Process for the polymerization of propylene

Patent metadata

Field	Value
Publication number	US-2017145128-A1
Application number	US-201515320040-A
Country	US
Kind code	A1
Filing date	Jun 16, 2015
Priority date	Jun 20, 2014
Publication date	May 25, 2017
Grant date	—

Abstract

The invention relates to a process for the preparation of ethylene-propylene copolymers having —a weight average molecular weight of 800,000-1,800,000, —a molecular weight distribution of 3-8, —an ethylene content of 1-10 wt %, preferably 1.5 to 5.5 wt %. —a melt flow in the range of 1.5-8 dg/min measured with a load of 21.6 kg at 230° C. and —a xylene soluble content of 2-15 wt % by converting propylene into the UHMWEP copolymer without pre-polymerization in the presence of a polymerization catalyst under a condition where the volume ratio of H 2 to propylene is at most 0.0020, wherein the catalyst comprises a catalyst component and a co-catalyst, wherein the catalyst component is obtained by a process wherein a compound with formula Mg(OAIk) x Cl y wherein x is larger than 0 and smaller than 2, y equals 2−x and each Alk, independently, represents an alkyl group, is contacted with a titanium tetraalkoxide and/or an alcohol in the presence of an inert dispersant to give an intermediate reaction product and wherein the intermediate reaction product is contacted with titanium tetrachloride in the presence of an internal donor.

First claim

1 . A process for the preparation of ethylene-propylene copolymers having
a weight average molecular weight of 800,000-1,800,000, a molecular weight distribution of 3-8, an ethylene content of 1-10 wt %, a melt flow in the range of 1.5-8 dg/min measured with a load of 21.6 kg at 230° C. and a xylene soluble content of 2-15 wt %, by converting propylene into the UHMWEP copolymer without pre-polymerization in the presence of a polymerization catalyst under a condition where the volume ratio of H 2 to propylene is at most 0.0020, wherein the catalyst comprises a catalyst component and a co-catalyst, wherein the catalyst component is obtained by a process wherein a compound with formula Mg(OAlk) x Cl y wherein x is larger than 0 and smaller than 2, y equals 2−x and each Alk, independently, represents an alkyl group, is contacted with a titanium tetraalkoxide and/or an alcohol in the presence of an inert dispersant to give an intermediate reaction product and wherein the intermediate reaction product is contacted with titanium tetrachloride in the presence of an internal donor.

2 . The process according to claim 1 , wherein the volume ratio of H 2 to propylene is at most 0.0010.

3 . The process according to claim 1 , wherein the volume ratio of H 2 to propylene is substantially 0.

4 . The process according to claim 1 , wherein the co-catalyst is an organoaluminium compound.

5 . The process according to claim 1 , wherein the catalyst further comprises an external donor, the external donor preferably being chosen from dialkyldimethoxysilanes and alkyltrimethoxysilanes.

6 . The process according to claim 5 , wherein the external donor is chosen from cyclohexylmethyldimethoxysilane, n-propyl trimethoxysilaan, di(iso-propyl)dimethoxysilane or di(iso-butyl)dimethoxysilane.

7 . The process according to claim 5 , wherein the molar ratio of the co-catalyst to the external donor is 0.30-100.

8 . Ethylene-polypropylene copolymer having
a molecular weight of 800,000-1,800,000, a molecular weight distribution of 3-8, an ethylene content between 1 and 10 wt %, a melt flow in the range of 1.5-8 dg/min measured with a load of 21.6 kg at 230° C. and a xylene soluble content of 2-15 wt %.

9 . The ethylene-polypropylene copolymer according to claim 8 , having
a molecular weight of 1,000,000-1,400,000, a molecular weight distribution of 3-6, an ethylene content between 1.5 and 5 wt %, a melt flow in the range of 1.5-8 dg/min measured with a load of 21.6 kg at 230° C. and a xylene soluble content of 6-10 wt %.

10 . The ethylene-polypropylene copolymer according to claim 8 , having a melt strength of at least 5-20 as measured by a capillary viscometer according to ASTM D3835, a zero shear viscosity of at least 10 kPa-second at 230° C. as measured according to ASTM D4440, and/or an elongational viscosity of at least 100 KPa-second at 170° C. as measured using Advanced Rheometric Expansion System equipped with EVF, and wherein the copolymer has a crystallinity of 45-50%, a crystallization temperature of 80-105° C., and/or a melting temperature of 130-155° C., as measured by differential scanning calorimeter according to ASTM D3418-08 at a heating rate of 10° C./min.

11 . A process for forming an article by extrusion, injection molding, thermoforming or blow molding the copolymer according to claim 8 .

12 . The process according to claim 11 , wherein the article is formed at a temperature of 240-280° C.

13 . The article obtainable by the process of claim 11 , having an environmental stress cracking (ESCR) of at least 1000 hours at 100% Igebal as measured according to ASTM D1693, a transparency measured as % haze of at least 15% for 2 mm thickness on a BYK Gardner Haze-gard Plus hazemeter in accordance with ASTM D1003, a gloss of at least 70 according to ASTM D2457 and/or a ratio of impact strength (J/m) over stiffness (MPa) of at least 0.45.

14 . The article according to claim 13 , wherein the article is a film, a pipe or a container.

15 . An article formed from the ethylene-propylene copolymer as obtained in the process according to claim 1 .

16 . An article formed from the ethylene-propylene copolymer according to claim 8 .

17 . The process according to claim 1 ,
wherein the ethylene content is 1.5 to 5.5 wt %, wherein the co-catalyst is triethyl aluminium, wherein the volume ratio of H 2 to propylene is at most 0.0005, and wherein the molar ratio of the co-catalyst to the external donor is 1.0-30.

Assignees

• Sabic Global Technologies Bv

Inventors

• Al-Shobilly Hesham A
• Alshaiban Ahmad Abdullah
• Albeladi Abdulrahman
• Meddad Abderrahman
• Al Humoud Riyadh A

Classifications

• C08F210/06 Primary

  Propene · CPC title

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F2410/06

  Catalyst characterized by its size · CPC title