Composition for fuel cell electrode

Patent metadata

Field	Value
Publication number	US-2017149067-A1
Application number	US-201615337890-A
Country	US
Kind code	A1
Filing date	Oct 28, 2016
Priority date	Oct 28, 2015
Publication date	May 25, 2017
Grant date	—

Abstract

In some examples, a fuel cell comprising an anode; an electrolyte; cathode barrier layer; and a nickelate composite cathode separated from the electrolyte by the cathode barrier layer; and a cathode current collector layer. The nickelate composite cathode includes a nickelate compound and an ionic conductive material, and the nickelate compound comprises at least one of Pr 2 NiO 4 , Nd 2 NiO 4 , (Pr u Nd v ) 2 NiO 4 , (Pr u Nd v ) 3 Ni 2 O 7 , (Pr u Nd v ) 4 Ni 3 O 10 , or (Pr u Nd v M w ) 2 NiO 4 , where M is an alkaline earth metal doped on an A—site of Pr and Nd. The ionic conductive material comprises a first co-doped ceria with a general formula of (A x B y )Ce 1-x-y O 2 , where A and B of the first co-doped ceria are rare earth metals. The cathode barrier layer comprises a second co-doped ceria with a general formula (A x B y )Ce 1-x-y O 2 , where at least one of A or B of the second co-doped ceria is Pr or Nd.

First claim

1 . A fuel cell comprising:
an anode; an electrolyte; cathode barrier layer; and a nickelate composite cathode separated from the electrolyte by the cathode barrier layer; and a cathode current collector layer, wherein the nickelate composite cathode includes a nickelate compound and an ionic conductive material, wherein the nickelate compound comprises at least one of:
Pr 2 NiO 4 ,
Nd 2 NiO 4 ,
(Pr u Nd v ) 2 NiO 4 ,
(Pr u Ad v ) 3 Ni 2 O 7 ,
(Pr u Nd v ) 4 Ni 3 O 10 , or
(Pr u Nd v Mw) 2 NiO 4 , where M is an alkaline earth metal doped on an A—site of Pr and Nd,
wherein the ionic conductive material comprises a first co-doped ceria with a general formula of (A x B y )Ce 1-x-y O 2 , where A and B of the first co-doped ceria are rare earth metals, wherein cathode barrier layer comprises a second co-doped ceria with a general formula (A x B y )Ce 1-x-y O 2 , where at least one of A or B of the second co-doped ceria is Pr or Nd, and wherein the anode, cathode barrier layer, nickelate composite cathode, cathode current collector layer, and electrolyte are configured to form an electrochemical cell.

2 . The fuel cell of claim 1 , wherein the cathode barrier layer is configured to prevent material diffusion between the nickelate composite cathode and electrolyte and increase phase stability of the nickelate composite cathode.

3 . The fuel cell of claim 1 , wherein the ionic conductive material is Pr-containing co-doped ceria, (Pr x B y )Ce 1-x-y O 2 , wherein B is rare earth metal, such as La, Gd, Sm, Nd, Tb, Dy, Yb, Y, Ho, Er, and the like.

4 . The fuel cell of claim 1 , wherein the ionic conductive material is Nd-containing co-doped ceria, (Nd x B y )Ce 1-x O 2 , wherein B is rare earth metal, such as La, Gd, Sm, Pr, Tb, Dy, Yb, Y, Ho, Er, and the like.

5 . The fuel cell of claim 1 , wherein ionic conductive material is Pr and Nd co-doped ceria, (Pr x Nd y )Ce 1-x-y O 2 .

6 . The fuel cell of claim 1 , wherein the nickelate composite cathode is substantially free of oxide formed exoluted A-site element and/or B-site element from the nickelate compound following operation at a temperature of approximately 790 degrees Celsius or greater after approximately 100 hours.

7 . The fuel cell of claim 1 , wherein the nickelate composite cathode includes diffused exolute from the nickelate in a phase of the ionic conductive material following operation at a temperature of approximately 790 degrees Celsius or greater after approximately 100 to 2000 hours.

8 . The fuel cell of claim 1 , wherein the cell including the nickelate composite cathode exhibits an area specific resistance (ASR) of approximately 0.22 ohm-cm 2 or lower following operation at a temperature of approximately 860 degrees Celsius after approximately 6600 hours.

9 . The fuel cell of claim 1 , wherein the cathode barrier layer is configured to prevent chemical interaction between the electrolyte and the nickelate compound that forms zirconate phase.

10 . The fuel cell of claim 1 , wherein the cathode barrier layer is configured to control rare earth metal oxide exolution from the nickelate compound to manage phase constitution in the nickelate composite cathode to keep desired phases for lower degradation rate.

11 . The fuel cell of claim 10 , wherein the cathode barrier layer is Pr-containing co-doped ceria, (Pr x B y )Ce 1-x-y O 2 , wherein B is rare earth metal, such as La, Gd, Sm, Nd, Tb, Dy, Yb, Y, Ho, Er, and the like.

12 . The fuel cell of claim 10 , wherein the cathode barrier layer is Nd-containing co-doped ceria, (Nd x B y )Ce 1-x O 2 , wherein B is rare earth metal, such as La, Gd, Sm, Pr, Tb, Dy, Yb, Y, Ho, Er, and the like

13 . The fuel cell of claim 10 , wherein the cathode barrier layer is Pr and Nd co-doped ceria, (Pr x Nd y )Ce 1-x-y O 2 .

14 . The fuel cell of claim 1 , wherein the nickelate composite cathode exhibits a thickness from approximately 3 microns to approximately 30 microns.

15 . The fuel cell of claim 1 , wherein the fuel cell is configured as one of a segmented-in-series cell pattern, tubular cell, anode supported planar cell, or electrolyte supported planar cell.

16 . The fuel cell of claim 1 , wherein the cathode current collector comprises a conductive ceramic that is chemically compatible with the nickelate composite cathode.

17 . The fuel cell of claim 12 , wherein the cathode current collector comprises at least one of a lanthanum nickel ferrite (La(NiFe)O 3-δ ) or a lanthanum strontium cobaltite ((LaSr)CoO 3-δ ).

18 . The fuel cell of claim 1 , wherein the nickelate composite cathode consists of or consists essentially of the nickelate compound and ionic conductive material.

19 . The fuel cell of claim 1 , wherein 0<x<0.5 and 0≦y<0.5.

20 . A method for making a fuel cell comprising an anode; an electrolyte; a cathode barrier layer; and a nickelate composite cathode separated from the electrolyte by the cathode barrier layer; and a cathode current collector layer, the method comprising:
forming the cathode barrier layer on the electrolyte; and forming the nickelate composite cathode on the cathode barrier layer; wherein the nickelate composite cathode includes a nickelate compound and an ionic conductive material, wherein the nickelate compound comprises at least one of:
Pr 2 NiO 4 ,
Nd 2 NiO 4 ,
(Pr u Nd v ) 2 NiO 4 ,
(Pr u Ad v ) 3 Ni 2 O 7 ,
(Pr u Nd v ) 4 Ni 3 O 10 , or
(Pr u Nd v M w ) 2 NiO 4 , where M is an alkaline earth metal doped on an A—site of Pr and Nd,
wherein the ionic conductive material comprises a first co-doped ceria with a general formula of (A x B y )Ce 1-x-y O 2 , where A and B of the first co-doped ceria are rare earth metals, wherein cathode barrier layer comprises a second co-doped ceria with a general formula (A x B y )Ce 1-x-y O 2 , where at least one of A or B of the second co-doped ceria is Pr or Nd, and wherein the anode, cathode barrier layer, nickelate composite cathode, cathode current collector layer, and electrolyte are configured to form an electrochemical cell.

Assignees

• Lg Fuel Cell Systems Inc

Inventors

• Liu Zhien
• Jung Hwa Young
• Xing Zhengliang
• Goettler Richard W

Classifications

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M4/8673

  Electrically conductive fillers · CPC title

• H01M4/9033 Primary

  Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites · CPC title

• H01M4/8817

  Treatment of supports before application of the catalytic active composition (coated porous composites H01M8/0245) · CPC title

• H01M4/8647 Primary

  consisting of more than one material, e.g. consisting of composites · CPC title