Adsorbent Materials And Methods of Adsorbing Carbon Dioxide

Patent metadata

Field	Value
Publication number	US-2017136405-A1
Application number	US-201615351693-A
Country	US
Kind code	A1
Filing date	Nov 15, 2016
Priority date	Nov 16, 2015
Publication date	May 18, 2017
Grant date	—

Abstract

Methods of designing zeolite materials for adsorption of CO 2 . Zeolite materials and processes for CO 2 adsorption using zeolite materials.

First claim

What is claimed is:

1 . A pressure swing adsorption process for separating CO 2 from a feed gas mixture, wherein the process comprises:
a) subjecting the feed gas mixture comprising CO 2 to an adsorption step by introducing the feed gas mixture into a feed input end of an adsorbent bed, wherein the adsorbent bed comprises:
a feed input end and a product output end; and
an adsorbent material selective for adsorbing CO 2 , wherein the adsorbent material comprises one or more of the following:
(i) a zeolite having a Si/Al ratio above about 100 and a framework structure selected from the group consisting of AFT, AFX, DAC, EMT, EUO, IMF ITH, ITT, KFI, LAU, MFS, MRE, MTT, MWW, NES, PAU, RRO, SFF, STF, STI, SZR, TER, TON, TSC, TUN, VFI, and a combination thereof; or
(ii) a zeolite with a framework structure selected from the group consisting of CAS, EMT, FAU, HEU, IRR, IRY, ITT, LTA, RWY, TSC and VFI, and a combination thereof, having:
a. a Si/Al ratio of about 5 to about 85; and
b. a potassium cation concentration of about 5% to about 100%;

wherein the adsorbent bed is operated at a first pressure and at a first temperature wherein at least a portion of the CO 2 in the feed gas mixture is adsorbed by the adsorbent bed and wherein a gaseous product depleted in CO 2 exits the product output end of the adsorbent bed; b) stopping the introduction of the feed gas mixture to the adsorbent bed before breakthrough of CO 2 from the product output end of the adsorbent bed; c) reducing the pressure in the adsorption bed to a second pressure resulting in desorption of at least a portion of CO 2 from the adsorbent bed; and d) recovering at least a portion of CO 2 from the adsorbent bed.

2 . The process of claim 1 , wherein the first temperature is from about −20° C. to about 80° C. and the first pressure is such that the partial pressure of CO 2 is from about 3 bar to about 25 bar.

3 . The process of claim 2 , wherein the first temperature is from about 0° C. to about 50° C. and the first pressure is such that the partial pressure of CO 2 is from about 3 bar to about 10 bar.

4 . The process of claim 2 , wherein the first temperature is from about 0° C. to about 50° C. and the first pressure is such that the partial pressure of CO 2 is from about 15 bar to about 25 bar.

5 . The process of claim 1 , wherein the second pressure is such that the partial pressure of CO 2 is from about 0.5 bar to about 2 bar.

6 . The process of claim 1 , wherein the feed gas mixture is a natural gas stream.

7 . The process of claim 1 , wherein the adsorbent material has a working capacity of about 2.0 mmol/cc to about 15.0 mmol/cc.

8 . The process of claim 1 , wherein the adsorbent bed has open flow channels throughout its entire length through which the feed gas mixture is passed.

9 . The process of claim 8 , wherein the adsorbent bed is a parallel channel contactor.

10 . The process of claim 1 , wherein the adsorbent material is a zeolite having a Si/Al ratio above about 100 and a framework structure selected from the group consisting of AFT, AFX, DAC, EMT, EUO, IMF, ITH, ITT, KFI, LAU, MFS, MRE, MTT, MWW, NES, PAU, RRO, SFF, STF, STI, SZR, TER, TON, TSC, TUN, VFI and a combination thereof.

11 . The process of claim 1 , wherein the adsorbent material is a zeolite with a framework structure selected from the group consisting of CAS, EMT, FAU, HEU, IRR, IRY, ITT, LTA, RWY, TSC, VFI, and combinations thereof, having:
a. a Si/Al ratio of about 5 to about 70; and b. a potassium concentration of about 10% to about 100%;

12 . The process of claim 1 , wherein the adsorbent material comprises one or more of the following:
(i) a zeolite having a Si/Al ratio above about 100 and a framework structure selected from the group consisting of AFT, AFX, KFI, PAU, TSC, and a combination thereof; or (ii) a zeolite with a framework structure selected from the group consisting of LTA, TSC, and a combination thereof, having:
a. a Si/Al ratio of about 40 to about 60; and
b. a potassium cation concentration of about 50% to about 90%.

13 . A pressure swing adsorption process for separating CO 2 from a feed gas mixture, wherein the process comprises:
a) subjecting the feed gas mixture comprising CO 2 to an adsorption step by introducing the feed gas mixture into a feed input end of an adsorbent bed, wherein the adsorbent bed comprises:
a feed input end and a product output end; and
an adsorbent material selective for adsorbing CO 2 , wherein the adsorbent material comprises a zeolite having a Si/Al ratio of between about 5 and about 45 and with a framework structure selected from the group consisting of CHA, FAU, FER, LTA, MFI, RHO, UFI, and a combination thereof;
wherein the adsorbent bed is operated at a first pressure and at a first temperature wherein at least a portion of the CO 2 in the feed gas mixture is adsorbed by the adsorbent bed and wherein a gaseous product depleted in CO 2 exits the product output end of the adsorbent bed;
b) stopping the introduction of the feed gas mixture to the adsorbent bed before breakthrough of CO 2 from the product output end of the adsorbent bed; c) reducing the pressure in the adsorption bed to a second pressure resulting in desorption of at least a portion of CO 2 from the adsorbent bed; and d) recovering at least a portion of CO 2 from the adsorbent bed.

14 . A pressure temperature swing adsorption process for separating a CO 2 from a feed gas mixture, wherein the process comprises:
a) subjecting the feed gas mixture comprising CO 2 to an adsorption step by introducing the feed gas mixture into a feed input end of an adsorbent bed, wherein the adsorbent bed comprises:
a feed input end and a product output end; and
an adsorbent material selective for adsorbing CO 2 , wherein the adsorbent material comprises one or more of the following:
(i) a zeolite having a Si/Al ratio above about 100 and a framework structure selected from the group consisting of AFT, AFX, CAS, DAC, HEU, IMF ITH, KFI, LAU, MFS, MTT, PAU, RRO, SFF, STF, SXR, TER, TON, TUN, and a combination thereof; or
(ii) a zeolite with a framework structure selected from the group consisting of AFT, AFX, CHA, EMT, EUO, FAU, IRR, IRY, ITT, KFI, LTA, MRE, MWW, NES, PAU, RHO, RWY, SFF, STI, TSC, UFI, VFI, and a combination thereof, having:
a. a Si/Al ratio of about 3 to about 100; and
b. a potassium cation concentration of about 1% to about 100%;

wherein the adsorbent bed is operated at a first pressure and at a first temperature wherein at least a portion of the CO 2 in the feed gas mixture is adsorbed by the adsorbent bed and wherein a gaseous product depleted in CO 2 exits the product output end of the adsorbent bed; b) stopping the introduction of the feed gas mixture to the adsorbent bed before breakthrough of CO 2 from the product output end of the adsorbent bed; c) heating the adsorbent bed to a second temperature higher than the first temperature, resulting in desorption of at least a portion of CO 2 from the adsorbent bed and recovering at least a first portion of CO 2 ; and d) reducing the pressure of the adsorbent bed to a second pressure lower than the first pressure and recovering a second portion of CO 2 .

15 . The process of claim 14 , wherein the first temperature is from about −20° C. to about 80° C. and the first pressure is such that the partial pressure of CO 2 is from about 3 bar to about 25 bar.

16 . The process of claim 15 , wherein the first temperature is from about 0° C. to about 50° C. and the first pressure is such that the partial pre

Assignees

• Exxonmobil Upstream Res Co
• Georgia Tech Res Inst

Inventors

• Ravikovitch Peter I
• Sholl David
• Paur Charanjit
• Strohmaier Karl G
• Fang Hanjun
• Kulkarni Ambarish R
• Awati Rohan V
• Kamakoti Preeti

Classifications

• B01D53/047

  Pressure swing adsorption · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D53/0462 Primary

  Temperature swing adsorption · CPC title

• C10L2290/12

  Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel · CPC title

• C10L3/104

  Carbon dioxide · CPC title