Electrostatic levitation crystal growth apparatus for solution and crystal growing method using the same

Patent metadata

Field	Value
Publication number	US-2016362811-A1
Application number	US-201615246980-A
Country	US
Kind code	A1
Filing date	Aug 25, 2016
Priority date	Feb 28, 2014
Publication date	Dec 15, 2016
Grant date	—

Abstract

An electrostatic levitation crystal growth apparatus for a solution and a crystal growing method using the same. The apparatus may include an upper electrode, a lower electrode vertically spaced apart from the upper electrode, a power supply unit configured to apply a vertical electrostatic field between the upper electrode and the lower electrode, and a droplet dispenser configured to eject a solution into a region between the upper and lower electrodes and thereby to form a solution droplet. The solution droplet may be maintained in a charged state and may be electrostatically levitated against the gravity exerted thereon, by the vertical electrostatic field. The solution droplet may be evaporated in the electrostatically levitated state, and a solute dissolved in the solution may be grown to form a crystal.

First claim

What is claimed is:

1 . An electrostatic levitation crystal growth apparatus, comprising:
an upper electrode; a lower electrode vertically spaced apart from the upper electrode; a power supply unit configured to apply a vertical electrostatic field between the upper electrode and the lower electrode; and a droplet dispenser configured to eject a solution into a region between the upper and lower electrodes and thereby to form a solution droplet, wherein the solution droplet can be maintained in a charged state and electrostatically levitated against a gravity by the vertical electrostatic field, the solution droplet can be evaporated in the electrostatically levitated state, and a solute dissolved in the solution can be grown to form a crystal.

2 . The apparatus of claim 1 , wherein the solution droplet is charged with the same type of charges as that of the lower electrode, through a triboelectric charging with the droplet dispenser.

3 . The apparatus of claim 1 , wherein the solution droplet is electrostatically levitated in an air pressure.

4 . The apparatus of claim 1 , wherein the droplet dispenser comprises a nozzle unit configured to eject a preliminary solution droplet,
the nozzle unit comprises a conductive material, the conductive material is maintained at a same electric potential as the lower electrode, and the conductive material is used to charge the preliminary solution droplet with positive charges.

5 . The apparatus of claim 1 , wherein the lower electrode is grounded, and
the upper electrode is maintained at a negative voltage.

6 . The apparatus of claim 1 , wherein the droplet dispenser comprises a nozzle unit configured to eject a preliminary solution droplet,
the nozzle unit comprises: a needle providing a fluid passage, the needle being configured to eject the solution and to form the preliminary solution droplet; and a droplet cutting unit enclosing the needle and comprising an upper cover with a hole, wherein the hole is configured to be opened, when an end portion of the needle passes through the hole, and the droplet cutting unit is configured to cut the ejected preliminary solution droplet and thereby to form a solution droplet, when the preliminary solution droplet is ejected from the needle that protrudes above the upper cover.

7 . The apparatus of claim 6 , wherein the upper cover of the droplet cutting unit is a cone-shaped structure, and
the upper cover comprises a plurality of slits extending from an apex of the upper cover in a radial direction.

8 . The apparatus of claim 4 , wherein the nozzle unit is formed of or coated with a water-repellent or hydrophobic material.

9 . The apparatus of claim 6 , wherein the upper cover is formed of a stretchable or elastic material.

10 . The apparatus of claim 6 , wherein the droplet dispenser comprises:
a needle linear motion driving unit configured to allow for a vertical motion of the needle; and a droplet cutting linear motion driving unit configured to allow for a vertical motion of the droplet cutting unit.

11 . The apparatus of claim 6 , wherein an end portion of the nozzle unit of the droplet dispenser is positioned between the lower electrode and the upper electrode through a through-hole formed at a center of the lower electrode.

12 . The apparatus of claim 1 , further comprising:
a pair of first auxiliary electrodes configured to apply a first auxiliary electric field to a plane perpendicular to a center axis of the lower electrode and disposed to face each other with the solution droplet interposed therebetween; a pair of second auxiliary electrodes configured to apply a second auxiliary electric field to a plane perpendicular to the center axis of the lower electrode and disposed to face each other with the solution droplet interposed therebetween; a first auxiliary power configured to apply a first auxiliary voltage between the first auxiliary electrodes; and a second auxiliary power configured to apply a second auxiliary voltage between the second auxiliary electrodes, wherein the first auxiliary electric field is substantially orthogonal to the second auxiliary electric field.

13 . The apparatus of claim 1 , further comprising at least one of:
a vertical position measuring light source configured to irradiate light onto the levitated solution droplet; a vertical position detection unit disposed to face the position measuring light source and configured to detect a position of the levitated solution droplet; a crystallization-inducing probe configured to be in contact with the levitated solution droplet and induce formation of a crystal; a sealing unit surrounding the levitated solution droplet and providing a sealed space; a temperature control unit configured to control an internal air temperature of the sealing unit; and a humidity control unit configured to control an internal humidity of the sealing unit.

14 . The apparatus of claim 1 , wherein the crystal is formed of AH 2 PO 4 (A=K, NH4, Cs), ABCl 3 (A=Cs, K, Rb; B=Co, Cu, Zn, Cd, Mn), LiASO 4 (A=Cs, K), CuSO 4 .5H 2 O, K 3 Fe(CN) 6 , DKDP, KDCO 3 , NiSO 4 .6H 2 O, NaKC 4 H 4 O 6 (potassium sodium tartrate, Rochelle Salt), (NH 2 CH 2 COOH) 3 .H 2 SO 4 (triglycine sulfate; TGS), KD 2 PO 4 (deuterated potassium dihydrogen phosphate; DKDP), NaCl, protein crystal, or KH 2 PO 4 (potassium dihydrogen phosphate; KDP).

15 . A method of growing a crystal using an electrostatic levitation technique, comprising:
applying a vertical electrostatic field between an upper electrode and a lower electrode against a direction of gravity; levitating a solution droplet between the upper electrode and the lower electrode; evaporating a solvent from the solution droplet to form a supersaturated solution; creating a crystal nucleus in the supersaturated solution; and growing the crystal nucleus to form a crystal.

16 . The method of claim 15 , wherein the levitating of the solution droplet between the upper electrode and the lower electrode comprises:
elevating a needle and a solution cutting unit enclosing the needle through a through-hole formed at a center of the lower electrode; applying a DC electric potential, which is higher than an electric potential of the upper electrode, to the needle; ejecting a solution through an end portion of the elevated needle to form a preliminary solution droplet; charging the preliminary solution droplet with positive charges; lowering the needle or elevating the solution cutting unit to cut the preliminary solution droplet; and lowering the solution cutting unit enclosing the needle and needle.

17 . The method of claim 15 , wherein the levitating of the solution droplet between the upper electrode and the lower electrode comprises:
elevating a needle through a through-hole formed at a center of the lower electrode; applying a DC electric potential, which is higher than an electric potential of the upper electrode, to the needle; ejecting a solution through an end portion of the elevated needle to form a preliminary solution droplet; charging the preliminary solution droplet with positive charges; increasing a magnitude of the vertical electrostatic field; and lowering the needle.

18 . The method of claim 15 , wherein the levitating of the solution droplet between the upper electrode and the lower electrode comprises:
elevating a needle through a through-hole formed at a center of the lower electrode; ejecting a solution through an end portion of the elevated needle to form a prelimina

Assignees

• Korea Res Inst Standards & Sci

Inventors

• Lee Geun-Woo
• Lee Soo Heyong

Classifications

• B23K26/70

  Auxiliary operations or equipment · CPC title

• B01D1/0082

  Regulation; Control · CPC title

• B01D1/0029

  Use of radiation · CPC title

• C30B7/02 Primary

  by evaporation of the solvent · CPC title

• C30B30/08

  in conditions of zero-gravity or low gravity · CPC title