Liquid Electrolyte Composition, and Electrochemical Cell Comprising Said Electrolyte Composition
US-2024347772-A1 · Oct 17, 2024 · US
US2016372791A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016372791-A1 |
| Application number | US-201514746761-A |
| Country | US |
| Kind code | A1 |
| Filing date | Jun 22, 2015 |
| Priority date | Jun 22, 2015 |
| Publication date | Dec 22, 2016 |
| Grant date | — |
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Electrolyte formulations including additives or combinations of additives. The electrolyte formulations are useful in lithium ion battery cells having lithium titanate anodes. The electrolyte formulations provide low temperature power performance and high temperature stability in such lithium ion battery cells.
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1 . A lithium ion battery cell, comprising: a first electrode; a second electrode comprising a lithium titanate active material; and an electrolyte formulation comprising LiPF 6 and comprising a first additive, wherein the first additive comprises tris(2,2,2-trifluoroethyl)borate, and a second additive, wherein the second additive comprises a fluorinated compound other than tris(2,2,2-trifluoroethyl)borate. 2 . The lithium ion battery cell of claim 1 , wherein the second additive comprises a fluorinated borate. 3 . The lithium ion battery cell of claim 1 , wherein the second additive comprises a fluorinated oxaborolane. 4 . The lithium ion battery cell of claim 3 , wherein the second additive comprises 4,4,5,5-tetramethyl-2-(4-trifluoromethylphenyl)-1,3,2-dioxaborolane. 5 . The lithium ion battery cell of claim 1 , wherein the second additive comprises a fluorinated ester. 6 . The lithium ion battery cell of claim 5 , wherein the second additive comprises ethyl difluoroacetate. 7 . The lithium ion battery cell of claim 1 , wherein the second additive comprises a fluorinated phosphonate. 8 . The lithium ion battery cell of claim 7 , wherein the second additive comprises diethyl (difluoromethyl)phosphonate. 9 . The lithium ion battery cell of claim 1 , wherein the second additive comprises a fluorinated phosphate. 10 . The lithium ion battery cell of claim 9 , wherein the second additive comprises tris(2,2,2-trifluoroethyl)phosphate. 11 . The lithium ion battery cell of claim 1 , wherein the second additive comprises a fluorinated carbonate. 12 . The lithium ion battery cell of claim 11 , wherein the second additive comprises methyl 2,2,2-trifluoroethyl carbonate. 13 . A lithium ion battery cell, comprising: a first electrode; a second electrode comprising a lithium titanate active material; and an electrolyte formulation comprising LiPF 6 and comprising a first additive, wherein the first additive comprises tris(2,2,2-trifluoroethyl)phosphate, and a second additive, wherein the second additive comprises a fluorinated compound other than tris(2,2,2-trifluoroethyl)phosphate. 14 . The lithium ion battery cell of claim 13 , wherein the second additive comprises a fluorinated borate. 15 . The lithium ion battery cell of claim 1 , wherein the second additive comprises a fluorinated oxaborolane. 16 . The lithium ion battery cell of claim 15 , wherein the second additive comprises 4,4,5,5-tetramethyl-2-(4-trifluoromethylphenyl)-1,3,2-dioxaborolane. 17 . The lithium ion battery cell of claim 13 , wherein the second additive comprises a fluorinated ester. 18 . The lithium ion battery cell of claim 17 , wherein the second additive comprises ethyl difluoroacetate. 19 . The lithium ion battery cell of claim 13 , wherein the second additive comprises a fluorinated phosphonate. 20 . The lithium ion battery cell of claim 19 , wherein the second additive comprises diethyl (difluoromethyl)phosphonate. 21 . A lithium ion battery cell, comprising: a first electrode; a second electrode comprising a lithium titanate active material; and an electrolyte formulation comprising LiPF 6 and comprising a first additive, wherein the first additive comprises methyl 2,2,2-trifluoroethyl carbonate, and a second additive, wherein the second additive comprises a fluorinated compound other than methyl 2,2,2-trifluoroethyl carbonate. 22 . The lithium ion battery cell of claim 21 , wherein the second additive comprises a fluorinated borate. 23 . The lithium ion battery cell of claim 21 , wherein the second additive comprises a fluorinated oxaborolane. 24 . The lithium ion battery cell of claim 23 , wherein the second additive comprises 4,4,5,5-tetramethyl-2-(4-trifluoromethylphenyl)-1,3,2-dioxaborolane. 25 . The lithium ion battery cell of claim 21 , wherein the second additive comprises a fluorinated ester. 26 . The lithium ion battery cell of claim 25 , wherein the second additive comprises ethyl difluoroacetate. 27 . The lithium ion battery cell of claim 21 , wherein the second additive comprises a fluorinated phosphonate. 28 . The lithium ion battery cell of claim 27 , wherein the second additive comprises diethyl (difluoromethyl)phosphonate.
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
Organic electrolyte · CPC title
of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title
characterised by the additives · CPC title
Energy storage using batteries · CPC title
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