System and method for measuring concentration of a trace gas in a gas mixture

Patent metadata

Field	Value
Publication number	US-2017003218-A1
Application number	US-201414278335-A
Country	US
Kind code	A1
Filing date	May 15, 2014
Priority date	May 15, 2014
Publication date	Jan 5, 2017
Grant date	—

Abstract

A method includes receiving a gas mixture at a first pressure including at least a primary gas and a secondary gas and changing a pressure of the received gas mixture from the first pressure to a second pressure. Further, the method includes determining a spectra of the gas mixture at the second pressure, wherein at least the first spectral line of the primary gas is spectrally distinguished from at least the second spectral line of the secondary gas, identifying a peak wavelength associated with the spectrally distinguished first spectral line of the primary gas based on at least two wavelengths of the secondary gas corresponding to at least two peak amplitudes in the spectra of the gas mixture, and determining a concentration of the primary gas based on the identified peak wavelength associated with the spectrally distinguished first spectral line of the primary gas.

First claim

1 . A method comprising:
receiving in a cell unit a gas mixture at a first pressure comprising at least a primary gas and a secondary gas, wherein at least a first spectral line of the primary gas interferes with at least a second spectral line of the secondary gas at the first pressure of the gas mixture; changing a pressure of the received gas mixture in the cell unit from the first pressure to a second pressure; using a sensor unit for determining a spectra of the gas mixture at the second pressure, wherein at least the first spectral line of the primary gas is spectrally distinguished from at least the second spectral line of the secondary gas, identifying a peak wavelength associated with the spectrally distinguished first spectral line of the primary gas based on at least two wavelengths of the secondary gas corresponding to at least two peak amplitudes in the spectra of the gas mixture, and determining a concentration of the primary gas based on the identified peak wavelength associated with the spectrally distinguished first spectral line of the primary gas.

2 . The method of claim 1 , wherein determining the spectra of the gas mixture at the second pressure comprises determining a derivative of the spectra effective to spectrally distinguish the first spectral line of the primary gas from the second spectral line of the secondary gas.

3 . The method of claim 2 , wherein determining the concentration of the primary gas comprises computing a peak amplitude in the derivative of the spectra at the identified peak wavelength associated with the spectrally distinguished first spectral line of the primary gas.

4 . The method of claim 2 , wherein determining the derivative of the spectra comprises computing a second derivative of the spectra to spectrally distinguish the first spectral line of the primary gas from the second spectral line of the primary gas.

5 . The method of claim 2 , wherein identifying the peak wavelength associated with the spectrally distinguished first spectral line of the primary gas comprises:
selecting the at least two wavelengths of the secondary gas in the derivative of the spectra; adjusting the derivative of the spectra such that the at least two peak wavelengths of the secondary gas match pre-stored peak wavelengths; and detecting the peak wavelength associated with the spectrally distinguished first spectral line of the primary gas based on the at least two peak wavelengths of the secondary gas in the adjusted derivative of the spectra.

6 . The method of claim 5 , wherein selecting the at least two peak wavelengths of the secondary gas in the derivative of the spectra comprises:
searching the at least two peak amplitudes of the secondary gas in the derivative of the spectra in one or more ranges including the pre-stored wavelengths; and selecting the at least two peak wavelengths corresponding to the at least two peak amplitudes of the secondary gas.

7 . The method of claim 5 , wherein detecting the peak wavelength associated with the spectrally distinguished first spectral line of the primary gas comprises:
searching for a peak wavelength in the adjusted derivative of the spectra within a wavelength range including a prestored peak wavelength of the primary gas; and representing the searched peak wavelength as the peak wavelength associated with the spectrally distinguished first spectral line of the primary gas.

8 . The method of claim 2 , wherein identifying the peak wavelength associated with the spectrally distinguished first spectral line of the primary gas comprises:
selecting the at least two peak wavelengths of the secondary gas in the derivative of the spectra; determining spectral separation between the at least two peak wavelengths of the secondary gas; and identifying the peak wavelength associated with the spectrally distinguished first spectral line of the primary gas based on the determined spectral separation between the at least two peak wavelengths of the secondary gas.

9 . The method of claim 8 , wherein the peak wavelength associated with the spectrally distinguished first spectral line of the primary gas is identified within the determined spectral separation at a location that is corresponding to a predefined function of the determined spectral separation.

10 . The method of claim 1 , wherein determining the concentration of the primary gas comprises recalibrating the sensor unit to determine the concentration of the primary gas.

11 . The method of claim 10 , wherein recalibrating the sensor unit comprises:
measuring an initial concentration of the primary gas at the second pressure of the gas mixture; reducing the pressure of the received gas mixture from the second pressure to a third pressure where the primary gas begins to become undetectable; calculating an actual concentration of the primary gas based on the third pressure of the gas mixture; and adjusting the sensor unit to measure the determined actual concentration of the primary gas at the second pressure of the gas mixture.

12 . The method of claim 11 , wherein calculating the actual concentration of the primary gas comprises estimating the actual concentration of the primary gas by using a pre-stored data corresponding to the third pressure of the gas mixture, wherein the pre-stored data indicates the actual concentration of the primary gas that becomes undetectable at the third pressure of the gas mixture.

13 . A system comprising:
a cell unit for receiving a gas mixture at a first pressure comprising at least a primary gas and a secondary gas, wherein at least a first spectral line of the primary gas interferes with at least a second spectral line of the secondary gas at the first pressure of the gas mixture; a pumping unit coupled to the cell unit for changing a pressure of the received gas mixture from the first pressure to a second pressure; and a control unit for:
determining a derivative of a spectra of the gas mixture at the second pressure, wherein at least the first spectral line of the primary gas is spectrally distinguished from at least the second spectral line of the secondary gas;
identifying a peak wavelength associated with the spectrally distinguished first spectral line of the primary gas based on at least two peak wavelengths of the secondary gas corresponding to at least two peak amplitudes in the derivative of the spectra; and
determining a concentration of the primary gas based on the identified peak wavelength associated with the spectrally distinguished first spectral line of the primary gas.

14 . The system of claim 13 further comprising:
a light source for emitting a beam;
a beam splitter for splitting the emitted beam into a first beam and a second beam, wherein the first beam is passed through the cell unit;
a first detector coupled to the cell unit for providing a first electrical signal corresponding to the determined derivative spectra of the gas mixture to the control unit;
a second detector coupled to the beam splitter for:
receiving the second beam from the beam splitter;
providing a second electrical signal corresponding to the received second beam to the control unit.

15 . The system of claim 14 , wherein the control unit comprises:
an amplifying unit coupled to the first detector and the second detector for amplifying the first electrical signal and the second electrical signal; a subtraction unit coupled to the amplifying unit for reducing noise in the amplified first electrical signal by subtracting the amplified first electrical signal with the amplified second electrical signal; and a lock-in unit c

Assignees

• Gen Electric

Inventors

• Sharma Rachit
• Mitra Chayan
• Maity Sandip
• Tilak Vinayak
• Liu Xiaoyong
• Kowal Anthony
• Tao Chong

Classifications

• G01N21/274

  Calibration, base line adjustment, drift correction · CPC title

• G01N2021/399

  Diode laser · CPC title

• G01N2201/1218

  for pressure variations · CPC title

• G01N21/39 Primary

  using tunable lasers · CPC title

• G01N33/004

  CO or CO2 · CPC title