Autoclavable cfx cell

Patent metadata

Field	Value
Publication number	US-2016359198-A1
Application number	US-201414148061-A
Country	US
Kind code	A1
Filing date	Jan 6, 2014
Priority date	Jan 4, 2013
Publication date	Dec 8, 2016
Grant date	—

Abstract

An autoclavable electrochemical cell that may be used in an implantable or external medical device is described. The anode active material comprises lithium or other material from groups IA and IIA of the Periodic Table. The cathode active material comprises carbon monofluoride, silver vanadium oxide, copper vanadium oxide, transition metal oxides, and combinations thereof. The solvent for the electrolyte has a boiling point greater than about 100° C. and is capable of wetting a surfactant free polymeric separator material such that the cell may be dimensionally and chemically stable during repeated exposures to an autoclave environment.

First claim

1 .- 12 . (canceled)

13 . An electrochemical cell that is configured for expose to an autoclave environment, the electrochemical cell comprising:
a) a casing; b) an anode comprising lithium; c) a cathode comprising carbon monofluoride; d) a separator positioned between the anode and the cathode to prevent them from direct physical contact with each other and to thereby form an electrode assembly disposed inside the casing; and e) an ionically conductive electrolyte provided in the casing to activate the electrode assembly, the electrolyte consisting essentially of:
i) LiBF 4 ;
ii) γ-butyrolactone (GBL); and
iii) diglyme,
iv) wherein, by volume percent, the ratio of GBL:diglyme ranges from 45:55 to 55:45.

14 . The electrochemical cell of claim 13 wherein the carbon monofluoride is selected from C 2 F and CF x with x ranging from about 0.1 to 1.9.

15 . (canceled)

16 . The electrochemical cell of claim 13 wherein the electrolyte has a dielectric constant of at least about 5.

17 . The electrochemical cell of claim 13 wherein the separator comprises polypropylene having a tensile strength of at least 135 kgf/cm 2 .

18 .- 23 . (canceled)

24 . The electrochemical cell of claim 14 wherein in the formula CF x for the carbon monofluoride, x ranges from about 0.5 and 1.2.

25 . The electrochemical cell of claim 13 wherein the separator comprises polypropylene devoid of a surfactant.

26 . The electrochemical cell of claim 13 wherein the separator is selected from the group consisting of polypropylene, fluoropolymeric fibers, polyethylenetetrafluoroethylene, polyethylenechlorotrifluoroethylene, and polytetraflouroethylene.

27 . The electrochemical cell of claim 13 wherein at least one of the cathode and the anode comprise a current collector composed of a material selected from the group consisting of titanium, stainless steel, a superferrite material, nickel, cobalt nickel alloys, copper, aluminum, tungsten, gold, and platinum.

28 . An electrochemical cell that is configured for expose to an autoclave environment, the electrochemical cell comprising:
a) a casing; b) an anode comprising lithium; c) a cathode comprising carbon monofluoride; d) a separator positioned between the anode and the cathode to prevent them from direct physical contact with each other and to thereby form an electrode assembly disposed inside the casing; and e) an electrolyte provided in the casing to activate the electrode assembly, the electrolyte consisting essentially of:
i) an ionically conductive lithium salt;
ii) γ-butyrolactone (GBL); and
iii) diglyme,
iv) wherein, by volume percent, the ratio of GBL:diglyme ranges from 45:55 to 55:45.

29 . The electrochemical cell of claim 28 wherein the cathode has a sandwich design comprising CF x and silver vanadium oxide (SVO).

30 . The electrochemical cell of claim 28 wherein the separator is selected from the group consisting of polypropylene, fluoropolymeric fibers, polyethylenetetrafluoroethylene, polyethylenechlorotrifluoroethylene, and polytetraflouroethylene.

31 . The electrochemical cell of claim 28 wherein the separator comprises polypropylene devoid of a surfactant.

32 . The electrochemical cell of claim 28 wherein the separator comprises polypropylene having a tensile strength of at least about 135 kgf/cm 2 .

33 . The electrochemical cell of claim 28 wherein the ionically conductive lithium salt is selected from the group consisting of LiBF 4 , LiPF 6 , LiAsF 6 , LiSbF 6 , LiClO 4 , LiO 2 , LiAlCl 4 , LiGaCl 4 , LiC(SO 2 CF 3 ) 3 , LiN(SO 2 CF 3 ) 2 , LiSCN, LiO 3 SCF 3 , LiC 6 F 5 SO 3 , LiO 2 CCF 3 , LiSO 6 F, LiB(C 6 H 5 ) 4 , LiCF 3 SO 3 , and mixtures thereof.

34 . The electrochemical cell of claim 28 wherein the electrolyte has a dielectric constant of at least about 5.

35 . An electrochemical cell that is configured for expose to an autoclave environment, the electrochemical cell comprising:
a) a casing; b) an anode comprising lithium; c) a cathode comprising carbon monofluoride; d) a separator positioned between the anode and the cathode to prevent them from direct physical contact with each other and to thereby form an electrode assembly disposed inside the casing; and e) an electrolyte provided in the casing to activate the electrode assembly, the electrolyte comprising:
i) an ionically conductive lithium salt selected from the group consisting of LiBF 4 , LiPF 6 , LiAsF 6 , LiSbF 6 , LiClO 4 , LiO 2 , LiAlCl 4 , LiGaCl 4 , LiC(SO 2 CF 3 ) 3 , LiN(SO 2 CF 3 ) 2 , LiSCN, LiO 3 SCF 3 , LiC 6 F 5 SO 3 , LiO 2 CCF 3 , LiSO 6 F, LiB(C 6 H 5 ) 4 , LiCF 3 SO 3 , and mixtures thereof; and
ii) a solvent mixture consisting essentially of γ-butyrolactone (GBL) and diglyme,
iii) wherein, by volume percent, diglyme comprises from about 30 volume percent to about 70 volume percent of the solvent mixture, the remainder comprising γ-butyrolactone.

36 . An electrochemical cell that is configured for expose to an autoclave environment, the electrochemical cell comprising:
a) a casing; b) an anode comprising lithium; c) a cathode comprising carbon monofluoride; d) a separator positioned between the anode and the cathode to prevent them from direct physical contact with each other and to thereby form an electrode assembly disposed inside the casing; and e) an electrolyte provided in the casing to activate the electrode assembly, the electrolyte comprising:
i) LiBF 4 ;
ii) γ-butyrolactone (GBL); and
iii) diglyme,
iv) wherein, by volume percent, the ratio of GBL:diglyme ranges from 45:55 to 55:45.

37 . The electrochemical cell of claim 36 wherein the cathode has a sandwich design comprising CF x and silver vanadium oxide (SVO).

38 . The electrochemical cell of claim 36 wherein the electrolyte has a dielectric constant of at least about 5.

39 . The electrochemical cell of claim 36 wherein the separator comprises polypropylene devoid of a surfactant.

Assignees

• Greatbatch Ltd

Inventors

• Gan Hong
• Guo Rui

Classifications

• H01M50/494

  Tensile strength · CPC title

• H01M50/417

  Polyolefins · CPC title

• H01M50/426

  Fluorocarbon polymers · CPC title

• H01M10/0569 Primary

  characterised by the solvents · CPC title

• H01M10/052

  Li-accumulators · CPC title