Three-Dimensional (3D) Printed Mortar and Preparation Method Therefor, and 3D Printing Method for Mortar
US-2024190039-A1 · Jun 13, 2024 · US
US2017081244A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017081244-A1 |
| Application number | US-201415123025-A |
| Country | US |
| Kind code | A1 |
| Filing date | Mar 3, 2014 |
| Priority date | Mar 3, 2014 |
| Publication date | Mar 23, 2017 |
| Grant date | — |
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In order to address the technical problem of allowing an unshaped refractory material using a spinel-containing alumina cement to provide further improved corrosion resistance and slag infiltration resistance while reducing the occurrence of crack/peeling, an unshaped refractory material is provided which comprises a refractory raw material mixture having a particle size of 8 mm or less, with the refractory raw material mixture having an alumina cement at least a part of which is a spinel-containing alumina cement, and, with respect to 100 mass % of the refractory raw material mixture, the alumina cement contains CaO in an amount of 0.5 to 2.5 mass %, and the spinel-containing alumina cement contains spinel in an amount of 3.5 to 10.5 mass %.
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1 . An unshaped refractory material comprising a refractory raw material mixture having a particle size of 8 mm or less, the refractory raw material mixture comprising an alumina cement at least a part of which is a spinel-containing alumina cement, wherein, with respect to 100 mass % of the refractory raw material mixture, the alumina cement contains CaO in an amount of 0.5 to 2.5 mass %, and the spinel-containing alumina cement contains spinel in an amount of 3.5 to 10.5 mass %. 2 . The unshaped refractory material of claim 1 , wherein the refractory raw material mixture further comprises a spinel raw material having a particle size of 0.1 mm or less, and wherein a total content of the spinel raw material and the spinel contained in the spinel-containing alumina cement is in the range of 5.5 to 22 mass %, with respect to 100 mass % of the refractory raw material mixture. 3 . The unshaped refractory material of claim 1 , wherein the refractory raw material mixture further comprises a magnesia raw material having a particle size of 0.1 mm or less, and wherein a content of the magnesia raw material is in the range of 2 to 9 mass %, with respect to 100 mass % of the refractory raw material mixture. 4 . The unshaped refractory material of claim 1 , wherein the refractory raw material mixture further comprises calcined alumina having a particle size of 3 μm or less, and wherein a content of the calcined alumina is 10 mass % or less, with respect to 100 mass % of the refractory raw material mixture. 5 . The unshaped refractory material of claim 1 , wherein the refractory raw material mixture further comprises calcined alumina having a particle size of 3 μm or less, and wherein a content of the calcined alumina is less than 4 mass %, with respect to 100 mass % of the refractory raw material mixture. 6 . The unshaped refractory material of claim 1 , wherein the refractory raw material mixture further comprises at least one of an alumina raw material and a spinel raw material each having a particle size of greater than 0.1 mm to 8 mm, and wherein a total content of the at least one of the alumina raw material and the spinel raw material is in the range of 50 to 75 mass %, with respect to 100 mass % of the refractory raw material mixture. 7 . The unshaped refractory material of claim 2 , wherein the refractory raw material mixture further comprises calcined alumina having a particle size of 3 μm or less, and wherein a content of the calcined alumina is 10 mass % or less, with respect to 100 mass % of the refractory raw material mixture. 8 . The unshaped refractory material of claim 3 , wherein the refractory raw material mixture further comprises calcined alumina having a particle size of 3 μm or less, and wherein a content of the calcined alumina is 10 mass % or less, with respect to 100 mass % of the refractory raw material mixture. 9 . The unshaped refractory material of claim 2 , wherein the refractory raw material mixture further comprises calcined alumina having a particle size of 3 μm or less, and wherein a content of the calcined alumina is less than 4 mass %, with respect to 100 mass % of the refractory raw material mixture. 10 . The unshaped refractory material of claim 3 , wherein the refractory raw material mixture further comprises calcined alumina having a particle size of 3 μm or less, and wherein a content of the calcined alumina is less than 4 mass %, with respect to 100 mass % of the refractory raw material mixture. 11 . The unshaped refractory material of claim 2 , wherein the refractory raw material mixture further comprises at least one of an alumina raw material and a spinel raw material each having a particle size of greater than 0.1 mm to 8 mm, and wherein a total content of the at least one of the alumina raw material and the spinel raw material is in the range of 50 to 75 mass %, with respect to 100 mass % of the refractory raw material mixture. 12 . The unshaped refractory material of claim 3 , wherein the refractory raw material mixture further comprises at least one of an alumina raw material and a spinel raw material each having a particle size of greater than 0.1 mm to 8 mm, and wherein a total content of the at least one of the alumina raw material and the spinel raw material is in the range of 50 to 75 mass %, with respect to 100 mass % of the refractory raw material mixture. 13 . The unshaped refractory material of claim 4 , wherein the refractory raw material mixture further comprises at least one of an alumina raw material and a spinel raw material each having a particle size of greater than 0.1 mm to 8 mm, and wherein a total content of the at least one of the alumina raw material and the spinel raw material is in the range of 50 to 75 mass %, with respect to 100 mass % of the refractory raw material mixture. 14 . The unshaped refractory material of claim 5 , wherein the refractory raw material mixture further comprises at least one of an alumina raw material and a spinel raw material each having a particle size of greater than 0.1 mm to 8 mm, and wherein a total content of the at least one of the alumina raw material and the spinel raw material is in the range of 50 to 75 mass %, with respect to 100 mass % of the refractory raw material mixture.
containing refractory metal compounds other than those covered by C04B35/103 - C04B35/106 · CPC title
millimeter or submillimeter sized, i.e. larger than 0,1 mm · CPC title
Magnesium oxides or oxide-forming salts thereof · CPC title
submicron sized, i.e. from 0,1 to 1 micron · CPC title
Calcium oxide or oxide-forming salts thereof, e.g. lime · CPC title
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