Zoned Exhaust System

Patent metadata

Field	Value
Publication number	US-2016367941-A1
Application number	US-201615183824-A
Country	US
Kind code	A1
Filing date	Jun 16, 2016
Priority date	Jun 18, 2015
Publication date	Dec 22, 2016
Grant date	—

Abstract

A catalytic article having a flow-through substrate having an inlet, an outlet, and an axial length; an SCR zone containing a first SCR catalyst; and an oxidation zone containing (a) an ASC zone and a DOC zone or (b) a mixed ASC and DOC zone, where the oxidation zone contains an ammonia oxidation catalyst and a DOC catalyst, the SCR zone is positioned on the substrate from the inlet end and extends less than the axial length of the substrate from the inlet, the DOC zone or the mixed ASC and DOC zone is position on the substrate from the outlet end, and when the DOC zone is present, the ASC zone is located between the SCR zone and the DOC zone. In other catalytic articles, the ASC zone further comprises a DEC catalyst. Methods of using the catalytic articles in an SCR process, where the amount of ammonia slip is reduced, are also described.

First claim

1 . A catalytic article comprising
i a flow-through substrate having an inlet, an outlet, and an axial length; ii an SCR zone having a first SCR catalyst and being positioned on the substrate from the inlet to less than the axial length of the substrate; and iii and an oxidation zone comprising a PGM-containing ammonia oxidation catalyst and a PGM-containing DOC catalyst wherein, the PGM-containing ammonia oxidation catalyst and the PGM-containing DOC catalyst are arranged in (a) an ASC zone and a separate DOC zone or (b) a mixed ASC and DOC zone, wherein the DOC zone or the mixed ASC and DOC zone is positioned on the substrate from the outlet end to less than the axial length of the substrate, and when the separate DOC zone is present, the ASC zone is located between the SCR zone and the DOC zone,
provided that the DOC catalyst has a higher concentration (grams per cubic liter) of PGM relative to the ammonia oxidation catalyst.

2 . The catalytic article of claim 1 , where the first SCR catalyst overlaps a portion of the ASC zone or a mixed ASC/DOC zone.

3 . The catalytic article of claim 1 , where (a) the ASC zone comprises a bottom layer comprising an ammonia oxidation catalyst and a top layer comprising the first SCR catalyst, where the first SCR catalyst covers the entire portion of the ammonia oxidation catalyst in the ASC zone, and (b) the DOC zone comprises a bottom layer comprising an ammonia oxidation catalyst and a top layer comprising the DOC catalyst, where the DOC catalyst covers the entire portion of the ammonia oxidation catalyst in the DOC zone.

4 . The catalytic article of claim 1 , where the ASC zone comprises a bottom layer comprising a mixture of an ammonia oxidation catalyst and a DOC, and a portion of the first SCR also forms a top layer that covers the entire portion of the mixture of the ammonia oxidation catalyst and the DOC in the ASC zone, and the DOC zone comprises a mixture of an ammonia oxidation catalyst and a DOC, where the mixture is located on the substrate in the ASC zone and the DOC zone.

5 . The catalytic article of claim 1 , where the ASC zone comprises a bottom layer comprising a mixture of an ammonia oxidation catalyst and a DOC, where the bottom layer is located on the substrate, and a portion of the first SCR forms a top layer that covers the entire portion of the bottom layer in the ASC zone, and the DOC zone comprises a mixture of an ammonia oxidation catalyst and a DEC, where the mixture of an ammonia oxidation catalyst and a DOC in the DOC zone is located on the substrate.

6 . The catalytic article of claim 1 , where the oxidation zone comprises a mixed ASC/DOC zone comprising a bottom layer comprising a mixture of an ammonia oxidation catalyst and a DOC, and a top layer comprising the first SCR, where the top layer covers the entire bottom layer, and the bottom layer is located on the substrate.

7 . The catalytic article of claim 1 , further comprising a second SCR catalyst, where the second SCR catalyst covers a portion of the first SCR catalyst and the second SCR catalyst is the same as, or different than, the first SCR catalyst.

8 . The catalytic article of claim 1 , further comprising a second SCR catalyst, where the first SCR catalyst covers a portion of the second SCR catalyst and the second SCR catalyst is the same as, or different than, the first SCR catalyst.

9 . The catalytic article of claim 7 , where the second SCR catalyst comprises a different active catalyst than the first SCR catalyst.

10 . The catalytic article of claim 8 , where the second SCR catalyst has a different loading than the first SCR catalyst.

11 . The catalyst article of claim 7 , where the ASC zone comprises the first SCR catalyst, the second SCR catalyst and an ammonia oxidation catalyst.

12 . The catalytic article of claim 7 , where the ASC zone comprises a bottom layer comprising an ammonia oxidation catalyst, a middle layer comprising the first SCR catalyst, and a third layer comprising the second SCR catalyst.

13 . The catalytic article of claim 7 , where the ASC zone comprises a bottom layer comprising a mixture of an ammonia oxidation catalyst and a DOC, a middle layer comprising the first oxidation catalyst, and a third layer comprising the second SCR catalyst.

14 . The catalytic article of claim 7 , where the SCR zone comprises the first SCR catalyst and the second SCR catalyst and the second SCR catalyst overlaps a portion of the first SCR catalyst in the SCR zone, and the mixed ASC/DOC zone comprises a bottom layer comprising a mixture of an ammonia oxidation catalyst and a DOC, where the bottom layer is located on the substrate, and a top layer comprising the second SCR that covers the entire portion of the bottom layer in the mixed ASC/DOC zone.

15 . The catalytic article of claim 1 , where the ASC comprises a bi-layer with a lower layer comprising an ammonia oxidation catalyst and an upper layer, comprising an SCR catalyst.

16 . An exhaust system comprising the catalytic article of claim 1 and a means for forming NH 3 in the exhaust gas or introducing NH 3 into the exhaust gas.

17 . A method of providing low temperature NOx control coupled with good ASC selectivity and DOC capability in the exhaust from a diesel engine, the method comprising contacting an exhaust gas from the engine with a catalyst article of claim 1 .

Assignees

• Johnson Matthey Plc

Inventors

• Gilbert Lee
• Newman Colin
• Newman Andrew
• Larsson Mikael

Classifications

• B01D53/9418 Primary

  for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas · CPC title

• F01N13/009

  having two or more separate purifying devices arranged in series · CPC title

• F01N13/0097

  the purifying devices are arranged in a single housing · CPC title

• F01N2330/06

  Ceramic, e.g. monoliths · CPC title

• F01N3/106

  Auxiliary oxidation catalysts · CPC title