Method of making electrodes containing carbon sheets decorated with nanosized metal particles and electrodes made therefrom

Patent metadata

Field	Value
Publication number	US-2017170459-A1
Application number	US-201615377661-A
Country	US
Kind code	A1
Filing date	Dec 13, 2016
Priority date	Dec 15, 2015
Publication date	Jun 15, 2017
Grant date	—

Abstract

A method of making carbon sheets comprising nanosized metal particle. The method includes dissolving sodium chloride, a salt containing the metal, and glucose into water, maintaining weight ratio weight of sodium chloride to glucose in the range of 1-8, resulting in a homogeneous aqueous solution. The homogeneous aqueous solution is then dried to form a homogeneous powder which is then heated for a time period resulting in a composite comprising carbon sheets containing the sodium chloride and nanoparticles of the metal. The sodium chloride is removed resulting in carbon sheets containing nanoparticles of the metal. A carbon sheet with 2D morphology containing nanosized metal particles. An electrode comprising a carbon sheet with 2D morphology containing nanosized metal particles. An electrochemical storage cell containing an anode comprising a carbon sheet with 2D morphology containing nanosized metal particles.

First claim

1 . A method of making carbon sheets comprising nanosized metal particles, the method comprising:
dissolving a quantity of sodium chloride, a quantity of a salt containing the metal, and a quantity of glucose into water, such that the ratio of weight of the sodium chloride and weight of the glucose is in the range of 1-8, resulting in a homogeneous aqueous solution of the sodium chloride, the glucose and the salt of the metal; drying the homogeneous aqueous solution at a temperature in the range of 80-100 degrees centigrade, resulting in a homogeneous powder containing the sodium chloride, the glucose and the salt of the metal; heating the homogeneous powder at a heating temperature in an inert atmosphere for a time period resulting in a composite comprising carbon sheets containing the sodium chloride and nanoparticles of the metal; and cooling the composite containing carbon sheet containing the sodium chloride and nanoparticles of the metal to room temperature and removing sodium chloride by dissolving the composite in water resulting in carbon sheets containing nanoparticles of the metal.

2 . The method of claim 1 , wherein the metal is cobalt and the metal salt is one of cobalt nitrate, cobalt chloride and cobalt acetate.

3 . The method of claim 1 , wherein the nanoparticles of cobalt are in the size range of 5-30 nm.

4 . The method of claim 1 , wherein the heating temperatures is in the range of 600-900° C.

5 . The method of claim 1 , wherein the time period is in the range of 1-5 hours.

6 . The method of claim 1 , wherein the carbon sheets contain mesoporosity.

7 . The method of claim 1 , wherein the metal is one of iron, antimony, tin, nickel, manganese and tungsten.

8 . A carbon sheet with 2D morphology containing nanosized metal particles.

9 . The carbon sheet of claim 8 , wherein the metal is an electrochemically active metal.

10 . The carbon sheet of claim 8 , wherein the electrochemically active metal is cobalt and the nanosized cobalt particles are covalently bonded to the carbon sheet forming a Co—C bond.

11 . The carbon sheet of claim 10 , wherein the nanoparticles of cobalt are in the size range of 5-30 nm.

12 . The carbon sheet of claim 8 , wherein the carbon sheet contains mesoporosity.

13 . The carbon sheet of claim 9 , wherein the electrochemically active metal is one of iron, antimony, tin, nickel, manganese and tungsten.

14 . An electrode comprising a carbon sheet with 2D morphology containing nanosized metal particles.

15 . The electrode of claim 14 , wherein the metal is an electrochemically active metal.

16 . The electrode of claim 15 , wherein the electrochemically active metal is cobalt and the nanosized cobalt particles are covalently bonded to the carbon sheet forming a Co—C bond.

17 . The electrode of claim 16 , wherein the nanoparticles of cobalt are in the size range of 5-30 nm.

18 . The electrode of claim 14 , the carbon sheet contains mesoporosity.

19 . The electrode of claim 15 , wherein the electrochemically active metal is one of iron, antimony, tin, nickel, manganese and tungsten.

20 . An electrochemical storage cell containing an anode comprising a carbon sheet with 2D morphology containing nanosized metal particles.

21 . The electrochemical storage cell of claim 20 , wherein the cell is a Li-ion cell.

22 . The electrochemical storage cell of claim 20 , wherein the metal is an electrochemically active metal.

23 . The electrochemical storage cell of claim 22 , wherein the electrochemically active metal is cobalt and the nanosized cobalt particles are covalently bonded to the carbon sheet forming a Co—C bond.

24 . The electrochemical storage cell of claim 23 , wherein the nanosized particles of cobalt are in the size range of 5-30 nm.

25 . The electrochemical storage cell of claim 20 , wherein the carbon sheet contains mesoporosity.

26 . The electrochemical storage cell of claim 22 , wherein the electrochemically active metal is one of iron, antimony, tin, nickel, manganese and tungsten.

Assignees

• Purdue Research Foundation

Inventors

• Pol Vilas Ganpat
• Etacheri Vinodkumar

Classifications

• B22F1/054

  Nanosized particles · CPC title

• B22F9/30

  with decomposition of metal compounds, e.g. by pyrolysis · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title