Method for separating a hydrocarbon mixture containing hydrogen, separating device, and olefin plant

Patent metadata

Field	Value
Publication number	US-2016348964-A1
Application number	US-201415109960-A
Country	US
Kind code	A1
Filing date	Dec 17, 2014
Priority date	Jan 7, 2014
Publication date	Dec 1, 2016
Grant date	—

Abstract

A method for separating a hydrogen-containing hydrocarbon mixture (C2minus), which in addition to the hydrogen essentially contains hydrocarbons with two carbon atoms and methane, using a distillation column ( 10 ). Fluid (a, c, e) of the hydrocarbon mixture (C2minus) is cooled stepwise at a first pressure level, during which time first condensates (b, d) are separated from the fluid (a, c, e). Fluid (e) from the hydrocarbon mixture (C2minus) which remains gaseous after this is fed at the first pressure level into a C2 absorber ( 7 ), to which a liquid reflux (r) is added at the top, while a second condensate (f) is drawn off from the sump of the C2 absorber ( 7 ) and a gaseous top stream (g) containing predominantly methane and hydrogen is drawn off at the top of the C2 absorber ( 7 ). Fluid of the above-mentioned gaseous top stream (g) from the top of the C2 absorber ( 7 ) is cooled to a third temperature level and transferred at the first pressure level into a hydrogen separator ( 8 ) in which a methane-rich third condensate (i) is separated from the fluid of the gaseous top stream (g), leaving behind a gaseous, hydrogen-rich stream (h). Fluid of the first condensates (b, d) and fluid of the second condensate (f) is depressurized from the first pressure level to a second pressure level below the first pressure level and fed into the distillation column ( 10 ) which is operated at the second pressure level. Fluid (e) of the third condensate (i) which is separated in the hydrogen separator ( 8 ) from the fluid of the gaseous top stream (g) from the top of the C2 absorber is used as the reflux (r) added at the top of the C2 absorber ( 7 ) and transferred from the hydrogen separator to the C2 absorber solely by gravity. The invention also relates to a corresponding separating unit and a corresponding olefin apparatus.

First claim

1 . Method for separating a hydrogen-containing hydrocarbon mixture (C2minus), which in addition to the hydrogen essentially contains hydrocarbons with two carbon atoms and methane, using a distillation column ( 10 ), wherein
fluid (a, c, e) of the hydrocarbon mixture (C2minus) is cooled stepwise, at a first pressure level, from a first temperature level, via two or more intermediate temperature levels, to a second temperature level, first condensates (b, d) being separated from the fluid (a, c, e) at each of the intermediate temperature levels, fluid (e) of the hydrocarbon mixture (C2minus) which remains gaseous at the second temperature level is fed at the first pressure level into a C2 absorber ( 7 ), to which a liquid reflux (r) is added at the top, wherein a second condensate (f) is drawn off from the sump of the C2 absorber ( 7 ) and a gaseous top stream (g) comprising predominantly methane and hydrogen is drawn off at the top of the C2 absorber ( 7 ), fluid of the gaseous top stream (g) from the top of the C2 absorber ( 7 ) is cooled to a third temperature level and transferred at the first pressure level into a hydrogen separator ( 8 ) in which a methane-rich third condensate (i) is separated from the fluid of the gaseous top stream (g), leaving behind a gaseous, hydrogen-rich stream (h), and fluid of the first condensates (b, d) and fluid of the second condensate (f) is depressurized from the first pressure level to a second pressure level below the first pressure level and fed into the distillation column ( 10 ) which is operated at the second pressure level, wherein in the distillation column ( 10 ) at least a liquid stream (o) essentially consisting of hydrocarbons with two carbon atoms, and a liquid stream (m) essentially consisting of methane are obtained and drawn off from the distillation column ( 10 ),
characterised in that the reflux (r) added at the top of the C2 absorber is formed from fluid of the third condensate (i) which is separated in the hydrogen separator ( 8 ) from the fluid of the gaseous top stream (g) from the top of the C2 absorber ( 7 ) and transferred from the hydrogen separator ( 8 ) into the C2 absorber ( 7 ) solely by the effect of gravity.

2 . Method according to claim 1 , wherein a quantity of the fluid of the third condensate (i) used as reflux (r) is selected so as to correspond to a quantity of the liquid stream (m), consisting essentially of methane, which is drawn off from the distillation column ( 10 ).

3 . Method according to claim 1 or 2 , wherein fluid from the liquid stream (m) which is drawn off from the distillation column ( 10 ) is used at least to cool the fluid (a, c, e) of the hydrocarbon mixture (C2minus) from the first temperature level, via the intermediate temperature levels, to the second temperature level.

4 . Method according to one of the preceding claims, wherein fluid from the gaseous, hydrogen-rich stream (h) from the hydrogen separator ( 8 ) is used to cool the fluid (a, c, e) of the hydrocarbon mixture (C2minus) from the first temperature level, via the intermediate temperature levels, to the second temperature level, and to cool the fluid of the gaseous top stream (g) from the top of the C2 absorber ( 7 ) to the third temperature level.

5 . Method according to one of the preceding claims which is used to separate a hydrocarbon mixture (C2minus) which is obtained from a cracked gas obtained by means of a steam cracking process ( 50 ).

6 . Separating unit ( 100 ) which is designed to separate a hydrogen-containing hydrocarbon mixture (C2minus), which in addition to hydrogen essentially contains hydrocarbons with two carbon atoms and methane, and comprises at least one distillation column ( 10 ), a C2 absorber ( 7 ) and a hydrogen separator ( 8 ), as well as means which are designed
to cool fluid (a, c, e) of the hydrocarbon mixture (C2minus), at a first pressure level, stepwise from a first temperature level, via two or more intermediate temperature levels, to a second temperature level and to separate first condensates (b, d) from the fluid (a, c, e) at each of the intermediate temperature levels, to feed, at the first pressure level, fluid (e) of the hydrocarbon mixture (C2minus) which remains gaseous at the second temperature level into the C2 absorber ( 7 ), to add a liquid reflux (r) to the C2 absorber at the top, and to draw off a second condensate (f) from the sump of the C2 absorber ( 7 ) and a gaseous top stream (g), predominantly containing methane and hydrogen, at the top of the C2 absorber ( 7 ), to cool fluid of the gaseous top stream (g) from the top of the C2 absorber ( 7 ) to a third temperature level and transfer it, at the first pressure level, into the hydrogen separator ( 8 ) and therein to separate off a methane-rich third condensate (i) from the fluid of the gaseous top stream (g), leaving behind a gaseous, hydrogen-rich stream (h), and to depressurize fluid of the first condensates (b, d) and fluid of the second condensate (f) from the first pressure level to a second pressure level below the first pressure level and to fed it into the distillation column ( 10 ), to operate the distillation column ( 10 ) at the second pressure level, and to obtain in, and to draw off from, the distillation column ( 10 ) at least a liquid stream (o) essentially consisting of hydrocarbons with two carbon atoms, and a liquid stream (m) essentially consisting of methane,
characterised in that means are provided which are designed to form the reflux (r) added at the top of the C2 absorber from fluid (e) of the third condensate (i) which is separated in the hydrogen separator ( 8 ) from the fluid of the gaseous top stream (g) from the top of the C2 absorber ( 7 ) and is transferred from the hydrogen separator ( 8 ) into the C2 absorber ( 7 ) solely by the effect of gravity.

7 . Separating unit ( 100 ) according to claim 6 , which is designed for carrying out a method according to one of claims 1 to 7 .

8 . Olefin apparatus which is designed to carry out a steam cracking process ( 50 ) using at least one cracking furnace ( 51 - 53 ), with means which are designed to recover a hydrocarbon mixture (C2minus) consisting essentially of hydrocarbons with two carbon atoms as well as methane and hydrogen, from fluid of a cracked gas (C) of the at least one steam cracking process ( 50 ), characterised by at least one separating unit ( 100 ) according to claim 6 or 7 , which is designed to separate the hydrocarbon mixture (C2minus).

Assignees

• Linde Ag

Inventors

• Fritz Helmut
• Höfel Torben

Classifications

• C07C7/09

  by fractional condensation · CPC title

• B01D53/002

  by condensation · CPC title

• F25J2270/60

  Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons · CPC title

• F25J2215/60

  Methane · CPC title

• B01D53/1493

  Selection of liquid materials for use as absorbents · CPC title