Methacrylic resin composition and molded article of same

Patent metadata

Field	Value
Publication number	US-2017190896-A1
Application number	US-201515320663-A
Country	US
Kind code	A1
Filing date	Jun 22, 2015
Priority date	Jun 23, 2014
Publication date	Jul 6, 2017
Grant date	—

Abstract

In order to provide a methacrylic resin composition that maintains all of physical properties such as excellent solvent resistance, heat resistance, mechanical strength, and stringing resistance, and has particularly excellent fluidity and also heat stability, the present invention provides a methacrylic resin composition that satisfies conditions (I) through (IV) and includes two types of methacrylic resins having mutually different peak molecular weights. (I) The weight ratio of methyl methacrylate units in the methacrylic resin is greater than 98.5 wt % with respect to 100 wt % of all monomer units. (II) The HP value indicating the higher peak molecular weight satisfies the expression 180,000≦HP≦220,000. (III) The LP value indicating the lower peak molecular weight satisfies the expression 24,000≦LP≦35,000. (IV) The PR value indicated by a/b, where a is the value indicating peak height in the HP and b is the value indicating peak height in the LP on a differential molecular weight distribution curve, satisfies the expression 1.32≦PR≦1.60.

First claim

1 . A methacrylic resin composition that comprises two methacrylic resins differing in peak molecular weight from each other, wherein
the methacrylic resin composition satisfies the following conditions (I), (II), (III), and (IV): (I) the methacrylic resins each have a methyl methacrylate unit as a monomer unit, and a weight ratio of the methyl methacrylate unit is higher than 98.5% by weight relative to 100% by weight of all monomer units; (II) when the higher peak molecular weight of the peak molecular weights of the methacrylic resins is denoted as “HP”, the value of HP satisfies the formula: 180,000≦HP≦220,000; (III) when the lower peak molecular weight of the peak molecular weights of the methacrylic resins is denoted as “LP”, the value of LP satisfies the formula: 24,000≦LP≦35,000; and (IV) when the value representing the height of a peak at HP is denoted as “a” and the value representing a height of a peak at LP is denoted as “b” on a differential molecular weight distribution curve, a value of PR defined by a/b satisfies the formula:
1.32≦ PR≦ 1.60.

2 . The methacrylic resin composition according to claim 1 , wherein the methacrylic resin composition is produced by continuous bulk polymerization.

3 . The methacrylic resin composition according to claim 1 , wherein the methacrylic resin composition is produced by continuous bulk polymerization using two complete mixing tanks.

4 . The methacrylic resin composition according to claim 1 , wherein the methacrylic resin composition comprises a methacrylic resin obtained by polymerization at a polymerization temperature of 110° C. to 160° C. at a weight ratio equal to or higher than 50% by weight relative to the total weight of the methacrylic resin composition.

5 . The methacrylic resin composition according to claim 1 , wherein the methacrylic resin composition is used for injection molding.

6 . The methacrylic resin composition according to claim 1 , wherein the methacrylic resin composition is used for a vehicle application.

7 . A molded article obtainable from the methacrylic resin composition according to claim 1 .

Assignees

• Sumitomo Chemical Co

Inventors

• Yamamori Akihiro
• Kadoya Hidenori
• Yamazaki Kazuhiro

Classifications

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2205/06

  having improved processability or containing aids for moulding methods · CPC title

• C08L33/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title