Photocatalysts

Patent metadata

Field	Value
Publication number	US-2016367968-A1
Application number	US-201415031738-A
Country	US
Kind code	A1
Filing date	Oct 24, 2014
Priority date	Oct 24, 2013
Publication date	Dec 22, 2016
Grant date	—

Abstract

The present invention provides photocatalysts capable of catalytic activity in the visible range of light comprising platinum group metal nanoparticles deposited on a metal oxide support. The nanoparticles have surface plasmon resonance in the visible range of light. The invention also provides processes for preparing the photocatalysts, methods of liquid and gas purification using the photocatalysts of the invention and devices for the same.

First claim

1 . A photocatalyst capable of catalytic activity in the visible range of light comprising amorphous platinum group metal nanoparticles on a metal oxide.

2 . A photocatalyst of claim 1 , wherein the nanoparticles have surface plasmon resonance in the visible range of light.

3 . A photocatalyst according to claim 1 wherein the nanoparticles are deposited on the metal oxide support, optionally by UV photodeposition.

4 . A photocatalyst according to claim 3 wherein the UV photodeposition is carried out for less than 30 minutes.

5 . A photocatalyst according to claim 1 wherein the nanoparticles have a size of between about 2 and about 5 nm.

6 . A photocatalyst according to claim 1 wherein the platinum group metal is platinum or palladium.

7 . A photocatalyst according to claim 1 wherein the metal oxide is a refractory metal oxide.

8 . A photocatalyst according to claim 7 , wherein the refractory metal oxide is titanium, chromium, zirconium, niobium, molybdenum, hafnium or tungsten.

9 . A photocatalyst according to claim 1 , wherein the metal oxide is a titanium metal oxide.

10 . A photocatalyst according to claim 9 , wherein the titanium metal oxide is TiO 2 .

11 . A photocatalyst according to claim 1 wherein the metal oxide is doped.

12 . A photocatalyst according to claim 11 , wherein the photocatalyst is doped with nitrogen.

13 . A purification device comprising a photocatalyst according to claim 1 .

14 . The purification device of claim 13 , wherein the device comprises a reaction chamber having an inlet and an outlet, and a source of visible light, and further wherein the photocatalyst is contained within the reaction chamber.

15 . The purification device of claim 14 , wherein the source of visible light is external to the reaction chamber and the reaction chamber is transparent to the visible light.

16 . The purification device of claim 14 , wherein the reaction chamber inlet and reaction chamber outlet comprise valves for controlling the flow of liquid or gas.

17 . The purification device of claim 14 , wherein the purification device further comprises a storage chamber for storing purified liquid or gas, wherein the storage chamber is in fluid communication with the reaction chamber via the reaction chamber outlet, optionally wherein the storage chamber further comprises a dispensing outlet having a valve.

18 . The purification device of claim 14 , further comprising:
a) a pump for feeding liquid or gas into the reaction chamber via the inlet; and/or b) a pump for expelling purified liquid or gas from the reaction chamber via the outlet.

19 . The purification device of claim 17 further comprising a pump for dispensing purified liquid or gas from the storage chamber via the dispensing outlet.

20 . The purification device of claim 16 , further comprising control means for controlling the flow of liquid or gas through the purification device, the control means being operably linked with one or more of the valves and/or pumps.

21 . The purification device of claim 14 , further comprising means for removing the photocatalyst from the purified liquid or gas.

22 . A hydrogen production device comprising a photocatalyst according to claim 1 .

23 . The hydrogen production device of claim 22 , wherein the device comprises a reaction chamber having a liquid inlet, a gas outlet, and a source of visible light, and further wherein the photocatalyst is contained within the reaction chamber.

24 . The hydrogen production device of claim 23 , further comprising a storage chamber in fluid communication with the reaction chamber for storing liberated hydrogen, optionally wherein the storage chamber further comprises a dispensing outlet having a valve.

25 . The hydrogen production device of claim 23 , wherein the reaction chamber further comprises a waste outlet.

26 . The hydrogen production device of claim 23 , further comprising valves to control the flow liquid into the reaction chamber via the liquid, the flow of gas out of the reaction chamber via the gas outlet, and/or the flow of waste through the waste outlet.

27 . The hydrogen production device of any claim 23 , further comprising:
a) a pump for feeding liquid into the reaction chamber via the liquid inlet; b) a pump for expelling liberated hydrogen gas via the gas outlet; c) a pump for expelling waste via the waste outlet, if present; and/or d) a pump for expelling purified gas from the storage chamber via the dispensing outlet, if present.

28 . The hydrogen production device of claim 23 , further comprising control means for controlling the flow of liquid or gas through the hydrogen production device, the control means being operably linked to one or more of the valves and/or pumps.

29 . A process for preparing a photocatalyst capable of catalytic activity in the visible range of light comprising depositing platinum group metal nanoparticles on a metal oxide.

30 . A process according to claim 29 , wherein the platinum group metal nanoparticles are deposited by irradiation.

31 . A process according to claim 30 wherein the irradiation is carried out by UV photodeposition and optionally the photodeposition is carried out for less than 30 minutes.

32 . A process according to claim 29 wherein the platinum group metal is in solution.

33 . A process according to claim 29 wherein the metal oxide is in the form of solid, optionally a powder or in crystalline form.

34 . A process according to claim 33 wherein the metal oxide solid is added to a solution of the platinum group metal.

35 . A process according to claim 29 wherein the photocatalyst is dried after irradiation.

36 . The process according to claim 29 , wherein the metal oxide is titanium dioxide.

37 . A process according to claim 29 , wherein the platinum group metal is palladium.

38 . A method of gas or liquid purification, sterilisation or decontamination, comprising mixing the liquid or gas with a photocatalyst of claim 1 , and applying visible light to the resulting mixture.

39 . The method of claim 38 , wherein the liquid is water.

40 . The method of claim 38 , wherein the gas is air.

41 . A photocatalyst obtainable according to the process of claim 29 .

Assignees

• Univ London Queen Mary

Inventors

• Guerrero Igor Larrosa
• Dunn Steven Colin
• Neto Armando Marsden Lacerda

Classifications

• B01J35/80

  characterised by their amorphous structures · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title