Methods for making conformational conductive coated materials

Patent metadata

Field	Value
Publication number	US-2017125802-A1
Application number	US-201615338248-A
Country	US
Kind code	A1
Filing date	Oct 28, 2016
Priority date	Oct 28, 2015
Publication date	May 4, 2017
Grant date	—

Abstract

The disclosure provides a method for conformationally conductively coating materials, the coated materials resulting therefrom, and the use of the coated materials for various applications, including in Li-ion batteries.

First claim

What is claimed is:

1 . A method to generate a conformational conductive coating on particles comprising the steps of:
adding a plurality of particles to a solution comprising an organic polymer dissolved in one or more solvents; incubating the particles in the solution until a coating of the organic polymer forms on the surface of the particles; isolating the organic polymer-coated particles; and pyrolyzing the organic polymer-coated particles in an inert and/or reducing atmosphere at 200° C. to 800° C. for 1 to 24 hours so that the organic polymer coating anneals and decomposes to form a conformal carbon coating that is electrically conductive on the surface of the particles that is 0.5 nm to 10 nm in thickness, wherein the particles are nano- to micron-sized particles that are comprised of an insulating material used for anodes or cathodes.

2 . The method of claim 1 , wherein the one or more solvents comprise a polar protic solvent.

3 . The method of claim 1 , wherein the organic polymer is selected from the group consisting of poly(vinyl alcohol), polyethylene, poly(butyl methacrylate), poly(α-methylstyrene), polyethylene glycols, polystyrene, polypropylene, polytetrafluoroethylene, polychlorotrifluoroethylene, para-aramid, polychloroprene, polyamide, polyacrylonitrile, copolyamid, polytetrafluroethylene, polyimide, aromatic polyester, poly-p-phenylene-2,6-benzobisoxazole, poly-4-vinylphenol, poly(2,6-diphenylphenylene oxide), poly(3,4-ethylenedioxythiphene), poly(hexamethylene carbonate), poly(hydridocarbyne), poly(methacrylic acid), poly(N-vinylacetamide), poly(p-phenylene oxide), polyphenylene sulfide, poly(p-phenylene vinylene), polyacetylene, polyallylamine hydrochloride, polyaniline, polyaniline nanofibers, polyaryletherketone, polybenzimidazole fiber, polybutadiene, polydiacetylenes, polydioctylfluorene, polyetherketoneketone, polyglycerol, polyricinoleate, polyhexahydrotriazine, polyhexamethylene guanidine, polyketone, polymacon, polymethylpentene, polyol, polybenzyl isocyanate, polypyridinium salts, polypyrrole, polystyrene sulfonate, polythiophene, cellulose, chitin, glycogen, polypeptides, polynucleotides, and polysaccharides.

4 . The method of claim 1 , wherein the polymer is polyethylene glycol or a functionalized polyethylene glycol.

5 . The method of claim 4 , wherein the solution comprises 5% to 30% by weight of polyethylene glycol or a functionalized polyethylene glycol.

6 . The method of claim 1 , wherein the plurality of particles is added from a suspension comprising evenly dispersed particles.

7 . The method of claim 6 , wherein the suspension comprises from 0.5% to 10% by weight of the particles in a polar protic solvent.

8 . The method of claim 6 , wherein the suspension is added drop by drop to an agitated solution comprising the organic polymer dissolved in one or more solvents.

9 . The method of claim 1 , wherein the solution comprising the particles and polymer is incubated under agitation for 0.5 hours to 3 hours at 15° C. to 30° C.

10 . The method of claim 1 , wherein the particles are isolated by centrifugation, by aggregation with salt, by sedimentation, and/or by evaporation.

11 . The method of claim 1 , wherein the particles are dried prior to the heating step.

12 . The method of claim 1 , wherein the particles are comprised of LiFePO 4 .

13 . The method of claim 1 , wherein the organic polymer-coated particles are pyrolyzed under a flowing 95% N 2 /5% H 2 forming gas.

14 . The method of claim 13 , wherein the organic polymer-coated particles are pyrolyzed at about 600° C. for two to four hours.

15 . The method of claim 1 , wherein the carbon coating is evenly distributed over the particle' surface, and wherein the carbon content of the carbon coated particle is less than 1% by weight.

16 . Conformational conductive coated particles made by the method of claim 1 .

17 . The particles of claim 16 , wherein the conformational conductive coated particles exhibit one or more of the following characteristics:
a carbon coating from about 1 nm to 2 nm; a large portion of the coating is graphitic versus disordered carbon; a crystal size from 42 to 80 nm; a G/D ration of about 1.30; a particle size from 300 nm to 620 nm; and/or a rate capability of about 80 mA h/g at 2 C.

18 . A cathode comprising the particles of claim 16 .

19 . A lithium ion battery comprising the cathode of claim 18 .

Assignees

• Univ California

Inventors

• Kisailus David

Classifications

• H01M4/0414

  by screen printing · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title