Electrospun microtubes and nanotubes containing rheological fluid
US-9809908-B2 · Nov 7, 2017 · US
US2017130366A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017130366-A1 |
| Application number | US-201615342954-A |
| Country | US |
| Kind code | A1 |
| Filing date | Nov 3, 2016 |
| Priority date | Nov 6, 2015 |
| Publication date | May 11, 2017 |
| Grant date | — |
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In a nanofiber structure in which a nanofiber A and a nanofiber B are tangled with each other, the softening point of the nanofiber A is different from that of the nanofiber B, a cross-section along a surface of the nanofiber A orthogonal to a longitudinal direction thereof has a shape having a concave portion, and the nanofiber A and the nanofiber B are fused with each other at this concave portion.
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What is claimed is: 1 . A nanofiber structure comprising: a nanofiber A; and a nanofiber B tangled with the nanofiber A, wherein: the softening point of the nanofiber A is different from the softening point of the nanofiber B, a cross-section along a surface of the nanofiber A orthogonal to a longitudinal direction thereof has a shape having a concave portion, and at the concave portion, the nanofiber A and the nanofiber B are fused with each other. 2 . The nanofiber structure according to claim 1 , wherein the concave portion is provided in an edge portion of the cross-section in a direction orthogonal to a longitudinal direction thereof. 3 . The nanofiber structure according to claim 1 , wherein the concave portion is provided in an edge portion of the cross-section in a longitudinal direction thereof. 4 . The nanofiber structure according to claim 1 , wherein: the average width of the cross-section of the nanofiber A is from 1 nm to 8×10 4 nm, the cross-section of the nanofiber A at which the width thereof is from 1 nm to 8×10 4 nm has a shape having at least two convex portions, the height of the convex portion is equal to or more than the average height of the cross-section of the nanofiber A and is equal to or less than the maximum height of the cross-section of the nanofiber A, and the average fiber diameter of the nanofiber B is from 1 nm to 3,000 nm. 5 . The nanofiber structure according to claim 1 , wherein a ratio L/Y of an average value L of the width of the cross-section of the nanofiber A to an average value Y of the fiber diameter of the nanofiber B is from 3.3×10 −4 to 8×10 3 . 6 . The nanofiber structure according to claim 1 , wherein constituent materials of the nanofiber A and the nanofiber B are each a thermoplastic resin, and the difference in softening point between the constituent material of the nanofiber A and the constituent material of the nanofiber B is from more than 0° C. to less than 100° C. 7 . The nanofiber structure according to claim 1 , wherein the difference in average solubility parameter between a constituent material of the nanofiber A and a constituent material of the nanofiber B is from 0 to 25 (J/cm 3 ) 1/2 . 8 . The nanofiber structure according to claim 1 , wherein an average presence rate of nanofibers on the surface of the nanofiber structure is from 10% to 60%. 9 . The nanofiber structure according to claim 1 , wherein: the nanofiber structure is a sheet-shaped structure, and the thickness of the sheet-shaped structure is from 1 μm to 1 mm. 10 . A method for manufacturing a nanofiber structure, wherein the nanofiber structure comprises: a nanofiber A; and a nanofiber B tangled with the nanofiber A, wherein: the softening point of the nanofiber A is different from the softening point of the nanofiber B, a cross-section along a surface of the nanofiber A orthogonal to a longitudinal direction thereof has a shape having a concave portion, and at the concave portion, the nanofiber A and the nanofiber B are fused with each other, the method comprising: forming a precursor by tangling at least the nanofiber A and the nanofiber B; and heating the precursor. 11 . The method according to claim 10 , wherein the nanofiber A or the nanofiber B contains an organic resin material and a low molecular weight organic compound having a chemical reactivity. 12 . The method according to claim 10 , wherein in the heating, the precursor is heated without pressure application.
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from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title
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comprising olefins as the major constituent · CPC title
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