Polyarylene sulfide dispersion, powder particles, method for producing polyarylene sulfide dispersion, and method for producing powder particles

Patent metadata

Field	Value
Publication number	US-2017145168-A1
Application number	US-201515312700-A
Country	US
Kind code	A1
Filing date	Apr 2, 2015
Priority date	May 22, 2014
Publication date	May 25, 2017
Grant date	—

Abstract

An object of the present invention is to provide a polyarylene sulfide dispersion which has high dispersion stability even if the polyarylene sulfide resin concentration is high, and which is coated with an anionic group-containing organic polymer compound having excellent bondability and adhesion to various base materials such as plastics, metals, and glasses. The present invention solves the aforementioned problem by providing a polyarylene sulfide dispersion which is including polyarylene sulfide particles having high stability even at a high concentration by being coated with an anionic group-containing organic polymer compound according to an acid deposition method; and powder particles obtained from the polyarylene sulfide dispersion.

First claim

1 . A polyarylene sulfide dispersion comprising:
polyarylene sulfide particles; an anionic group-containing organic polymer compound; a base; and an aqueous medium, the polyarylene sulfide particles being coated with the anionic group-containing organic polymer compound.

2 . The polyarylene sulfide dispersion according to claim 1 ,
wherein an anionic group of the anionic group-containing organic polymer compound is at least one anionic group selected from the group consisting of a carboxyl group, a carboxylate group, a sulfonic acid group, a sulfonate group, and a phosphoric acid group.

3 . The polyarylene sulfide dispersion according to claim 1 ,
wherein a main skeleton of the anionic group-containing organic polymer compound is at least one organic polymer compound selected from the group consisting of a (meth)acrylate resin, a (meth)acrylate-styrene resin, a (meth)acrylate-epoxy resin, a vinyl resin, a urethane resin, and a polyamideimide resin.

4 . The polyarylene sulfide dispersion according to claim 1 ,
wherein an acid value of the anionic group-containing organic polymer compound is from 10 to 300 mgKOH/g.

5 . The polyarylene sulfide dispersion according to claim 1 ,
wherein in the anionic group-containing organic polymer compound, a base used for neutralization of the anionic group is at least one base selected from the group consisting of a metal hydroxide and an organic amine.

6 . The polyarylene sulfide dispersion according to claim 1 ,
wherein a volume average particle size of the polyarylene sulfide particles in the polyarylene sulfide dispersion is 1 μm or less.

7 . Polyarylene sulfide powder particles obtained by drying the polyarylene sulfide dispersion according to claim 1 .

8 . A method for producing a polyarylene sulfide dispersion comprising:
a step (A) of heating polyarylene sulfide in an organic solvent to obtain a solution; a step (B) of adding the solution of polyarylene sulfide obtained in the step (A) to a resin aqueous solution in which an anionic group-containing organic polymer compound is added to water and dissolved, so as to form polyarylene sulfide fine particles; a step (C) of reacting the polyarylene sulfide fine particles obtained in the step (B) with an acid to deposit the anionic group-containing organic polymer compound on the surface of the polyarylene sulfide fine particles and thereby precipitate the polyarylene sulfide particles coated with an anionic group-containing organic polymer; a step (D) of filtering the polyarylene sulfide particles coated with the anionic group-containing organic polymer obtained in the step (C), followed by washing, to obtain a hydrous wet cake of the polyarylene sulfide particles coated with an anionic group-containing organic polymer; and a step (E) of reacting the hydrous wet cake of the polyarylene sulfide particles coated with an anionic group-containing organic polymer obtained in the step (D) with a base to thereby obtain a dispersion including the polyarylene sulfide particles coated with an anionic group-containing organic polymer compound.

9 . The method for producing a polyarylene sulfide dispersion according to claim 8 ,
wherein the organic solvent used in the step (A) is at least one organic solvent selected from N-methyl-2-pyrrolidone, 1-chloronaphthalene, and 1,3-dimethyl-2-imidazolidinone.

10 . A method for producing polyarylene sulfide powder particles comprising:
a step (A) of heating polyarylene sulfide in an organic solvent to obtain a solution; a step (B) of adding the solution of polyarylene sulfide obtained in the step (A) to a resin aqueous solution in which an anionic group-containing organic polymer compound is added to water and dissolved, so as to form polyarylene sulfide fine particles; a step (C) of reacting the polyarylene sulfide fine particles obtained in the step (B) with an acid to thereby deposit the anionic group-containing organic polymer compound on the surface of the polyarylene sulfide fine particles and precipitate the polyarylene sulfide particles coated with an anionic group-containing organic polymer; a step (D) of filtering the polyarylene sulfide particles coated with the anionic group-containing organic polymer obtained in the step (C), followed by washing, to obtain a hydrous wet cake of polyarylene sulfide particles coated with an anionic group-containing organic polymer; and a step (F1) of drying the hydrous wet cake of the polyarylene sulfide particles coated with the anionic group-containing organic polymer obtained in the step (D) to thereby obtain polyarylene sulfide powder particles coated with an anionic group-containing organic polymer.

11 . A method for producing polyarylene sulfide powder particles, comprising:
a step (A) of heating polyarylene sulfide in an organic solvent to obtain a solution; a step (B) of adding the solution of polyarylene sulfide solution obtained in the step (A) to a resin aqueous solution in which an anionic group-containing organic polymer compound is added to water and dissolved, so as to form polyarylene sulfide fine particles; a step (C) of reacting the polyarylene sulfide fine particles obtained in the step (B) with an acid to thereby deposit the anionic group-containing organic polymer compound on the surface of the polyarylene sulfide fine particles and precipitate the polyarylene sulfide particles coated with an anionic group-containing organic polymer; a step (D) of filtering the polyarylene sulfide particles coated with the anionic group-containing organic polymer obtained in the step (C), followed by washing, to obtain a hydrous wet cake of polyarylene sulfide particles coated with an anionic group-containing organic polymer; a step (E) of reacting the hydrous wet cake of polyarylene sulfide particles coated with the anionic group-containing organic polymer obtained in the step (D) with a base to thereby obtain a dispersion including the polyarylene sulfide particles coated with an anionic group-containing organic polymer compound; and a step (F2) of drying the dispersion including the polyarylene sulfide particles coated with an anionic group-containing organic polymer compound obtained in the step (E) to thereby obtain polyarylene sulfide powder particles coated with an anionic group-containing organic polymer.

12 . The method for producing polyarylene sulfide powder particles according to claim 10 ,
wherein the organic solvent used in the step (A) is at least one organic solvent selected from N-methyl-2-pyrrolidone, 1-chloronaphthalene, and 1,3-dimethyl-2-imidazolidinone.

13 . The method for producing a polyarylene sulfide dispersion according to claim 8 ,
wherein, after the step (B), a dispersion liquid including the polyarylene sulfide obtained in the step (B) is mechanically pulverized.

14 . The method for producing polyarylene sulfide powder particles according to claim 10 ,
wherein, after the step (B), a dispersion liquid including the polyarylene sulfide obtained in the step (B) is mechanically pulverized.

15 . The polyarylene sulfide dispersion according to claim 2 ,
wherein a main skeleton of the anionic group-containing organic polymer compound is at least one organic polymer compound selected from the group consisting of a (meth)acrylate resin, a (meth)acrylate-styrene resin, a (meth)acrylate-epoxy resin, a vinyl resin, a urethane resin, and a polyamideimide resin.

16 . The polyarylene sulfide dispersion according to claim 2 ,
wherein an acid value of the anionic group-containing organic polymer compound is from 10 to 300 mgKOH/g.

17 . Th

Assignees

• Dainippon Ink & Chemicals

Inventors

• Enomoto Yuya
• Imamura Shoji
• Kuwamura Shinichi

Classifications

• C08J3/14

  by precipitation from solutions {(C08J3/122 takes precedence)} · CPC title

• C08G75/0213

  containing elements other than carbon, hydrogen or sulfur · CPC title

• C08J3/05 Primary

  from solid polymers · CPC title

• C08J2425/14

  with unsaturated esters · CPC title

• C08J2381/02

  Polythioethers; Polythioether-ethers · CPC title