Positive electrode for lithium ion secondary battery and lithium ion secondary battery using same

Patent metadata

Field	Value
Publication number	US-2016351902-A1
Application number	US-201515119016-A
Country	US
Kind code	A1
Filing date	Feb 5, 2015
Priority date	Feb 20, 2014
Publication date	Dec 1, 2016
Grant date	—

Abstract

There is provided a lithium ion secondary battery having a high capacity retention rate in the charge-discharge cycles. There is provided a positive electrode for a lithium ion secondary battery, including a positive electrode active material including a compound represented by the following formula (1), Li x (Ni y Co z Al w )O 2 , wherein, in formula (1), 0.95≦x≦1.05, 0.70≦y≦0.85, 0.05≦z≦0.20, 0.00≦w≦0.10, and y+z+w=1, and a compound represented by the following formula (2), Li 1+u Mn 2−u/3 O 4 , wherein, in formula (2), wherein the content of the alkali metal hydroxide in the positive electrode active material is 0.15% by mass or less.

First claim

1 . A positive electrode for a lithium ion secondary battery, comprising a positive electrode active material comprising a compound represented by the following formula (1)
Li x (Ni y Co z Al w )O 2   (1)
wherein, in formula (1), 0.95≦x≦1.05, 0.70≦y≦0.85, 0.05≦z≦0.20, 0.00≦w≦0.10, and y+z+w=1, and a compound represented by the following formula (2)
Li 1+u Mn 2−u/3 O 4   (2)

wherein, in formula (2), 0≦u≦0.05, wherein the content of the alkali metal hydroxide in the positive electrode active material is 0.15% by mass or less.

2 . The positive electrode for a lithium ion secondary battery according to claim 1 , wherein the content of the alkali metal hydroxide comprised as an impurity in the compound represented by formula (1) is 0.45% by mass or less.

3 . The positive electrode for a lithium ion secondary battery according to claim 1 , wherein the alkali metal hydroxide is lithium hydroxide.

4 . The positive electrode for a lithium ion secondary battery according to claim 1 , wherein the pH of an aqueous dispersion comprising 2% by mass of the compound represented by formula (1) is 11.0 or more and 11.5 or less.

5 . The positive electrode for a lithium ion secondary battery according to claim 1 , wherein the content of the alkali metal hydroxide in the positive electrode active material is 0.01% by mass or more.

6 . The positive electrode for a lithium ion secondary battery according to claim 1 , wherein the content of the alkali metal hydroxide in the positive electrode active material is less than 0.10% by mass.

7 . The positive electrode for a lithium ion secondary battery according to claim 1 , wherein the mass of the compound represented by formula (1) comprised in the positive electrode active material is 5% by mass or more and 50% by mass or less in relation to the total mass of the compound represented by formula (1) and the compound represented by formula (2) comprised in the positive electrode active material.

8 . The positive electrode for a lithium ion secondary battery according to claim 1 , wherein polyvinylidene fluoride is comprised as a binder.

9 . A lithium ion secondary battery comprising the positive electrode for a lithium ion secondary battery according to claim 1 and a negative electrode.

10 . The lithium ion secondary battery according to claim 9 , wherein the negative electrode comprises a negative electrode active material comprising graphite.

11 . The lithium ion secondary battery according to claim 10 , wherein the graphite has no coating film provided on the surface thereof, or the graphite has a coating film provided on the surface thereof, and the amount of the coating film is less than 10% by mass in relation to the graphite.

12 . The lithium ion secondary battery according to claim 9 , comprising an electrolyte solution comprising as an additive a compound capable of forming a coating film having a Lewis acid on the negative electrode by charge-discharge.

13 . The lithium ion secondary battery according to claim 9 , comprising an electrolyte solution comprising LiPF 6 .

Assignees

• Nec Energy Devices Ltd

Inventors

• Hamanaka Nobuaki

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title