Electrochemical process for gas separation

Patent metadata

Field	Value
Publication number	US-2017113182-A1
Application number	US-201615335258-A
Country	US
Kind code	A1
Filing date	Oct 26, 2016
Priority date	Oct 27, 2015
Publication date	Apr 27, 2017
Grant date	—

Abstract

The present disclosure generally relates to apparatuses, systems, and methods for separating a target species (e.g., CO 2 ) from a gas mixture (e.g., gas stream) via an electrochemical process.

First claim

What is claimed is:

1 . An electrochemical cell, comprising:
a first negative electrode and a second negative electrode, each comprising a gas permeable layer and a primary electroactive composite layer; a positive electrode positioned between the first and second negative electrodes and comprising a first complementary electroactive composite layer facing the first negative electrode and a second complementary electroactive composite layer facing the second negative electrode; a first separator positioned between the first negative electrode and the positive electrode; and a second separator positioned between the second negative electrode and the positive electrode, wherein each of the first and second separators is able to be saturated with an ionic liquid.

2 . The electrochemical cell of claim 1 , wherein the primary electroactive composite layer comprises a first electroactive species capable of bonding with carbon dioxide gas, when the first electroactive species is in a reduced state, and releasing carbon dioxide gas, when the first electroactive species is in an oxidized state.

3 . The electrochemical cell of claim 1 , wherein the primary electroactive composite layer comprises a first electroactive species that in a reduced state has a binding constant with carbon dioxide of 10 1 to 10 3 M −1 .

4 . The electrochemical cell of claim 1 , wherein the primary electroactive composite layer comprises a first electroactive species comprising polyanthraquinone.

5 . The electrochemical cell of claim 1 , wherein the complementary electroactive composite layer comprises a second electroactive species comprising polyvinyl ferrocene.

6 . The electrochemical cell of claim 1 , wherein the primary electroactive composite layer comprises a first immobilized polymeric composite of a first electroactive species and of a first carbonaceous material.

7 . The electrochemical cell of claim 6 , wherein the complementary electroactive composite layer comprises a second immobilized polymeric composite of a second electroactive species and of a second carbonaceous material.

8 . The electrochemical cell of claim 1 , wherein the positive electrode further comprises a substrate layer positioned between the first and second complementary electroactive composite layers.

9 . The electrochemical cell of claim 1 , wherein each of the first and second separators is saturated with a room temperature ionic liquid.

10 . The electrochemical cell of claim 1 , wherein the room temperature ionic liquid comprises Bmim BF 4 .

11 . A gas separation system, comprising:
a plurality of electrochemical cells in fluid communication with a gas inlet and a gas outlet, each of the plurality of electrochemical cells comprising:
a first porous negative electrode and a second porous negative electrode, each comprising a first electroactive species;
a positive electrode comprising a second electroactive species;
a first separator positioned between the first porous negative electrode and the positive electrode; and
a second separator positioned between the second porous negative electrode and the positive electrode, wherein each of the first and second separators is able to be saturated with an ionic liquid.

12 . The gas separation system of claim 11 , wherein the first electroactive species is immobilized in a first polymeric composite.

13 . The gas separation system of claim 12 , wherein the second electroactive species is immobilized in a second polymeric composite.

14 . The gas separation system of claim 11 , wherein the first electroactive species comprises polyanthraquinone.

15 . The gas separation system of claim 14 , wherein the second electroactive species comprising polyvinyl ferrocene.

16 . The gas separation system of claim 11 , further comprising an external circuit connecting the first and second porous negative electrodes and the positive electrode of each electrochemical cell to a power source configured to apply a potential difference across the first and second negatives electrodes and the positive electrode of each electrochemical cell.

17 . A method of treating a gas stream, the method comprising:
applying a first potential difference across an electrochemical cell, the electrochemical cell comprising:
at least one porous negative electrode comprising a first electroactive species;
a positive electrode comprising a second electroactive species; and
a separator saturated with a conductive liquid and positioned between the at least one porous negative electrode and the positive electrode; and
introducing a gas stream comprising a target species to the electrochemical cell to bond the target species to the first electroactive species to produce a treated gas stream.

18 . The method of claim 17 , wherein the target species comprises CO 2 .

19 . The method of claim 17 , further comprising applying a second potential difference across the electrochemical cell to release the target species from the first electroactive species to produce a target species-rich gas stream.

20 . The method of claim 17 , wherein the first electroactive species comprises polyanthraquinone.

Assignees

• Massachusetts Inst Technology

Inventors

• Voskian Sahag
• Hatton Trevor Alan

Classifications

• B01D2257/504

  Carbon dioxide · CPC title

• B01D53/326 Primary

  in electrochemical cells · CPC title

• C25B13/04

  characterised by the material · CPC title

• C25B11/085

  Organic compound · CPC title

• C25B9/19

  with diaphragms · CPC title