Multiple hydrophilic head corrosion inhibitors

Patent metadata

Field	Value
Publication number	US-2017190952-A1
Application number	US-201715465787-A
Country	US
Kind code	A1
Filing date	Mar 22, 2017
Priority date	May 5, 2014
Publication date	Jul 6, 2017
Grant date	—

Abstract

Compounds comprising multiple hydrophilic heads and a lipophilic tail may be contacted with a metal or other surface so as to adhere to the surface and inhibit corrosion, among other things. Suitable hydrophilic heads may include quaternary ammonium cation moieties, phosphonium cation moieties, and combinations thereof. Such corrosion-inhibiting compounds may be introduced into a wellbore penetrating at least a portion of a subterranean formation, for instance in oil and/or gas recovery operations and the like, whereupon the compound may adhere to a metal or other surface downhole so as to inhibit corrosion of the surface. These compounds may be employed in various other environments, such as any metal or other surface that may be exposed to corrosive conditions.

First claim

What is claimed is:

1 . A method of inhibiting corrosion, the method comprising:
introducing a composition comprising a hydrophilic solvent and a corrosion-inhibiting compound into a wellbore penetrating at least a portion of a subterranean formation; and contacting a metal surface in the wellbore with the corrosion-inhibiting compound; wherein the corrosion-inhibiting compound has the structural formula:

wherein each of R 1 and R 2 is CH 3 and R 3 is benzyl;
wherein each of M, M′, and M″ is nitrogen;
wherein R is a C 1 to C 30 hydrocarbon chain;
wherein J is selected from the group consisting of hydrogen, a C 1 to C 6 hydrocarbon chain, and combinations thereof; and
wherein each of X, X′, and X″ is an anion selected from the group consisting of halide, carboxylate, sulfate, organic sulfonate, hydroxide, and combinations thereof.

2 . The method of claim 1 further comprising increasing the hydrophobicity of the metal surface.

3 . The method of claim 1 wherein the corrosion-inhibiting compound is present in a concentration of from 1 ppm to 100 ppm.

4 . The method of claim 1 wherein the corrosion-inhibiting compound comprises the reaction product of a reaction process that comprises (i) a first reaction between a long-chain primary amine and an epihalohydrin, and (ii) a second reaction between the product of the first reaction with an amine selected from the group consisting of a secondary amine, a tertiary amine, and any combination thereof.

5 . The method of claim 4 wherein the reaction process occurs at a temperature in a range of from 20° C. to 80° C.

6 . The method of claim 1 wherein J is hydrogen.

7 . The method of claim 1 wherein J is a C 1 to C 6 hydrocarbon chain.

8 . The method of claim 1 wherein X is a halide.

9 . The method of claim 1 wherein X″ is a halide.

10 . A method comprising:
introducing a composition comprising a hydrophilic solvent and a corrosion-inhibiting compound into a pipeline; and contacting a metal surface in the pipeline with the corrosion-inhibiting compound; wherein the corrosion-inhibiting compound has the structural formula:

wherein each of R 1 and R 2 is CH 3 and R 3 is a benzyl group;
wherein each of X and X′ is an anion selected from the group consisting of halide, carboxylate, sulfate, organic sulfonate, hydroxide, and combinations thereof; and
wherein R is a C 8 to C 30 hydrocarbon chain.

11 . The method of claim 10 further comprising increasing the hydrophobicity of the metal surface.

12 . The method of claim 10 wherein the corrosion-inhibiting compound is present in a concentration of from 1 ppm to 100 ppm.

13 . The method of claim 10 wherein the corrosion-inhibiting compound comprises the reaction product of a reaction process that comprises (i) a first reaction between a long-chain primary amine and an epihalohydrin, and (ii) a second reaction between the product of the first reaction with an amine selected from the group consisting of a secondary amine, a tertiary amine, and any combination thereof.

14 . The method of claim 13 wherein the reaction process occurs at a temperature in a range of from 20° C. to 80° C.

15 . The method of claim 10 wherein each of X and X′ is a halide.

16 . The method of claim 10 wherein X″ is a halide.

17 . A method of inhibiting corrosion, the method comprising:
introducing a composition comprising a hydrophilic solvent and a corrosion-inhibiting compound into a wellbore penetrating at least a portion of a subterranean formation; and contacting a metal surface in the wellbore with the corrosion-inhibiting compound; wherein the corrosion-inhibiting compound has the structural formula:

wherein each of R 1 and R 2 is CH 3 and R 3 is benzyl;
wherein each of M, M′, and M″ is nitrogen;
wherein each of X, X′, and X″ is a halide;
wherein R is a C 12 to C 16 hydrocarbon chain; and
wherein J is hydrogen.

18 . The method of claim 17 further comprising increasing the hydrophobicity of the metal surface.

19 . The method of claim 17 wherein the corrosion-inhibiting compound is present in a concentration of from 1 ppm to 100 ppm.

20 . The method of claim 17 wherein the corrosion-inhibiting compound comprises the reaction product of a reaction process that comprises (i) a first reaction between a long-chain primary amine and an epihalohydrin, and (ii) a second reaction between the product of the first reaction with an amine selected from the group consisting of a secondary amine, a tertiary amine, and any combination thereof.

Assignees

• Multi Chem Group Llc

Inventors

• Qu Liangwei
• Davis Nathan Darrell
• Zhao Funian
• Fu Qiang

Classifications

• C23F11/146

  containing a multiple nitrogen-to-carbon bond · CPC title

• F16L58/04

  Coatings characterised by the materials used (F16L58/16 takes precedence) · CPC title

• C09K8/54 Primary

  Compositions for in situ inhibition of corrosion in boreholes or wells · CPC title

• C09K2208/32

  Anticorrosion additives · CPC title

• C09K8/40

  Spacer compositions, e.g. compositions used to separate well-drilling from cementing masses · CPC title