Moulding materials containing dicarboxylic acid ester and 1,2-cyclohexane dicarboxylic acid ester

Patent metadata

Field	Value
Publication number	US-2017145186-A1
Application number	US-201515323514-A
Country	US
Kind code	A1
Filing date	Jul 7, 2015
Priority date	Jul 8, 2014
Publication date	May 25, 2017
Grant date	—

Abstract

The present invention relates to molding compounds containing at least one polymer and a plasticizer composition which contains at least one ester of an aliphatic dicarboxylic acid and at least one ester of 1,2-cyclohexanedicarboxylic acid, and use of these plasticizer compositions and molding compounds.

First claim

1 .- 15 . (canceled)

16 . A molding compound containing at least one polymer and one plasticizer composition, containing
a) at least one compound of the general formula (I),
R 1 —O—C(═O)—X—C(═O)—O—R 2    (I)

wherein
X stands for an unbranched or branched C 2 -C 8 alkylene group or an unbranched or branched C 2 -C 8 alkenylene group, containing at least one double bond,
and
R 1 and R 2 are mutually independently selected from C 3 -C 5 alkyl,
b) at least one compound of the general formula (II),

wherein R 3 and R 4 are mutually independently selected from branched and unbranched C 7 -C 12 alkyl residues,

wherein the content of the compounds (I) in the molding compound is at least 11 parts by weight based on 100 parts by weight polymer (phr).

17 . The molding compound as claimed in claim 16 , wherein X stands for an unbranched C 2 -C 5 alkylene group.

18 . The molding compound as claimed in claim 16 , wherein R 1 and R 2 mutually independently stand for n-butyl, isobutyl, n-pentyl, 2-methylbutyl or 3-methylbutyl.

19 . The molding compound as claimed in claim 16 , wherein R 1 and R 2 both stand for n-butyl.

20 . The molding compound as claimed in claim 16 , wherein R 3 and R 4 both stand for 2-ethylhexyl, both stand for isononyl or both stand for 2-propylheptyl.

21 . The molding compound as claimed in claim 16 , which further comprises a plasticizer different from the compounds (I) and (II), and said plasticizer is dialkyl esters of phthalic acid, alkyl aralkyl esters of phthalic acid, dialkyl esters of terephthalic acid, trialkyl esters of trimellitic acid, alkyl esters of benzoic acid, dibenzoate esters of glycols, hydroxybenzoate esters, esters of saturated monocarboxylic acids, saturated dicarboxylate esters different from compounds (I), unsaturated dicarboxylate esters different from compounds (I), amides and esters of aromatic sulfonic acids, alkylsulfonate esters, glycerin esters, isosorbide esters, phosphate esters, citrate triesters, alkylpyrrolidone derivatives, esters of 2,5-furandicarboxylic acid, esters of 2,5-tetrahydrofurandicarboxylic acid, epoxidized plant oils, expoxidized monoalkyl esters of fatty acids or polyesters of aliphatic and/or aromatic polycarboxylic acids with at least dihydric alcohols.

22 . The molding compound as claimed in claim 16 , wherein the polymer is a thermoplastic polymer which is selected from the group consisting of
homo- or copolymers which contain at least one monomer incorporated by polymerization, which is selected from C 2 -C 10 monoolefins, 1,3-butadiene, 2-chloro-1,3-butadiene, vinyl alcohol and C 2 -C 10 alkyl esters thereof, vinyl chloride, vinylidene chloride, vinylidene fluoride, tetrafluoroethylene, glycidyl acrylate, glycidyl methacrylate, acrylates and methacrylates of C 1 -C 10 alcohols, vinylaromatics, (meth)acrylonitrile, maleic anhydride and α,β-ethylenically unsaturated mono- and dicarboxylic acids, homo- and copolymers of vinylacetals, polyvinyl esters, polycarbonates, polyesters, polyethers, polyether ketones, thermoplastic polyurethanes, polysulfides, polysulfones, polyether sulfones, cellulose alkyl esters and mixtures thereof.

23 . The molding compound as claimed in claim 22 , wherein the thermoplastic polymer is polyvinyl chloride (PVC), polyvinylbutyral (PVB), homo- and copolymers of vinyl acetate, homo- and copolymers of styrene, polyacrylates, thermoplastic polyurethanes (TPU) or polysulfides.

24 . The molding compound as claimed claim 22 , wherein the thermoplastic polymer is polyvinyl chloride (PVC).

25 . The molding compound as claimed in claim 16 , wherein the polymer is an elastomer.

26 . The molding compound as claimed in claim 16 , wherein the polymer is a natural rubber, synthetic rubber or mixtures thereof.

27 . A plasticizer composition containing
a) at least one compound of the general formula (I)
R 1 —O—C(═O)—X—C(═O)—O—R 2    (I)

wherein
X stands for an unbranched or branched C 2 -C 8 alkylene group or an unbranched or branched C 2 -C 8 alkenylene group, containing at least one double bond,
and
R 1 and R 2 are mutually independently selected from C 3 -C 5 alkyl,
b) at least one compound of the general formula (II),

wherein R 3 and R 4 are mutually independently selected from branched and unbranched C 7 -C 12 alkyl residues,

wherein the content of the compounds (I) in the molding compound is at least 11 parts by weight based on 100 parts by weight polymer (phr).

28 . A thermoplastic polymer or elastomer which comprises the plasticizer as claimed in claim 27 .

29 . A plastisol which comprises the plasticizer as claimed in claim 27 wherein the content of the compounds (I) is at least 11 parts by weight based on 100 parts by weight of the thermoplastic polymer or elastomer to be plasticized (phr).

30 . A molded article or film which comprises the molding composition as claimed in claim 16 .

31 . The molded article or film as claimed in claim 30 , wherein the article or film is a housing for an electrical appliance, a computer housing, a tool, a pipe, a cable, a hose, a wire coating, a window profile, a component for vehicle manufacture, a tire, a furniture, a foam for cushions and mattresses, a tarpaulin, a seal, a composite sheet, a record, an artificial leather, a packaging container, an adhesive tape film or a coating.

32 . A molded article or film which comprises the molding composition as claimed in claim 16 and said article or film comes directly into contact with a person or a foodstuff.

33 . A process for utilizing a molded article or film which come directly into contact with people or with foods which comprises contacting the molding composition as defined in claim 16 with people or foods.

34 . The molded article or film as claimed in claim 32 , wherein the molded article or film is a medicinal product, a hygiene product, a food packaging, a product for the indoor sector, a toy, a child care article, a sport product, a leisure product, a clothing or a fibers for fabrics.

35 . The process as claimed in claim 33 , wherein the molded article or film is a medicinal product, hygiene product, food packaging, a product for the indoor sector, a toy, a child care article, a sport product, a leisure product, clothing or a fiber for fabric.

Assignees

• Basf Se

Inventors

• Pfeiffer Matthias
• Breitscheidel Boris
• Grimm Axel
• Morgenstern Herbert

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08K5/11 Primary

  of acyclic polycarboxylic acids · CPC title

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08J2327/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08K5/12 Primary

  of cyclic polycarboxylic acids · CPC title