Additive, electrolyte and lithium ion battery using the same

Patent metadata

Field	Value
Publication number	US-2017117584-A1
Application number	US-201715400599-A
Country	US
Kind code	A1
Filing date	Jan 6, 2017
Priority date	Jul 9, 2014
Publication date	Apr 27, 2017
Grant date	—

Abstract

An additive for a lithium ion battery is disclosed. The additive is a polymer obtained by polymerizing a maleimide type monomer with an organic diamine type compound. The maleimide type monomer comprises at least one of a maleimide monomer, a bismaleimide monomer, a multimaleimide monomer and a maleimide type derivative monomer. An electrolyte liquid and a lithium ion battery are also disclosed.

First claim

What is claimed is:

1 . An additive for a lithium ion battery, the additive being a polymer obtained by polymerizing a maleimide type monomer with an organic diamine type compound,
wherein the maleimide type monomer is selected from the group consisting of maleimide monomer, bismaleimide monomer, multimaleimide monomer, maleimide type derivative monomer, and combinations thereof; and the organic diamine type compound is represented by formula III or formula IV:

wherein R 3 is a bivalent organic substituent and R 4 is another bivalent organic substituent.

2 . The additive of claim 1 , wherein R 3 is selected from the group consisting of —(CH 2 ) n —, —CH 2 —O—CH 2 —, —CH(NH)—(CH 2 ) n —, phenylene, diphenylene, substituted phenylene, substituted diphenylene, and bivalent alicyclic group, R 4 is selected from the group consisting of —(CH 2 ) n —, —O—, —S—, —S—S—, —CH 2 —O—CH 2 —, —CH(NH)—(CH 2 ) n —, and —CH(CN)(CH 2 ) n —, and n=1 to 12.

3 . The additive of claim 1 , wherein the organic diamine type compound is selected from the group consisting of ethylenediamine, phenylenediamine, diamino-diphenyl-methane, diamino-diphenyl-ether, and combinations thereof.

4 . The additive of claim 1 , wherein the maleimide monomer is represented by formula I:

wherein R 1 is a monovalent organic substitute.

5 . The additive of claim 4 , wherein R 1 is selected from the group consisting of —R, —RNH 2 R, —C(O)CH 3 , —CH 2 OCH 3 , —CH 2 S(O)CH 3 , —C 6 H 5 , —C 6 H 4 C 6 H 5 , —CH 2 (C 6 H 4 )CH 3 , and monovalent alicyclic group; R is hydrocarbyl with 1 to 6 carbon atoms.

6 . The additive of claim 1 , wherein the maleimide monomer is selected from the group consisting of N-phenyl-maleimide, N-(p-methyl-phenyl)-maleimide, N-(m-methyl-phenyl)-maleimide, N-(o-methyl-phenyl)-maleimide, N-cyclohexane-maleimide, maleimide, maleimide-phenol, maleimide-benzocyclobutene, di-methylphenyl-maleimide, N-methyl-maleimide, ethenyl-maleimide, thio-maleimide, keto-maleimide, methylene-maleimide, maleimide-methyl-ether, maleimide-ethanediol, 4-maleimide-phenyl sulfone, and combinations thereof.

7 . The additive of claim 1 , wherein the bismaleimide monomer is represented by formula II:

wherein R 2 is a bivalent organic substitute.

8 . The additive of claim 7 , wherein R 2 is selected from the group consisting of —R—, —RNH 2 R—, —C(O)CH 2 —, —CH 2 OCH 2 —, —C(O)—, —O—, —O—O —, —S—, —S—S—, —S(O)—, —CH 2 S(O)CH 2 —, —(O)S(O)—, —CH 2 (C 6 H 4 )CH 2 —, —CH 2 (C 6 H 4 )(O)—, —R—Si(CH 3 ) 2 —O—Si(CH 3 ) 2 —R—, —C 6 H 4 —, —C 6 H 4 C 6 H 4 —, bivalent alicyclic group or —(C 6 H 4 )—R 5 —(C 6 H 4 )—; R 5 is —CH 2 —, —C(O)—, —C(CH 3 ) 2 —, —O—,—O—O—, —S—, —S—S—, —S(O)—, and —(O)S(O)—; and R is hydrocarbyl with 1 to 6 carbon atoms.

9 . The additive of claim 1 , wherein the bismaleimide monomer is selected from the group consisting of N,N′-bismaleimide-4,4′-diphenyl-methane, 1,1′-(methylene-di-4,1-phenylene)-bismaleimide, N,N′-(1,1′-diphenyl-4,4′-dimethylene)-bismaleimide, N,N′-(4-methyl-1,3-phenylene)-bismaleimide, 1,1′-(3,3′-dimethyl-1,1′-diphenyl-4,4′-dimethylene)-bismaleimide, N,N′-ethenyl-bismaleimide, N,N′-butenyl-bismaleimide, N,N′-(1,2-phenylene)-bismaleimide, N,N′-(1,3-phenylene)-bismaleimide, N,N′-bismaleimide sulfide, N,N′-bismaleimide disulfide, keto-N,N′-bismaleimide, N,N′-methylene-bismaleimide, bismaleimide-methyl-ether, 1,2-bismaleimide-1,2-glycol, N,N′-4,4′-diphenyl-ether-bismaleimide, 4,4′-bismaleimide-diphenyl sulfone and combinations thereof.

10 . The additive of claim 1 , wherein a molar ratio of the maleimide type monomer to the organic diamine type compound is (0.5 to 4):1.

11 . The additive of claim 1 , wherein a molecular weight of the polymer is in a range from about 1000 to about 500000.

12 . An electrolyte liquid comprising an electrolyte salt, a non-aqueous solvent, and an additive, wherein the additive is a polymer obtained by polymerizing of a maleimide type monomer with an organic diamine type compound;
the maleimide type monomer is selected from the group consisting of a maleimide monomer, a bismaleimide monomer, a multimaleimide monomer, a maleimide type derivative monomer, and combinations thereof; the organic diamine type compound is represented by formula III or formula IV:

wherein R 3 is a bivalent organic substituent and R 4 is another bivalent organic substituent;
the non-aqueous solvent comprises propylene carbonate.

13 . The electrolyte liquid of claim 12 , wherein a mass-volume concentration of the additive in the electrolyte liquid is about 0.01% to about 10%.

14 . The electrolyte liquid of claim 12 , wherein the non-aqueous solvent further comprises at least one of ethylene carbonate, diethyl carbonate, propylene carbonate, dimethyl carbonate, ethyl methyl carbonate, butylene carbonate, gamma-butyrolactone, gamma-valerolactone, dipropyl carbonate, N-methyl pyrrolidone, N-methylformamide, N-methylacetamide, N,N-dimethylformamide, N,N-diethylformamide, diethyl ether, acetonitrile, propionitrile, anisole, succinonitrile, adiponitrile, glutaronitrile, dimethyl sulfoxide, dimethyl sulfite, vinylene carbonate, ethyl methyl carbonate, dimethyl carbonate, diethyl carbonate, fluoroethylene carbonate, chloropropylene carbonate, acetonitrile, succinonitrile, methoxymethylsulfone, tetrahydrofuran, 2-methyltetrahydrofuran, epoxy propane, methyl acetate, ethyl acetate, propyl acetate, methyl butyrate, ethyl propionate, methyl propionate, 1,3-dioxolane, 1,2-diethoxyethane, 1,2-dimethoxyethane, and 1,2-dibutoxy.

15 . The electrolyte liquid of claim 12 , wherein the electrolyte salt is selected from the group consisting of lithium chloride, lithium hexafluorophosphate, lithium tetrafluoroborate, lithium methanesulfonate, lithium trifluoromethanesulfonate, lithium hexafluoroarsenate, lithium hexafluoroantimonate, lithium perchlorate, Li[BF 2 (C 2 O 4 )], Li[PF 2 (C 2 O 4 ) 2 ], Li[N(CF 3 SO 2 ) 2 ], Li[C(CF 3 SO 2 ) 3 ], lithium bisoxalatoborate (LiBOB), and combinations thereof.

16 . A lithium ion battery comprising a cathode, an anode, a separator, and an electrolyte liquid, wherein the electrolyte liquid comprising an electrolyte salt, a non-aqueous solvent, and an additive;
the additive is a polymer obtained by polymerizing of a maleimide type monomer with an organic diamine type compound; the maleimide type monomer is selected from the group consisting of a maleimide monomer, a bismaleimide monomer, a multimaleimide monomer, a maleimide type derivative monomer, and combinations thereof; the organic diamine type compound is represented by formula III or formula IV:
H 2 N—R 3 —NH 2   III

wherein R 3 is a bivalent organic substituent and R 4 is another bivalent organic substituent;
the non-aqueous solvent comprises propylene carbonate.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• Qian guan-nan
• He xiang-ming
• Shang yu-ming
• Li Jian-Jun
• Wang Li
• Gao Jian
• Yang ju-ping
• Wang yao-wu
• Zhao Peng

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2300/0025

  Organic electrolyte · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0569

  characterised by the solvents · CPC title