercritical hydrothermal method, or a microwave synthesis method.

12 . The method of claim 1 , wherein the carbon source is selected from the group consisting of glucose, sucrose, fructose, lactose, starch, polyvinyl chloride, polyvinyl alcohol, polyvinyl butyral, polyvinyl pyrrolidone, polyacrylonitrile, phenolic resin, and combinations thereof.

13 . The method of claim 1 , wherein a mass ratio of the carbon source to the plurality of electrode active material particles in the first mixture liquid is in a range from about 10% to about 300%.

14 . The method of claim 1 , wherein a drying temperature of the second mixture liquid is in a range from about 100° C. to about 150° C.

15 . The method of claim 1 , wherein the plurality of carbon source coated electrode active material particles are sintered in an inert gas.

16 . The method of claim 1 , wherein the plurality of carbon source coated electrode active material particles are sintered at a temperature range from about 400° C. to about 1000° C. for about 2 hours to about 10 hours.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• Liu shao-jun
• Wang Li
• Li Jian-Jun
• He xiang-ming
• Luo Jing
• Xu cheng-hao
• Shang yu-ming
• Gao Jian
• Wang yao-wu

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C09D1/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• B05D3/0254

  After-treatment · CPC title

• H01M4/1397 Primary

  of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title