Method for evaluating weatherability of fluorinated coating film

Patent metadata

Field	Value
Publication number	US-2017038293-A1
Application number	US-201615298687-A
Country	US
Kind code	A1
Filing date	Oct 20, 2016
Priority date	Jun 9, 2014
Publication date	Feb 9, 2017
Grant date	—

Abstract

To provide a method for evaluating the weather resistance by which the weather resistance of a fluorinated coating film can be evaluated accurately in a short time.
A method for evaluating the weather resistance of a fluorinated coating film, which comprises a fluorinated coating film deterioration step (I) comprising a step (ia) of exposing the fluorinated coating film to xenon arc radiation and a step (ib) of attaching an aqueous hydrogen peroxide solution to the fluorinated coating film under xenon arc radiation to wet the fluorinated coating film, and an evaluation step (II) of comparing characteristics of the fluorinated coating film as between before and after the deterioration step (I) to evaluate the weather resistance of the fluorinated coating film.

First claim

What is claimed is:

1 . A method for evaluating the weather resistance of a fluorinated coating film, which comprises a fluorinated coating film deterioration step (I) comprising a step (ia) of exposing the fluorinated coating film to xenon arc radiation and a step (ib) of attaching an aqueous hydrogen peroxide solution to the fluorinated coating film under xenon arc radiation to wet the fluorinated coating film, and an evaluation step (II) of comparing characteristics of the fluorinated coating film as between before and after the deterioration step (I) to evaluate the weather resistance of the fluorinated coating film.

2 . The method for evaluating the weather resistance according to claim 1 , wherein the irradiance of the xenon arc radiation in the step (ia) is from 50 to 400 W/m 2 within a wavelength range of from 300 to 400 nm.

3 . The method for evaluating the weather resistance according to claim 1 , wherein in the step (ib), the concentration of the aqueous hydrogen peroxide solution is from 0.05 to 10.0 mass %.

4 . The method for evaluating the weather resistance according to claim 1 , wherein the step (ib) is carried out more than once.

5 . The method for evaluating the weather resistance according to claim 1 , which further comprises a drying step (ic) after the step (ib) is carried out and before the evaluation step (II) is carried out.

6 . The method for evaluating the weather resistance according to claim 1 , wherein the weather resistance is evaluated by at least one selected from the group consisting of glossiness, color difference, outer appearance of the coating film by observation with a scanning electron microscope, mapping of F atoms and titanium atoms by energy dispersive X-ray spectroscopy, and peak variation of fluororesin by infrared analysis.

7 . The method for evaluating the weather resistance according to claim 1 , wherein the total time of the xenon arc radiation is from 1 to 10,000 hours.

8 . The method for evaluating the weather resistance according to claim 1 , wherein the fluorinated coating film contains at least one fluororesin in an amount of at least 5 mass % in the fluorinated coating film (100 mass %), and has a film thickness of from 10 to 100 μm.

9 . The method for evaluating the weather resistance according to claim 1 , wherein the fluorinated coating film is formed by using a powder coating material, a solvent-based coating material or an aqueous coating material.

10 . A method for producing a fluorinated coating film, which comprises forming a fluorinated coating film on a substrate, evaluating the weather resistance of the fluorinated coating film by the method for evaluating the weather resistance as defined in claim 1 , and selecting a fluorinated coating film which has achieved an optional standard of weather resistance by the evaluation.

Assignees

• Asahi Glass Compay Ltd
• Asahi Glass Co Ltd

Inventors

• Saito Shun
• Alkawa Masataka

Classifications

• G01N17/00 Primary

  Investigating resistance of materials to the weather, to corrosion, or to light · CPC title

• B05D3/06

  by exposure to radiation (B05D3/02 takes precedence {; plasma treatment B05D3/141}) · CPC title

• B05D1/02

  performed by spraying · CPC title

• B05D3/067

  Curing or cross-linking the coating · CPC title

• B05D3/00

  Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials (successively applying liquids or other fluent materials B05D1/36; drying ovens F26B) · CPC title