Materials engineering for anti-coking coating stacks
US-2024175119-A1 · May 30, 2024 · US
US2017190591A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017190591-A1 |
| Application number | US-201515101849-A |
| Country | US |
| Kind code | A1 |
| Filing date | Aug 28, 2015 |
| Priority date | Aug 28, 2015 |
| Publication date | Jul 6, 2017 |
| Grant date | — |
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A surface-coated cutting tool according to the present invention includes a coating. The coating has an α-Al 2 O 3 layer. The α-Al 2 O 3 layer includes a lower layer portion and an upper layer portion. When respective crystal orientations of crystal grains of α-Al 2 O 3 are specified by performing EBSD analyses with an FE-SEM on a cross-section obtained when the α-Al 2 O 3 layer is cut along a plane including a normal line of a surface of the α-Al 2 O 3 layer and a color map is prepared based on the crystal orientations, in the color map, an area in the upper layer portion occupied by the crystal grains of which normal direction of a (001) plane is within ±10° with respect to a normal direction of the surface of the α-Al 2 O 3 layer is equal to or more than 90%, and such an area in the lower layer portion is equal to or less than 50%.
Opening claim text (preview).
1 . A surface-coated cutting tool, comprising: a base material; and a coating formed on the base material, the coating including an α-Al 2 O 3 layer containing a plurality of crystal grains of α-Al 2 O 3 , the α-Al 2 O 3 layer including a lower layer portion which is located on a base material side in a thickness direction and has a thickness of 1 μm and an upper layer portion which is located on a surface side opposite to the base material side and has a thickness of 2 μm, when respective crystal orientations of the crystal grains are specified by performing electron beam backscattering diffraction analyses with a field emission-type scanning microscope, on a cross section obtained when the α-Al 2 O 3 layer is cut along a plane including a normal line of a surface of the α-Al 2 O 3 layer and a color map is prepared based on the crystal orientations, in the color map, an area in the upper layer portion occupied by the crystal grains of which normal direction of a (001) plane is within ±10° with respect to a normal direction of the surface of the α-Al 2 O 3 layer being equal to or more than 90%, and an area in the lower layer portion occupied by the crystal grains of which normal direction of the (001) plane is within ±10° with respect to the normal direction of the surface of the α-Al 2 O 3 layer being equal to or less than 50%, and the α-Al 2 O 3 layer having a stress distribution varying in the thickness direction, the surface side of the α-Al 2 O 3 layer having a compressive residual stress, and the base material side of the α-Al 2 O 3 layer having a tensile residual stress. 2 . (canceled) 3 . The surface-coated cutting tool according to claim 1 , wherein the stress distribution has a first region where an absolute value of the compressive residual stress continuously increases from the surface side toward the base material side, and a second region located on the base material side relative to the first region, where an absolute value of the compressive residual stress continuously decreases and is turned to the tensile residual stress, and successively an absolute value of the tensile residual stress continuously increases, from the surface side toward the base material side, and the first region and the second region are continuous, with an intermediate point where the absolute value of the compressive residual stress is greatest being interposed. 4 . The surface-coated cutting tool according to claim 1 , wherein the α-Al 2 O 3 layer has an absolute value of the compressive residual stress not greater than 1000 MPa and an absolute value of the tensile residual stress not greater than 2000 MPa. 5 . The surface-coated cutting tool according to claim 1 , wherein the coating includes a first intermediate layer between the base material and the α-Al 2 O 3 layer, and the first intermediate layer is a TiCN layer. 6 . The surface-coated cutting tool according to claim 5 , wherein the coating includes a second intermediate layer between the first intermediate layer and the α-Al 2 O 3 layer, the second intermediate layer is a TiCNO layer or a TiBN layer, and a difference between a greatest thickness and a smallest thickness of the second intermediate layer is not smaller than 0.3 μm. 7 . The surface-coated cutting tool according to claim 1 , wherein the coating includes a surface layer located at an outermost surface, and the surface layer is a TiC layer, a TiN layer, or a TiB 2 layer. 8 . A surface-coated cutting tool, comprising: a base material; and a coating formed on the base material, the coating including an α-Al 2 O 3 layer containing a plurality of crystal grains of α-Al 2 O 3 , the α-Al 2 O 3 layer including a lower layer portion which is located on a base material side in a thickness direction and has a thickness of 1 μm and an upper layer portion which is located on a surface side opposite to the base material side and has a thickness of 2 μm, when respective crystal orientations of the crystal grains are specified by performing electron beam backscattering diffraction analyses with a field emission-type scanning microscope, on a cross section obtained when the α-Al 2 O 3 layer is cut along a plane including a normal line of a surface of the α-Al 2 O 3 layer and a color map is prepared based on the crystal orientations, in the color map, an area in the upper layer portion occupied by the crystal grains of which normal direction of a (001) plane is within ±10° with respect to a normal direction of the surface of the α-Al 2 O 3 layer being equal to or more than 90%, and an area in the lower layer portion occupied by the crystal grains of which normal direction of the (001) plane is within ±10° with respect to the normal direction of the surface of the α-Al 2 O 3 layer being equal to or less than 50%, and the α-Al 2 O 3 layer having a stress distribution varying in the thickness direction, wherein the stress distribution has a first region where an absolute value of the compressive residual stress continuously increases from the surface side toward the base material side, and a second region located on the base material side relative to the first region, where an absolute value of the compressive residual stress continuously decreases and is turned to the tensile residual stress, and successively an absolute value of the tensile residual stress continuously increases, from the surface side toward the base material side, and the first region and the second region are continuous, with an intermediate point where the absolute value of the compressive residual stress is greatest being interposed.
with specified thickness · CPC title
Alumina or aluminates · CPC title
of aluminium, magnesium or beryllium · CPC title
applied by physical vapour deposition [PVD] · CPC title
Deposition of sub-layers, e.g. to promote the adhesion of the main coating · CPC title
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