Method for preparing alkali metal bicarbonate particles

Patent metadata

Field	Value
Publication number	US-2016368779-A1
Application number	US-201414900514-A
Country	US
Kind code	A1
Filing date	Jun 26, 2014
Priority date	Jun 26, 2013
Publication date	Dec 22, 2016
Grant date	—

Abstract

A method for preparing alkali metal bicarbonate particles by crystallization from an alkali metal carbonate and/or bicarbonate solution with an additive present in the solution, chosen from among sulfates, sulfonates, polysulfonates, amines, hydroysultaines, polycarboxylates, polysaccharides, polyethers and ether-phenols, alkali metal hexametaphosphate, phosphates, sulfosuccinates, amidosulfonates, amine sulfonates, preferably chosen from among polysaccharides, and such that the additive is present in the solution at a concentration of at least 1 ppm and preferably at most 200 ppm.

First claim

1 . A method for preparing, by crystallization, alkali metal bicarbonate particles starting from a solution of alkali metal carbonate and/or bicarbonate in the presence of an additive in the solution, wherein:
the additive is selected from group consisting of:
sulfates, in particular sodium sulfate and organosulfates;
sulfonates;
polysulfonates;
amines, in particular primary amines, cyclic amines, quaternary amines comprising at least one carboxylic acid group;
hydroxysultaines;
polycarboxylates;
polyethers and ether-phenols;
sulfosuccinates;
amidosulfonates;
aminosulfonates;
alkali metal hexametaphosphate in particular of sodium or potassium; and
phosphates, in particular organophosphates, and phosphonates;
and the additive is present in the solution at a concentration of at least 1 ppm.

2 . A method for preparing, by crystallization, alkali metal bicarbonate particles starting from a solution of alkali metal carbonate and/or bicarbonate in the presence of an additive in the solution,
wherein the additive is a polysaccharide; and wherein the additive is present in the solution at a concentration of at least 1 ppm.

3 . The method as claimed in claim 2 , wherein the additive is a guar gum or a derivative thereof.

4 . The method as claimed in claim 2 , wherein the additive is alginic acid or salts thereof.

5 . The method as claimed in claim 2 , wherein the additive is carboxymethylcellulose.

6 . The method as claimed in claim 2 , wherein the additive is present in the solution at a concentration of at most 200 ppm.

7 . The method as claimed in claim 2 , wherein crystallization of the alkali metal bicarbonate particles is carried out by cooling the solution.

8 . The method as claimed in claim 7 , wherein cooling of the solution is carried out between 70° and 30° C.

9 . The method as claimed in claim 2 , wherein crystallization of the alkali metal bicarbonate particles is carried out by carbonation of the solution with carbon dioxide.

10 . The method as claimed in claim 9 , wherein carbonation of the solution is carried out at a temperature of at least 20° C.

11 . The method as claimed in claim 2 , wherein crystallization of the alkali metal bicarbonate particles is carried out by evaporation of at least a portion of the solution.

12 . The method as claimed in claim 2 , wherein crystallization of the alkali metal bicarbonate particles is carried out by concomitant cooling and carbonation of the solution; or by concomitant cooling and carbonation and evaporation of the solution.

13 . The method as claimed in claim 9 , wherein carbonation of the solution with carbon dioxide is carried out with a gas comprising: 10 to 100% of CO 2 by volume based on dry gas.

14 . The method as claimed in claim 2 , being carried out at a temperature between 20° C. and 95° C.

15 . The method as claimed in claim 2 , wherein addition of the additive to the solution is carried out for controlling or modifying:
the granulometry, or the undersize or oversize on a sieve at 125 μm, or the undersize or oversize on a sieve at 250 μm,
of the alkali metal bicarbonate particles obtained after separation of the crystallization solution and of the alkali bicarbonate particles.

16 . The method as claimed in claim 2 , wherein addition of the additive to the solution is carried out for controlling or modifying:
the dissolution time, or the bulk density (BD), or the flow rate in a calibrated orifice, or the abrasion index,
of the alkali metal bicarbonate particles obtained after separation of the crystallization solution and of the alkali bicarbonate particles, then drying of the alkali metal bicarbonate particles.

17 . The method as claimed in claim 16 , wherein the additive is alginic acid or carboxymethylcellulose, wherein crystallization is carried out by cooling, and wherein addition of the additive to the solution makes it possible to increase the BD of the alkali metal bicarbonate particles by at least 10% relative to the BD of alkali metal bicarbonate particles obtained in the same conditions of crystallization but without addition of the additive.

18 . The method as claimed in claim 16 , wherein the additive is alginic acid, wherein crystallization is carried out by carbonation, and wherein addition of the additive to the solution makes it possible to increase the BD of the alkali metal bicarbonate particles by at least 10% relative to the BD of alkali metal bicarbonate particles obtained in the same conditions of crystallization but without addition of the additive.

19 . The method as claimed in claim 16 , wherein the additive is guar or a derivative such as hydroxypropylguar, or is carboxymethylcellulose, wherein crystallization is carried out by carbonation, and wherein addition of the additive to the solution makes it possible to reduce the BD of the alkali metal bicarbonate particles by at least 10% relative to the BD of alkali metal bicarbonate particles obtained in the same conditions of crystallization but without addition of the additive.

20 . The method as claimed in claim 2 , wherein the additive is selected from: alginic acid or carboxymethylcellulose, and wherein addition of the additive to the solution makes it possible to:
increase the granulometry or reduce the span, or reduce the sieve undersize at 125 μm, or increase the sieve oversize at 250 μm, or reduce the dissolution time, or increase the bulk density (BD), or reduce the abrasion index,
of the alkali metal bicarbonate particles relative to one and the same preparation effected without the additive.

21 . The method as claimed in claim 20 , wherein crystallization of the alkali metal bicarbonate particles is carried out by cooling and/or by carbonation.

22 . Alkali metal bicarbonate particles obtainable by the method as claimed in claim 2 and comprising at least 10 ppm of the additive

Assignees

• Solvay

Inventors

• Savary David Jean Lucien

Classifications

• C01P2006/11

  Powder tap density · CPC title

• C01P2004/51

  Particles with a specific particle size distribution · CPC title

• C01D7/40 Primary

  Influencing the crystallisation process · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01D7/24

  Crystallisation · CPC title