Iridium (iii) based phosphors bearing pincer carbene and pyrazolyl chelates

Patent metadata

Field	Value
Publication number	US-2016355534-A1
Application number	US-201514806801-A
Country	US
Kind code	A1
Filing date	Jul 23, 2015
Priority date	Jun 5, 2015
Publication date	Dec 8, 2016
Grant date	—

Abstract

The present invention provides a class of iridium (III) based phosphors bearing both pincer carbene and pyrazolyl chelates. Differing from the conventional cyclometalated Ir(III) metal complexes, these novel phosphorescent Ir(III) metal complexes are synthesized from a class of pincer carbene chelate, a class of pyrazolyl-based chelate and an iridium metal source complex. Because the phosphorescent Ir(III) metal complex proposed by the present invention includes multiple strong bonding interactions (Ir—C bond), the non-radiative decay from the higher lying triplet excited state can be effectively suppressed. Thus, this novel phosphorescent Ir(III) metal complex is able to emit a range of visible light (particularly the blue light) with high color purity and high efficiency as neat sample. Moreover, this novel phosphorescent Ir(III) metal complex is also adapted as the guest emitter in the light emitting layer (EML) for the traditional doped OLED architecture.

First claim

What is claimed is:

1 . An iridium (III) based phosphor bearing both pincer carbene and pyrazolyl chelates, and fabricated by using a dicarbene chelate, a pyrazolyl-based chelate and an iridium metal source complex as starting materials for carrying out chemical synthesis.

2 . The iridium (III) based phosphor bearing both pincer carbene and pyrazolyl chelates of claim 1 , wherein the phosphorescent Ir(III) metal complex is represented by following chemical formulas I, II, III, IV, V, VI, VII, VIII, and IX:

wherein R in chemical formulas I˜IX is an aliphatic substituent represented by isopropyl (i-Pr).

3 . The iridium (III) based phosphor bearing both pincer carbene and pyrazolyl chelates of claim 1 , wherein the dicarbene chelate is synthesized from following chemical formulas L1 and L2:

wherein R in chemical formulas L1 and L2 is an aliphatic molecular group represented by isopropyl (i-Pr).

4 . The iridium (III) based phosphor bearing pincer carbene and pyrazolyl chelates of claim 1 , wherein the pyrazolyl-based chelate is synthesized from the following chemical formulas L3, L4, L5, L6, L7, L8, and L9:

5 . The iridium (III) based phosphor bearing both pincer carbene and pyrazolyl chelates of claim 1 , wherein the iridium metal source complex is μ-chloro-bis[1,5-cyclooctadiene]iridium (III) dimer with the molecular formula of [Ir(COD)(μ-Cl)] 2 .

6 . The iridium (III) based phosphor bearing both pincer carbene and pyrazolyl chelates of claim 1 , having highest occupied molecular orbital energy levels (E HOMO ) ranged from 5.1 eV to 5.65 eV.

7 . The iridium (III) based phosphor bearing both pincer carbene and pyrazolyl chelates of claim 1 , wherein the phosphorescent Ir(III) metal complex containing double tridentate ligands can be applied as a guest light-emitting material in the OLED applications.

Assignees

• Nat Univ Tsing Hua

Inventors

• Chi Yun
• Tong Bihai
• Chen I-Jen
• Kuei Chu-Yun

Classifications

• C09K2211/185

  of the platinum group, i.e. Os, Ir, Pt, Ru, Rh or Pd · CPC title

• H01L51/0085

  Electricity · mapped topic

• C07F15/0033 Primary

  Iridium compounds · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• H10K85/342

  comprising iridium · CPC title