Tire with tread for combination of low temperature performance and for wet traction

Patent metadata

Field	Value
Publication number	US-2016376428-A1
Application number	US-201514748343-A
Country	US
Kind code	A1
Filing date	Jun 24, 2015
Priority date	Jun 24, 2015
Publication date	Dec 29, 2016
Grant date	—

Abstract

This invention relates to a tire with tread for promoting a combination of wet traction and service at low temperatures of a rubber composition containing a styrene/butadiene elastomer, cis 1,4-polybutadiene rubber, liquid high Tg styrene/butadiene polymer, resin and vegetable triglyceride oil.

First claim

1 . A pneumatic tire having a circumferential rubber tread of a sulfur cured rubber composition comprised of, based on parts by weight per 100 parts by weight elastomer (phr):
(A) 100 phr of at least one diene-based elastomer comprised of;
(1) about 25 to about 75 phr of a styrene/butadiene elastomer having a Tg in a range of from about −35° C. to about −5° C.,
(2) about 25 to about 75 phr of high cis 1,4-polybutadiene rubber having a Tg in a range of from about −100° C. to about −109° C.,
(3) about 3 to about 50 phr of low molecular weight liquid styrene/butadiene polymer having a number average molecular weight in a range of from about 3,000 to about 30,000 and a Tg in a range of from −25° C. to about −5° C.,
(B) about 50 to about 250 phr of rubber reinforcing filler comprised of a combination of precipitated silica and rubber reinforcing carbon black in a ratio of precipitated silica to rubber reinforcing carbon black of at least 9/1, together with silica coupling agent having a moiety reactive with hydroxyl groups on said precipitated silica and another different moiety interactive with said diene-based elastomers and polymer, (C) about 7.5 to about 25 phr of traction resin consisting of styrene-alphamethylstyrene resin having a softening point in a range of from about 60° C. to about 80° C. and a styrene content of from about 10 to about 30 percent, and (D) about 10 to about 50 phr of vegetable triglyceride oil comprised of soybean oil, wherein said styrene/butadiene elastomer is a tin coupled functionalized elastomer having functional groups comprised of at least one of siloxy, amine and thiol groups reactive with hydroxyl groups on said precipitated silica, wherein said precipitated silica and silica coupling agent are provided as a pre-reacted composite thereof, and wherein said silica coupling agent is comprised of at least one of a bis(3-triethoxysilylpropyl) polysulfide containing an average of from about 2 to about 4 sulfur atoms in its connecting polysulfidic bridge and an organoalkoxymercaptosilane.

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9 . The tire of claim 1 wherein said tread rubber composition further contains up to 25 phr of at least one additional diene based elastomer.

10 . The tire of claim 9 wherein said additional elastomer is comprised of at least one of cis 1,4-polyisoprene, isoprene/butadiene, styrene/isoprene and 3,4-polyisoprene rubber.

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21 . The tire of claim 1 wherein said silica coupling agent for said pre-reacted composite of precipitated silica and coupling agent is an alkoxyorganomercaptosilane.

Assignees

• Goodyear Tire & Rubber

Inventors

• Sandstrom Paul Harry
• Thielen Georges Marcel Victor
• Steiner Pascal Patrick
• Isitman Nihat Ali

Classifications

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L9/06 Primary

  Copolymers with styrene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L91/00

  Compositions of oils, fats or waxes; Compositions of derivatives thereof · CPC title